CAS: 138495-42-8; 2H,3H-Decafluoropentane

该化合物是全氟化合物,其特点是完全氟化的碳柱骨;该物质是五氟结构,其所有氢原子都由氟原子取代,从而产生高度稳定和非极分子;室温无色气体,由于碳-氟的密钥强,其反应力较低;该化合物沸点低,在水中溶解,在各种应用中有用,包括作为一种制冷剂和特殊溶剂;其高热和化学稳定性,加上与其他氟化合物相比全球升温潜能较低,使其在某些工业过程中具有吸引力;然而,它与许多全氟物质一样,因其持久性和潜在生物累积性而引起环境问题;在处理和接触准则方面,应参考安全数据表,因为如果吸入或摄取,可能会对健康造成危害.

结构式图片

欧盟法规

ECHA物质C&L通报

合成工艺路线路线简述

    海关参考信息

    专利信息


    专利号:US-11970449-B2
    优先权日:2021-10-04
    标 题:Mechanochemical based synthesis of perfluoropyridine monomers for polymerization
    发明人:IACONO SCOTT T; FRIESEN CHADRON M
    权利人:US GOV AIR FORCE; US AIR FORCE
    摘要:The present invention relates to a mechanochemical based synthesis of perfluoropyridine monomers, polymers made using such monomers and methods of making and using articles comprising such polymers. Such perfluoropyridine monomers are easily chemically tuned have the strength needed for high temperature applications and the flexibility needed for low temperature applications. In addition, to the aforementioned monomers, a mechanochemical based synthesis for such perfluoropyridine monomers is provided. All of the aforementioned performance application advantages are also found in polymers comprising Applicants' perfluoropyridine monomers.

    专利号:US-6187954-B1
    优先权日:1999-07-15
    标题:Synthesis of fluorinated amides
    发明人:FALCONE SAMUEL J
    权利人:SEAGATE TECHNOLOGY LLC
    摘要:A fluoropolyalkylether is prepared under mild reaction condictions by combining a fluoropolyalkylether substituted with one or more ester end-groups with an amine. Embodiments include combining: (i) a fluoropolyalkylether substituted with one or more ester end-groups having the formula:with (ii) an amine having the formula:and (iii) a solvent comprising a hydrofluorocarbon or a hydrofluoroether together with a lower alcohol at a temperature of from about 15° C. to about 30° C. to form the fluoropolyalkylether amide, where Rf is a perfluoropolyether, R' is a lower alkyl group, q is 1-4; R1 is H and R2 is a C2-C4 or a C2-C4 substituted with at least one hydroxyl group.

    专利号:US-10273156-B2
    优先权日:2014-02-12
    标题 :Mechanochemical synthesis of alane
    发明人:GUPTA SHALABH; PECHARSKY VITALIJ K; KOBAYASHI TAKESHI; PRUSKI MAREK; HLOVA IHOR
    权利人:UNIV IOWA STATE RES FOUND INC
    摘要:In some examples, a method of forming alane (AlH3), the method comprising reacting one of: 1) a MAlH4, wherein M is an alkali metal; 2) alkali-metal hydride, MH; or 3) alkali-metal with one or more aluminum halides (AlX3, where X is a halogen), via a mechanochemical process, to form the alane, wherein the reaction is substantially solvent free and carried out in an environment with a temperature between approximately 250 K and approximately 330 K.

    专利号:US-8143462-B2
    优先权日:2007-12-17
    标题 :Processes for the synthesis of 2-chloro-1,1,1,3,3,4,4,4-heptafluoro-2-butene and hexafluoro-2-butyne
    发明人:NAPPA MARIO JOSEPH
    权利人:NAPPA MARIO JOSEPH; DU PONT
    摘要:Disclosed is a process comprising reacting CF3CCl2CF2CF3 (CFC-318ma) with hydrogen in the presence of a dehalogenation catalyst to produce CF3CClâ•?CFCF3 (CFC-1317mx). Also disclosed is a process comprising reacting CF3CClâ•?CFCF3 (CFC-1317mx) with hydrogen in the presence of a dehalogenation catalyst to produce CF3C≡CCF3 (hexafluoro-2-butyne). Hexafluoro-2-butyne can be used to produce CF3CHâ•?CHCF2CF3 (1,1,1,4,4,5,5,5-octafluoro-2-pentene).

    专利号:US-2024309128-A1
    优先权日:2023-03-13
    标 题 :Perfluoropyridine based polymers obtained via radical initiated methods
    发明人:JENNINGS ABBY R; IACONO SCOTT T; AULECIEMS ZACHARY J; LOCHMAIER EMELINE C
    权利人:US GOV AIR FORCE
    摘要:The synthesis of the fluorinated monomer, 2-((perfluoropyridin-4-yl)amino)ethyl methacrylate, and the use of the same in the preparation of fluorinated homo- and copolymers is provided. Such monomer was designed to contain a terminal methacrylate group, allowing for polymerization through free-radical techniques, both chain-growth and reversible addition-fragmentation chain-transfer methods. The monomer was designed to be compatible with other commercially available monomers and solvents to facilitate ease of copolymerization through free-radical polymerization techniques. The polymerization does not require perfluorinated alkyl substances or perfluorooctanoic acids or related compounds in the synthesis of the fluoropolymers.

    专利号:US-2023057420-A1
    优先权日:2021-08-11
    标题 :Ion exchange membrane, membrane electrode assembly, fuel cell, redox flow secondary battery, water electrolyzer, and electrolyzer for organic hydride synthesis
    发明人:YAMASHITA JUNYA
    权利人:ASAHI CHEMICAL IND
    摘要:Provided are an ion exchange membrane that has excellent mechanical strength as well as can exhibit an excellent proton conductivity over a long period, a membrane electrode assembly, a fuel cell, a redox flow secondary battery, a water electrolyzer, and an electrolyzer for organic hydride synthesis. n An ion exchange membrane containing: n an electrolyte containing a perfluorocarbon sulfonic acid polymer; and n glass fiber having a SiO 2 content of 99.9% by mass or more.
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    合成参考文献


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    摘要:USEPA/Pollution Prevention and Toxics; 2012 Chemical Data Reporting Database. Pentane, 1,1,1,2,2,3,4,5,5,5-decafluoro- (138495-42-8). Available from, as of Mar 15, 2016:
    摘要:S95 | PFASANEXCH | PFAS List from the NORMAN PFAS Analytical Exchange Activity | DOI:10.5281/zenodo.6384309
    参考文献:10.1016/j.ijpharm.2009.12.004
    摘要:Paul A, Talbot GL, Bowles JW, James J, Griffiths PC, Rogueda PG. Partitioning and phase equilibria of PEGylated excipients in fluorinated liquids. International Journal of Pharmaceutics. 2010 Mar;387(1-2):230–5. doi: 10.1016/j.ijpharm.2009.12.004.
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