CAS: 58328-31-7; 4,4-Di(9H-Carbazol-9-yl)-1,1-Biphenyl

该化合物是一种高性能有机半导体材料,广泛用于光电子应用,特别是有机光排放二极管和光伏装置,其主要优点包括极好的洞车运输特性,高热稳定性和在多层装置结构中高效充电运输的配对能源水平;硬性双苯核心和碳酸盐替代成分有助于其高玻璃转换温度(Tg),确保运作条件下的形态稳定性;CBP还因其良好的电影成型能力和与各种东道方系统兼容性而闻名,使它成为需要可靠高效性能的先进有机电子应用的首选.

结构式图片

相似化合物

838862-47-8 58328-31-7 848086-93-1

欧盟法规

ECHA物质C&L通报

上下游产品

4-(4-bromophenyl)bromobenzene 9H-carbazole 4,4'-diiodobiphenyl N-(trimethylsilyl)-9H-carbazole

合成工艺路线路线简述

    2-溴联苯置于正丁基锂,Dichloro(Pentamethylcyclopentadienyl)Rhodium (Iii) Dimer,Silver(I) Acetate,Sodium Carbonate体系中,用 四氢呋喃,1,4-二氧六环 作为反应溶剂,化学反应 25.0H,反应生成 4,4'-二(9-咔唑)联苯
    参考文献:Rh(iii)催化芳基叠氮化物对硼酸的c-h活化
    标题:Rh(iii)催化芳基叠氮化物对硼酸的c-h活化
    摘要:已开发出一种rh(iii)催化的芳基叠氮化物对硼酸的chh活化,从而获得不对称的咔唑,1 H吲哚或二氢吲哚.该反应通过sp 2 / Sp 3 C-H活化和铑氮烯插入构建了两个不同的c-n键.综合而言,这种方法代表了广泛使用咔唑衍生物的途径.还已经对cbp和不对称tcta衍生物进行了实际应用.力学实验和dft计算表明,五元rhodocycle物种是关键的中间体.
    DOI:10.1021/acs.Orglett.8B02247

    海关参考信息

    专利信息


    专利号:US-6350875-B1
    优先权日:1999-08-16
    标 题:Synthesis of cyclooctatetraene derivatives and their use as electron transporters in organic light emitting diodes
    发明人:WEBER WILLIAM P; LU PING; THOMPSON MARK E; HONG HAIPING
    权利人:UNIV SOUTHERN CALIFORNIA
    摘要:The synthesis of asymmetric tetrasubstituted cyclooctatetraenes (“COTsâ€?) and the use of said compounds in organic light emitting diodes is reported, wherein said COTs represent a class of wide gap electron transporters that are readily deposited in vacuum.

    专利号:US-8987451-B2
    优先权日:2012-01-03
    标题 :Synthesis of cyclometallated platinum(II) complexes
    发明人:TSAI JUI-YI; KOTTAS GREGG; YEAGER WALTER
    权利人:UNIVERSAL DISPLAY CORP
    摘要:A single-step method of making tetradentate platinum complexes is disclosed. The method advantageously allows the formation of a platinum complex in a single step, even with sterically hindered ligands, without the use of highly reactive intermediates. The compounds made by the disclosed method are useful in OLED applications.

    专利号:US-2024215280-A1
    优先权日:2022-10-31
    标 题:In situ core/shell perovskite nanocrystal material, method of preparation thereof, and light emitting device comprising the same
    发明人:LEE TAE-WOO; KIM JOO SUNG
    权利人:SEOUL NAT UNIV R&DB FOUNDATION; PEROLED CO LTD
    摘要:The present inventive concept relates to an in situ core/shell perovskite nanocrystal film formed by an in situ nanocrystal synthesis process, a method for producing the same, and a light emitting device comprising the same as a light-emitting layer. The in situ core/shell perovskite nanocrystal film formed by the in situ nanocrystal synthesis process according to the present inventive concept exhibits a strong charge confinement effect by nanocrystal formation, and can simultaneously greatly improve the luminescence efficiency and lifetime by maintaining the fast charge transport capability of polycrystalline perovskite.

    专利号:US-2019036041-A1
    优先权日:2014-10-28
    标 题:Organometallic Iridium Complex, Light-Emitting Element, Light-Emitting Device, Electronic Device, Lighting Device, and Synthesis Method of Organometallic Iridium Complex
    发明人:INOUE HIDEKO; YAMAGUCHI TOMOYA; SEO SATOSHI; YAMADA YUI
    权利人:SEMICONDUCTOR ENERGY LAB
    摘要:A high-purity organometallic iridium complex is provided. The organometallic iridium complex includes iridium and a plurality of ligands cyclometallated to the iridium. Each of the plurality of ligands includes a heteroaromatic ring having a coordinatable nitrogen atom. In LC analysis of the organometallic iridium complex, an impurity which has a monochlorinated ligand among the plurality of ligands is 0.1% or less by quantitating using peak area count with a PDA detector.

    专利号:EP-4471014-A1
    优先权日:2023-05-29
    标 题 :Derivate of quinoxaline with thermally activated delayed fluorescence
    发明人:SERDIUK ILLIA; MONKA MICHAL; GRZYWACZ DARIA
    权利人:UNIV GDANSKI
    摘要:The invention relates to the triarylamine derivatives of quinoxaline with thermally activated delayed fluorescence (TADF) bearing heavy atoms and methods of their synthesis. The emitters are characterized by spectral and photophysical properties with improved TADF parameters as compared to their analogues reported before. The disclosed emitters can convert triplet excitons into singlet ones faster and with higher efficiency. The emitters cover orange, red, and/or near infrared (NIR) spectral ranges. Furthermore, the mixtures of new emitters with fluorescent dopants exhibit narrowband NIR emission preserving fast triplet-singlet exciton conversion.The invention concerns functional organic materials which exhibit TADF and can be potentially used for the electroluminescence applications, e.g. in organic light emitting diodes (OLED), and/or applications of materials with long-lived excited states, e.g. photosensibilization, photocatalysis, and/or other fields where excited triplet states or excitons play important role.

    专利号:US-2013172561-A1
    优先权日:2012-01-03
    标 题:Synthesis of cyclometallated platinum(ii) complexes
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    主要参考文献

    [参考文献]: Chloé De Perre, Et Al. A Simultaneous Extraction Method For Organophosphate, Pyrethroid, And Neonicotinoid Insecticides In Aqueous Samples. Arch Environ Contam Toxicol. 2015 May;68(4):745-56.
    [参考文献]: Gabriela Morin, Et Al. A Rhesus Rhadinovirus Viral Interferon (Ifn) Regulatory Factor Is Virion Associated And Inhibits The Early Ifn Antiviral Response. J Virol. 2015 Aug;89(15):7707-21.
    [参考文献]: Jinxiang Dai, Et Al. Olig1 Acetylation And Nuclear Export Mediate Oligodendrocyte Development. J Neurosci. 2015 Dec 2;35(48):15875-93.
    [参考文献]: Johannes G M Rack, Et Al. The Phd Finger Of P300 Influences Its Ability To Acetylate Histone And Non-Histone Targets. J Mol Biol. 2014 Dec 12;426(24):3960-3972.
    [参考文献]: Khushbu K Modi, Et Al. Sodium Benzoate, A Metabolite Of Cinnamon And A Food Additive, Upregulates Ciliary Neurotrophic Factor In Astrocytes And Oligodendrocytes. Neurochem Res. 2015 Nov;40(11):2333-47.

    合成参考文献


    参考文献:10.1055/s-0039-1690759
    摘要:Ban J, Lim M, Shabbir S, Baek J, Rhee H. Site-Specific Synthesis of Carbazole Derivatives through Aryl Homocoupling and Amination. Synthesis. 2019 Nov 26;52(06):917–27. doi: 10.1055/s-0039-1690759.
    参考文献:10.1007/978-3-030-63713-2_63
    摘要:Fresta E, Costa RD. Applying Ionic Transition Metal Complexes to Light-Emitting Electrochemical Cells. 2022. In: Springer Handbooks.
    参考文献:10.1007/s40843-022-2350-7
    摘要:Ban C, Yin Y, Luo X, Liu Z, Chen K, Tang M, Dong X, Zhang D, Li Z, Wu Y, Liu J, Huang W. Light-/steam-driven polymeric crosslinking with porous multistructure pattern for ultrastable and fast-speed memory. Sci. China Mater. 2023 Feb 06;66(5):2023–31. doi: 10.1007/s40843-022-2350-7.
    参考文献:10.1007/s00214-023-02966-1
    摘要:Mandal S, Datta A. DFT calculations predict that inverted geometries at carbon can be stabilized within multi-component co-crystals. Theor Chem Acc. 2023 Feb 23;142(3). doi: 10.1007/s00214-023-02966-1.
    参考文献:10.1055/a-1904-0582
    摘要:Qian L, Liao J, Tao L. Catalytic Asymmetric [3+3] Cycloaddition of Activated Isocyanides with Azomethine Imines. Synlett. 2022 Aug 12;33(19):1873–8. doi: 10.1055/a-1904-0582.
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