CAS: 217479-60-2; 2,4,6-Trichlorobenzyl Alcohol

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CAS号50-43-1 2,4,6-三氯苯甲酸 | CAS号23749-65-7 1,3,5-trichloro... | CAS号17293-03-7 1,3,5-三氯-2-(氯甲基)苯 | CAS号24473-00-5 2,4,6-三氯苯甲醛

2,4,6-Trichlorobenzyl Bromide置于sodium Hydroxide体系中,用 乙醇,水,乙腈 用作溶剂,化学反应 13.0H,反应生成2,4,6-三氯苯甲醇
参考文献:Banfi,Stefano; Cavazzini,Marco; Pozzi,Gianluca,Journal Of The Chemical Society. Perkin Transactions 2 (2001),2000,# 4,P. 871-877
标题:Banfi,Stefano; Cavazzini,Marco; Pozzi,Gianluca,Journal Of The Chemical Society. Perkin Transactions 2 (2001),2000,# 4,P. 871-877

专利信息

专利号:US-5519128-A
优先权日:1993-03-31
标题:Process for the synthesis of acylated derivatives of fatty acid-transporting thiols and in particular acyl-coenzymes A and the thus obtained acyl-coenzymes A
发明人：LELLOUCHE JEAN-PAUL; LEVANNIER KARINE; MIOSKOWSKI CHARLES
权利人:COMMISSARIAT ENERGIE ATOMIQUE
摘要:The invention relates to a process for the synthesis of an acylated derivative of a fatty acid-transporting thiol such as the coenzyme A. According to this process, a silylated or stannylated thiol is prepared by reacting the thiol with a silylation or stannylation reagent in order to at least partly replace the unstable hydrogens of the thiol by SiR3 or SnR3 groups with R being an alkyl or aryl group. The silylated or stannylated thiol is then reacted in an anhydrous organic medium with an activated organic acid and a deprotection reagent able to eliminate the silyl or stannyl groups. In this way it is possible to obtain acylated derivatives of the coenzyme A, in which the acyl group can have up to 30 carbon atoms with high yields.

专利号:FR-2703356-A1
优先权日:1993-03-31
标 题 :Process for the synthesis of acycled derivatives of thiols transporting fatty acids, in particular acyl-coenzymes A, and the acyl-coenzymes A thus obtained.

专利号:US-5424415-A
优先权日:1993-03-31
标题:Process for the synthesis of acylated derivatives of fatty acid-transporting thiols and in particular acyl-coenzymes A and the thus obtained acyl-coenzymes A