CAS: 18666-68-7; Triphenylvinylsilane

该化合物是一种有机硅化合物,其特征是附于硅原子的乙烯基化合物,该化合物进一步粘合在三个苯基组之间,该化合物一般看起来无色可粉黄色液体或固体,视其纯度和温度而定,以其稳定性和相对低的活性而闻名,使其在各种化学应用中有用,包括作为有机合成和材料科学的前体.三苯基乙烯硅烷可以参与流水等反应,并可作为更为复杂的硅衍生物的建筑块.其独特的结构允许具有有趣的电子和光学特性,可用于开发先进的材料,例如聚合物和涂层.此外,由于该氯基化合物的存在,它可以发生聚合反应,有助于建立功能化的硅氧网络.在处理这一化合物时,应当注意安全防范,因为可能具有刺激性,因此许多有机硅化合物.

结构式图片

欧盟法规

ECHA物质C&L通报REACH预注册

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CAS号75-94-5 乙烯基三氯硅烷 | CAS号591-51-5 苯基锂 | CAS号593-66-8 碘乙烯 | CAS号789-25-3 三苯基硅烷 | CAS号6229-00-1 三苯基硅乙炔 | CAS号58617-51-9 dimethyl-(2-tri... | CAS号24379-30-4 4-methyl-N'-(1-... | CAS号4916-42-1 Acetyltriphenyl... | CAS号76-86-8 三苯基氯硅烷 | CAS号1826-67-1 乙烯基溴化镁 | CAS号18676-45-4 1-bromoethenyl-... | CAS号27644-07-1 2,6-dimethyldod... | CAS号1730-67-2 2-triphenylsily... | CAS号2117-32-0 butyl(triphenyl... | CAS号76734-21-9 diphenyl(2-trip... | CAS号66303-55-7 2-phenylsulfany... | CAS号804-83-1 triphenyl(1-phe... | CAS号61979-36-0 1,2-dibromoethy... | CAS号52629-60-4 1-phenyl-2-trip...

合成工艺路线路线简述

    Dimethyl-(2-Triphenylsilanyl-Ethyl)-Amine置于邻溴氟苯,正丁基锂体系中,用 乙醚 用作溶剂,化学反应生成乙烯基三苯基硅烷
    参考文献:Reaction Of N,N-Dimethyl-2-Triorganosilylethylamines With Benzyne
    标题:Reaction Of N,N-Dimethyl-2-Triorganosilylethylamines With Benzyne
    摘要:
    Doi:10.1021/jo00873A015

    海关参考信息

    专利信息


    专利号:CN-1384123-A
    优先权日:2001-03-26
    标 题 :Synthesis of polymer and film of the polymer

    专利号:US-11767388-B1
    优先权日:2019-09-18
    标 题 :Silicon-functionalized rubber
    发明人:ENSIGN SETH CODY; VIELHABER MARGARET FLOOK; JOHNGRASS JENA LYNN; MA LIQING
    权利人:GOODYEAR TIRE & RUBBER
    摘要:The compatibility between silica fillers and synthetic rubbers which are synthesized utilizing lanthanide-based catalyst systems, such as neodymium catalyst systems can be improved by terminating the polymerization with a vinyl silane terminating agent. In doing so the vinyl silane is allowed to react with the polymer chain ends of the neodymium rubber to functionalize the chain ends of the polymer chains with silicon containing groups. This results in the rubber having better characteristics for utilization in tire rubber formulations, such a tire tread formulations, that exhibit improved wear characteristics and lower rolling resistance. The process for the synthesis of such functionalized polydiene rubber comprises (1) polymerizing a diene monomer in the presence of a lanthanide-based catalyst system, and (2) terminating the polymerization with a vinyl silane terminator. The functionalized polydiene rubber composition made by this method is comprised of a polydiene rubber which is functionalized at its chain ends with a silicon containing group.

    专利号:CN-112409118-A
    优先权日:2020-11-20
    标 题:A kind of method for electrochemical synthesis of trans-4-(trans-4'-alkylcyclohexyl)cyclohexylene liquid crystal monomer

    专利号:US-6787601-B2
    优先权日:2001-03-26
    标题 :Polymer synthesis
    发明人:LAMOLA ANGELO A; BLANKENSHIP ROBERT M
    权利人:SHIPLEY CO LLC
    摘要:Disclosed is a method of preparing emulsion polymers and a method of preparing porous dielectric materials using the emulsion polymers.

    专利号:US-6903175-B2
    优先权日:2001-03-26
    标 题 :Polymer synthesis and films therefrom
    发明人:GORE ROBERT H; GALLAGHER MICHAEL K; YOU YUJIAN
    权利人:SHIPLEY CO LLC
    摘要:Disclosed are methods of preparing solution polymers and compositions derived therefrom.

    专利号:US-4668809-A
    优先权日:1982-05-03
    标 题 :Transition metal complex catalysts
    发明人:OSWALD ALEXIS A; JERMASEN TORRIS G; WESTNER ANDREW A; HUANG I-DER
    权利人:EXXON RESEARCH ENGINEERING CO
    摘要:Compositions of matter are disclosed which are highly useful in hydroformylation processes. The compositions are non-charged, non-chelated bis- and tris-(alkyl diaryl phosphine) rhodium carbonyl hydrides. The substituents of the alkyl group includes heteroorganic radicals containing ether, ester, keto and hydroxy oxygen, phosphine oxide and phosphorus ester phosphorus, amine, amide, amine oxide and heterocyclic nitrogen groups. These compositions are highly stable and selective catalysts for the hydroformylation of olefins under certain conditions. The disclosed catalyst systems contain a large excess of phosphine ligand and employ alpha-olefin plus synthesis gas reactant mixtures having a high H2/CO ratio at relatively low pressures. They produce moslty aldehydes derived from terminal attack on the alpha-olefin reactant. In the case of low olefins, such as butene-1, the products can be advantageously removed in a continuous manner, as distillate components from a ligand reaction mixture kept at an elevated temperature and continuously fed by an appropriate mixture of the reactants.
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    合成参考文献


    摘要:Wirth, T.; Singh, F. V., Science of Synthesis Knowledge Updates, (2017) 1, 422.
    摘要:Zhu, S., Science of Synthesis: Special Topics, (2022) 1, 517.
    摘要:Sanz, R.; Su, Science of Synthesis: Knowledge Updates, (2024) 1, 105.
    摘要:Yang, Y.; Wang, C., Science of Synthesis: Base-Metal Catalysis, (2023) 2, 712.
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