5-乙基-2-甲基-吡啶置于cerium(Iv) Oxide,二氧化碳体系中,化学反应生成2-甲基-5-乙烯基吡啶 参考文献:Process Of Making 2-Methyl-5-Vinyl Pyridine 标题:Process Of Making 2-Methyl-5-Vinyl Pyridine
专利号:US-8703952-B2 优先权日:2008-12-12 标题:Synthesis of 9-(arylalkyl)-1,2,3,4-tetrahydro-γ-carboline and analogues and intermediates 发明人:WILLIAMSON CRAIG; STOREY JOHN MERVYN DAVID 权利人:WILLIAMSON CRAIG; STOREY JOHN MERVYN DAVID; WISTA LAB LTD 摘要:The present invention pertains generally to methods of preparing certain 9-(arylalkyl)-1,2,3,4-tetrahydro-γ-carboline compounds and their analogues, and especially to methods of preparing dimebon. The present invention also pertains to methods of preparing certain intermediate compounds which find use in the synthesis of the 9-(arylalkyl)-1,2,3,4-tetrahydro-γ-carboline compounds.
专利号:US-6610802-B2 优先权日:2001-05-29 标题 :Process for synthesis of polymer compositions, polymer compositionS obtainable by the process, and use of the same 发明人:ROOS SEBASTIAN; EISENBERG BORIS; HARPE CAROLIN 权利人:ROHMAX ADDITIVES GMBH 摘要:The present invention relates to a process for synthesis of polymer compositions with reduced catalyst content, wherein ethylenically unsaturated monomers containing less than 0.5 wt % of ethylenically unsaturated monomers with at least one carboxylic group, sulfonic acid group and/or at least one phosphonic acid group relative to the total weight of the ethylenically unsaturated monomers are polymerized by means of initiators containing a transferable group of atoms and of one or more catalysts comprising at least one transition metal in the presence of ligands which can form a coordination compound with the metal catalyst or catalysts and, after the polymerization, the catalyst contained in the polymer is at least partly separated. For this purpose, the polymer composition is filtered, after the polymerization, in the presence of at least one filter aid which contains at least 0.5 wt %, relative to the total weight of the filter aid, of repeating units that contain at least one carboxylic acid group, sulfonic acid group and/or at least one phosphonic acid group.
专利号:US-6610801-B1 优先权日:2000-11-13 标题:Processes for synthesis of polymer compositions 发明人:SCHERER MARKUS 权利人:ROHMAX ADDITIVES GMBH 摘要:The present invention relates to processes for synthesis of poly(meth)acrylate compositions, wherein ethylenically unsaturated monomers are transformed to polymers by means of initiators containing a transferable group of atoms and of one or more catalysts comprising at least one transition metal in the presence of ligands which can form a coordination compound with the metal catalyst or catalysts, wherein ethylenically unsaturated monomers containing 50 to 100 wt %, relative to the total weight of ethylenically unsaturated monomers, of (meth)acrylates of formula (I) are polymerizedwherein R denotes hydrogen or methyl, R1 denotes a straight-chain or branched alkyl group with 8 to 40, carbon atoms, R2 and R3 independently denote hydrogen or a group of the formula -COOR1, wherein R' denotes hydrogen or a straight-chain or branched alkyl group with 8 to 40, carbon atoms, in the presence of copper, the total concentration of copper of oxidation numbers (I) and (II) in the polymerization composition being <=200 ppm relative to the total weight of the composition.
专利号:US-6639029-B1 优先权日:2000-11-13 标 题 :Process for continuous synthesis of polymer compositions as well as use of same 发明人:SCHERER MARKUS; BOLLINGER JOSEPH MARTIN; COOPER JR DAVID J; TILLERY LARRY STEPHEN; WOODRUFF ROBERT 权利人:ROHMAX ADDITIVES GMBH 摘要:The present invention relates to a process for synthesis of polymer compositions, wherein ethylenically unsaturated monomers are polymerized by means of initiators containing a transferable atom or group of atoms and of one or more catalysts comprising at least one transition metal in the presence of ligands which can form a coordination compound with the metal catalyst or catalysts, the process being characterized in that the polymerization takes place by means of continuous process operation.
专利号:US-6689844-B2 优先权日:2001-05-29 标题 :Process for synthesis of polymer compositions with reduced halogen content, polymer composition with reduced halogen content as well as use of this composition 发明人:ROOS SEBASTIAN; BOLLINGER JOSEPH MARTIN; SCHERER MARKUS 权利人:ROHMAX ADDITIVES GMBH 摘要:Polymer compositions with reduced living halogen content are used as additive to lubricating oils and are prepared by polymerizing at least one ethylenically unsaturated monomer using a) at least one initiator containing a transferable halogen and b) one or more metal catalysts containing at least one transition metal, in the presence of ligands which can form a coordination compound with the one or more metal catalysts, to obtain a polymer composition having a living halogen content, and after the polymerizing, reacting the polymer composition having a living halogen content with at least one organic nitrogen compound in the presence of a nonpolar solvent, thereby reducing the living halogen content to obtain the polymer composition having a reduced halogen content.
专利号:US-8426497-B2 优先权日:2008-04-01 标题 :Synthesis of improved binders and modified tacticity 发明人:SCHWIND HELMUT; WIESLER UWE-MARTIN; BORGMANN CORNELIA; LEUNINGER HEIKE; SCHMIED THOMAS; MAUS STEFANIE; FRIEDRICH WERNER; BALK SVEN 权利人:SCHWIND HELMUT; WIESLER UWE-MARTIN; BORGMANN CORNELIA; LEUNINGER HEIKE; SCHMIED THOMAS; MAUS STEFANIE; FRIEDRICH WERNER; BALK SVEN; EVONIK ROEHM GMBH 摘要:The invention relates to a process for preparing polymers for coating applications by polymerizing esters of acrylic acid or of methacrylic acid or vinyl aromatics or other free-radically polymerizable vinyl compounds or monomer mixtures composed predominantly of such monomers by means of a continuous polymerization process. In particular, the invention relates to a solvent-free preparation process for polymers, through which the binder can be prepared for coating applications with superior processing properties, very good thermal stability, improved pigment wetting and a higher gloss.
参考标题:Facile Atom-Economic Synthesis Of Ammonium Diselenophosphinates Via Three-Component Reaction Of Secondary Phosphines, Elemental Selenium, And Ammonia 作者:Boris Trofimov,Alexander Artem'Ev,Svetlana Malysheva,Nina Gusarova,Nataliya Belogorlova |发布日期:2010.6 摘要:The Three-Component Reaction Between Secondary Phosphines, R2Ph [r = Ph(Ch2)2, Phchmech2, Phch2Chme, 4-T-Buc6H4(Ch2)2, 4-Meoc6H4(Ch2)2, 2-Furyl(Ch2)2, 4-Pyridyl(Ch2)2, 6-Me-3-Pyridyl(Ch2)2, Ph], Elemental Selenium, And Ammonia Proceeds Under Mild Conditions (Etoh-H2O, 53-55 ëc Or Etoh, R.T., 10 Min) Without The Formation Of Byproducts To Give The First Representatives Of Ammonium Diselenophosphinates In High Yields (Up To 96%).
合成参考文献
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