CAS: 1606-67-3; Pyren-1-Amine

该化合物是一种多环芳烃衍生物,在颗粒岩芯的1位置上进行氨基替代,该化合物由于其强大的荧光特性和反应性,广泛用作荧光探测器和有机合成的中间体;其同质结构有助于材料科学的应用,特别是在开发光电子装置和传感器方面;氨基化合物可增加极溶剂的溶解性,促进进一步的功能化,使其对生物化学标签中的共价同化具有价值;高纯度确保研究和工业应用的一贯性;建议适当处理,因为它对光和空气具有潜在敏感性.

结构式图片

相似化合物

5522-43-0 14923-84-3 128008-86-6

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

CAS号5522-43-0 1-硝基芘 | CAS号129-00-0 芘 | CAS号36171-39-8 azidopyrene | CAS号1714-29-0 1-溴芘 | CAS号34244-14-9 1-氯芘 | CAS号1398531-34-4 7-(((2-hydroxyn... | CAS号22755-15-3 Acetamide, N-1-... | CAS号64-17-5 乙醇 | CAS号86674-51-3 1-Nitrosopyrene | CAS号7664-41-7 氨 | CAS号5522-43-0 1-硝基芘 | CAS号42397-65-9 1,8-二硝基芘 | CAS号42397-64-8 1,6-二硝基芘 | CAS号75321-20-9 1,3-二硝基芘 | CAS号42189-56-0 N-(1-芘基)马来酰亚胺 | CAS号22965-22-6 1-Pyrenamine, N... | CAS号22755-15-3 Acetamide, N-1-... | CAS号30269-01-3 6-nitropyren-1-amine | CAS号24722-90-5 1-芘异硫氰酸 | CAS号129944-95-2 ethyl N-(pyren-...

合成工艺路线路线简述

    芘置于palladium On Activated Charcoal,硝酸,甲酸铵,乙酸酐体系中,用 甲醇 用作溶剂,化学反应 15.0H,反应生成1-氨基芘
    参考文献:Tunable Star-Shaped Triphenylamine Fluorophores For Fluorescence Quenching Detection And Identification Of Nitro-Aromatic Explosives
    标题:Tunable Star-Shaped Triphenylamine Fluorophores For Fluorescence Quenching Detection And Identification Of Nitro-Aromatic Explosives
    摘要:含有芘或芫荽烯的三苯胺基荧光团对硝基炸药显示出不同的荧光淬灭灵敏度.最灵敏的荧光团能够检测到 Ng Cm-2 级的 Tnt;该阵列可用于识别硝基芳烃.
    Doi:10.1039/c2Cc34008A

    海关参考信息

    专利信息


    专利号:US-4801744-A
    优先权日:1985-03-01
    标 题 :Catalytic synthesis of urea from carbon monoxide and amine compound
    发明人:HERMAN JEAN-JACQUES; LECLOUX ANDRE
    权利人:SOLVAY
    摘要:Process for the catalytic synthesis of nitrogen-containing organic compounds, comprising the reaction of carbon monoxide with at least one amino compound in a reaction mixture containing a catalyst based on selenium and a substituted pyridine. The process is particularly suitable for the synthesis of ureas and of their polymers.

    专利号:US-5965746-A
    优先权日:1997-06-02
    标题:Efficient method for the synthesis of N-cyclic maleamic acids and N-cyclic maleimides
    发明人:FUJITA SATOSHI; REDDY PAIDI YELLA; TORU TAKESHI
    权利人:AISIN SEIKI
    摘要:Provided are methods for the synthesis of N-cyclic maleamic acids and N-cyclic maleimide derivatives, as well as N-cyclic maleamic acids and N-cyclic maleimides synthesized thereby. The method for synthesis of an N-cyclic maleamic acid involves reacting an amino group-containing N-cyclic compound with maleic anhydride in acetic acid to obtain an N-cyclic maleamic acid. An N-cyclic maleimide can be formed by adding hexamethyldisilazane to an N-cyclic maleamic acid prepared according to the above-described method, thereby cyclizing a maleamic acid site of the N-cyclic maleamic acid. The described methods allow for the products to be obtained at high yields.

    专利号:WO-2008127396-A2
    优先权日:2006-11-02
    标 题 :A solution synthesis of carbon nanotube/metal-containing nanoparticle conjugated assemblies

    专利号:US-7973158-B2
    优先权日:2006-11-29
    标 题 :Method of preparing benzoxazines
    发明人:TADEN ANDREAS J; LIU PUWEI; WONG ALEX C; PARKER ERIC A
    权利人:HENKEL CORP; HENKEL AG & CO KGAA
    摘要:This invention relates to a novel synthesis for the preparation of benzoxazine components from phenolic components, aldehyde components, and amine components in a solvent other than toluene.

    专利号:CN-109280011-A
    优先权日:2018-09-30
    标题 :Synthesis of OLED Intermediate 2-Bromopyrene

    专利号:EP-4234771-A2
    优先权日:2020-12-09
    标 题:Device and method for continuous synthesis of graphene
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    主要参考文献

    [参考文献]: Alison E Mahan, Et Al. A Method For High-Throughput, Sensitive Analysis Of Igg Fc And Fab Glycosylation By Capillary Electrophoresis. J Immunol Methods. 2015 Feb:417:34-44.
    [参考文献]: B Mao, Et Al. Solution Conformation Of The N-(Deoxyguanosin-8-Yl)-1-Aminopyrene ([参考文献]: Bert Willis, Et Al. Triple Recognition Of B-Dna. Bioorg Med Chem Lett. 2009 Sep 1;19(17):4974-9.
    [参考文献]: Johan Vrevik, Et Al. Differential Chemokine Induction By 1-Nitropyrene And 1-Aminopyrene In Bronchial Epithelial Cells: Importance Of The Tace/tgf-α/egfr-Pathway. Environ Toxicol Pharmacol. 2013 Mar;35(2):235-9.
    [参考文献]: John C Bachman, Et Al. Electrochemical Polymerization Of Pyrene Derivatives On Functionalized Carbon Nanotubes For Pseudocapacitive Electrodes. Nat Commun. 2015 May 6:6:7040.

    合成参考文献


    摘要:Liang, Y.; Wen, Z.; Cabrera, M.; Howlader, A. H.; Wnuk, S. F., Science of Synthesis Knowledge Updates, (2020) 1, 305.
    参考文献:10.1016/s1383-5718(01)00254-6
    摘要:Hatanaka N, Yamazaki H, Oda Y, Guengerich FP, Nakajima M, Yokoi T. Metabolic activation of carcinogenic 1-nitropyrene by human cytochrome P450 1B1 in Salmonella typhimurium strain expressing an O-acetyltransferase in SOS/umu assay. Mutation Research/Genetic Toxicology and Environmental Mutagenesis. 2001 Oct;497(1-2):223–33. doi: 10.1016/s1383-5718(01)00254-6.
    参考文献:10.1080/10934529.2013.729998
    摘要:Fullove TP, Johnson B, Yu H. Structure-dependent lipid peroxidation by photoirradiation of pyrene and its mono-substituted derivatives. Journal of Environmental Science and Health, Part A. 2013 Feb;48(3):233–41. doi: 10.1080/10934529.2013.729998.
    参考文献:10.1016/0378-4274(94)90028-0
    摘要:Scheepers PT, Thuis HJ, Martens MH, Bos RP. Assessment of occupational exposure to diesel exhaust. The use of an immunoassay for the determination of urinary metabolites of nitroarenes and polycyclic aromatic hydrocarbons. Toxicol Lett. 1994 Jun;72(1-3):191–8. doi: 10.1016/0378-4274(94)90028-0.
    参考文献:10.1155/2007/71943
    摘要:Stockwell PB. Abstracts of Papers Presented at the 2007 Pittsburgh Conference. Journal of Automated Methods and Management in Chemistry. 2007;2007():1–85. doi: 10.1155/2007/71943.
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