CAS: 53348-05-3; 3,6-Dibromophenanthrene-9,10-Dione

上下游产品

CAS号84-11-7 菲醌 | CAS号85-01-8 菲 | CAS号13974-99-7 5,5'-Dibromodip... | CAS号216312-73-1 3,6-二溴芴酮

菲置于potassium Dichromate,硫酸,溴,过氧化苯甲酰体系中,用 水,硝基苯 作为反应溶剂,化学反应 1.0H,反应生成 3,6-二溴菲醌
参考文献:使用二苯乙烯光环化脱氢的改进方案快速合成螺旋
标题:使用二苯乙烯光环化脱氢的改进方案快速合成螺旋
摘要:已开发出一种用于合成菲和螺旋烯的二苯乙烯光脱氢环化的改进程序.该过程涉及使用 Thf 作为碘介导的光脱氢环化过程中产生的氢碘酸的清除剂.由于与环氧丙烷相比,Thf的沸点更高,成本更低且易于获得,因此使用thf是有利的.该方法用于合成多种菲和螺旋.
DOI:10.3998/ark.5550190.0012.902

专利信息

专利号:EP-4471014-A1
优先权日:2023-05-29
标 题 :Derivate of quinoxaline with thermally activated delayed fluorescence
发明人：SERDIUK ILLIA; MONKA MICHAL; GRZYWACZ DARIA
权利人:UNIV GDANSKI
摘要:The invention relates to the triarylamine derivatives of quinoxaline with thermally activated delayed fluorescence (TADF) bearing heavy atoms and methods of their synthesis. The emitters are characterized by spectral and photophysical properties with improved TADF parameters as compared to their analogues reported before. The disclosed emitters can convert triplet excitons into singlet ones faster and with higher efficiency. The emitters cover orange, red, and/or near infrared (NIR) spectral ranges. Furthermore, the mixtures of new emitters with fluorescent dopants exhibit narrowband NIR emission preserving fast triplet-singlet exciton conversion.The invention concerns functional organic materials which exhibit TADF and can be potentially used for the electroluminescence applications, e.g. in organic light emitting diodes (OLED), and/or applications of materials with long-lived excited states, e.g. photosensibilization, photocatalysis, and/or other fields where excited triplet states or excitons play important role.

专利号:WO-2022052135-A1
优先权日:2020-09-14
标 题 :Chiral thermally activated delayed fluorescence material and preparation method therefor
发明人：TANG JIANXIN; XIE FENGMING; LI YANQING; ZHOU JINGXIONG; ZENG XINYI
权利人:UNIV SOOCHOW
摘要:The present invention relates to a chiral thermally activated delayed fluorescence (TADF) material and a preparation method therefor. The chiral TADF material is R/S-18,21-bis(10H-phenoxazine-10-yl)-3,4,5,6,7,8,9,10-octahydrodibenz[a,c]dinaphtho[2',1':5,6;1',2':7,8][1,4]dioxin[2,3-i]phenazine or R/S-16,17-bis(4-(10H-phenoxazine-10-yl)phenyl)-3,4,5,6,7,8,9,10-octahydrodinaphtho[2',1':5,6;1',2':7,8][1,4]dioxane[2,3-g]quinoxaline. The provided compound has the characteristics of rigid large-plane twisted structure and significant intramolecular charge transfer (ICT) effect, and has the typical advantages such as TADF property, circular polarization (CPL) property, high photoluminescence quantum yield (PLQY), and good thermal stability. Moreover, the chiral TADF material has few synthesis and preparation steps, readily available raw materials, simple synthesis and purification processes, and high yield, and can be synthesized and prepared on a large scale.

专利号:CN-116283721-A
优先权日:2023-01-05
标题:Simultaneously generate two kinds of active oxygen near-infrared photosensitizer and its synthesis method and application