CAS: 140-76-1; 2-Methyl-5-Vinylpyridine

该化合物是多用途的七环环化合物,在5位置用苯乙烯组取代五位置的丙烯核心,在2位置用甲基组取代.这一结构赋予适合有机合成应用的回活动,特别是作为制药,农用化学和特殊材料的一个构件.该化合物的同质系统和富电子的丙烯酯环增强了其在协调化学和催化方面的效用.在标准条件下和与各种反应条件相容的稳定性使得它成为功能化和衍生的有价值的中间体. 电子和甲基组的存在都提供了选择性的修改途径,使得复杂的分子结构能够有针对性地合成.

结构式图片

相似化合物

1121-55-7 3883-39-4 1220279-77-5

欧盟法规

REACH注册ECHA物质C&L通报REACH预注册

上下游产品

CAS号3430-13-5 5-溴-2-甲基吡啶 | CAS号7486-35-3 三丁基乙烯基锡 | CAS号53014-84-9 5-甲酰基-2-甲基吡啶 | CAS号1779-49-3 甲基三苯基溴化膦 | CAS号104-90-5 2-甲基-5-乙基吡啶 | CAS号3613-73-8 2,3,4,5-四氢-2,8-... | CAS号3222-47-7 6-甲基烟酸 | CAS号53014-84-9 5-甲酰基-2-甲基吡啶 | CAS号21241-10-1 [2-acetyloxy-2-... | CAS号6960-22-1 6-甲基烟酰胺 | CAS号102207-58-9 2-ethyl-8-methy... | CAS号100189-17-1 6-甲基-3-吡啶乙醇 | CAS号104-90-5 2-甲基-5-乙基吡啶 | CAS号56019-64-8 1-(6-甲基吡啶-3-基)乙醇 | CAS号100-26-5 吡啶-2,5-二羧酸

合成工艺路线路线简述

    5-乙基-2-甲基-吡啶置于cerium(Iv) Oxide,二氧化碳体系中,化学反应生成2-甲基-5-乙烯基吡啶
    参考文献:Process Of Making 2-Methyl-5-Vinyl Pyridine
    标题:Process Of Making 2-Methyl-5-Vinyl Pyridine

    海关参考信息

    专利信息


    专利号:US-8703952-B2
    优先权日:2008-12-12
    标题:Synthesis of 9-(arylalkyl)-1,2,3,4-tetrahydro-γ-carboline and analogues and intermediates
    发明人:WILLIAMSON CRAIG; STOREY JOHN MERVYN DAVID
    权利人:WILLIAMSON CRAIG; STOREY JOHN MERVYN DAVID; WISTA LAB LTD
    摘要:The present invention pertains generally to methods of preparing certain 9-(arylalkyl)-1,2,3,4-tetrahydro-γ-carboline compounds and their analogues, and especially to methods of preparing dimebon. The present invention also pertains to methods of preparing certain intermediate compounds which find use in the synthesis of the 9-(arylalkyl)-1,2,3,4-tetrahydro-γ-carboline compounds.

    专利号:US-6610802-B2
    优先权日:2001-05-29
    标题 :Process for synthesis of polymer compositions, polymer compositionS obtainable by the process, and use of the same
    发明人:ROOS SEBASTIAN; EISENBERG BORIS; HARPE CAROLIN
    权利人:ROHMAX ADDITIVES GMBH
    摘要:The present invention relates to a process for synthesis of polymer compositions with reduced catalyst content, wherein ethylenically unsaturated monomers containing less than 0.5 wt % of ethylenically unsaturated monomers with at least one carboxylic group, sulfonic acid group and/or at least one phosphonic acid group relative to the total weight of the ethylenically unsaturated monomers are polymerized by means of initiators containing a transferable group of atoms and of one or more catalysts comprising at least one transition metal in the presence of ligands which can form a coordination compound with the metal catalyst or catalysts and, after the polymerization, the catalyst contained in the polymer is at least partly separated. For this purpose, the polymer composition is filtered, after the polymerization, in the presence of at least one filter aid which contains at least 0.5 wt %, relative to the total weight of the filter aid, of repeating units that contain at least one carboxylic acid group, sulfonic acid group and/or at least one phosphonic acid group.

    专利号:US-6610801-B1
    优先权日:2000-11-13
    标题:Processes for synthesis of polymer compositions
    发明人:SCHERER MARKUS
    权利人:ROHMAX ADDITIVES GMBH
    摘要:The present invention relates to processes for synthesis of poly(meth)acrylate compositions, wherein ethylenically unsaturated monomers are transformed to polymers by means of initiators containing a transferable group of atoms and of one or more catalysts comprising at least one transition metal in the presence of ligands which can form a coordination compound with the metal catalyst or catalysts, wherein ethylenically unsaturated monomers containing 50 to 100 wt %, relative to the total weight of ethylenically unsaturated monomers, of (meth)acrylates of formula (I) are polymerizedwherein R denotes hydrogen or methyl, R1 denotes a straight-chain or branched alkyl group with 8 to 40, carbon atoms, R2 and R3 independently denote hydrogen or a group of the formula -COOR1, wherein R' denotes hydrogen or a straight-chain or branched alkyl group with 8 to 40, carbon atoms, in the presence of copper, the total concentration of copper of oxidation numbers (I) and (II) in the polymerization composition being <=200 ppm relative to the total weight of the composition.

    专利号:US-6639029-B1
    优先权日:2000-11-13
    标 题 :Process for continuous synthesis of polymer compositions as well as use of same
    发明人:SCHERER MARKUS; BOLLINGER JOSEPH MARTIN; COOPER JR DAVID J; TILLERY LARRY STEPHEN; WOODRUFF ROBERT
    权利人:ROHMAX ADDITIVES GMBH
    摘要:The present invention relates to a process for synthesis of polymer compositions, wherein ethylenically unsaturated monomers are polymerized by means of initiators containing a transferable atom or group of atoms and of one or more catalysts comprising at least one transition metal in the presence of ligands which can form a coordination compound with the metal catalyst or catalysts, the process being characterized in that the polymerization takes place by means of continuous process operation.

    专利号:US-6689844-B2
    优先权日:2001-05-29
    标题 :Process for synthesis of polymer compositions with reduced halogen content, polymer composition with reduced halogen content as well as use of this composition
    发明人:ROOS SEBASTIAN; BOLLINGER JOSEPH MARTIN; SCHERER MARKUS
    权利人:ROHMAX ADDITIVES GMBH
    摘要:Polymer compositions with reduced living halogen content are used as additive to lubricating oils and are prepared by polymerizing at least one ethylenically unsaturated monomer using a) at least one initiator containing a transferable halogen and b) one or more metal catalysts containing at least one transition metal, in the presence of ligands which can form a coordination compound with the one or more metal catalysts, to obtain a polymer composition having a living halogen content, and after the polymerizing, reacting the polymer composition having a living halogen content with at least one organic nitrogen compound in the presence of a nonpolar solvent, thereby reducing the living halogen content to obtain the polymer composition having a reduced halogen content.

    专利号:US-8426497-B2
    优先权日:2008-04-01
    标题 :Synthesis of improved binders and modified tacticity
    发明人:SCHWIND HELMUT; WIESLER UWE-MARTIN; BORGMANN CORNELIA; LEUNINGER HEIKE; SCHMIED THOMAS; MAUS STEFANIE; FRIEDRICH WERNER; BALK SVEN
    权利人:SCHWIND HELMUT; WIESLER UWE-MARTIN; BORGMANN CORNELIA; LEUNINGER HEIKE; SCHMIED THOMAS; MAUS STEFANIE; FRIEDRICH WERNER; BALK SVEN; EVONIK ROEHM GMBH
    摘要:The invention relates to a process for preparing polymers for coating applications by polymerizing esters of acrylic acid or of methacrylic acid or vinyl aromatics or other free-radically polymerizable vinyl compounds or monomer mixtures composed predominantly of such monomers by means of a continuous polymerization process. In particular, the invention relates to a solvent-free preparation process for polymers, through which the binder can be prepared for coating applications with superior processing properties, very good thermal stability, improved pigment wetting and a higher gloss.
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    主要参考文献

    参考标题:Facile Atom-Economic Synthesis Of Ammonium Diselenophosphinates Via Three-Component Reaction Of Secondary Phosphines, Elemental Selenium, And Ammonia
    作者:Boris Trofimov,Alexander Artem'Ev,Svetlana Malysheva,Nina Gusarova,Nataliya Belogorlova |发布日期:2010.6
    摘要:The Three-Component Reaction Between Secondary Phosphines, R2Ph [r = Ph(Ch2)2, Phchmech2, Phch2Chme, 4-T-Buc6H4(Ch2)2, 4-Meoc6H4(Ch2)2, 2-Furyl(Ch2)2, 4-Pyridyl(Ch2)2, 6-Me-3-Pyridyl(Ch2)2, Ph], Elemental Selenium, And Ammonia Proceeds Under Mild Conditions (Etoh-H2O, 53-55 ëšc Or Etoh, R.T., 10 Min) Without The Formation Of Byproducts To Give The First Representatives Of Ammonium Diselenophosphinates In High Yields (Up To 96%).

    合成参考文献


    摘要:Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure, Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982, -(88), 1982
    摘要:Gigiena i Sanitariya. For English translation, see HYSAAV., 39(4)(86), 1974
    摘要:International Labour Office. Encyclopedia of Occupational Health and Safety. Vols. I&II. Geneva, Switzerland: International Labour Office, 1983., p. 1810
    摘要:Kirk-Othmer Encyclopedia of Chemical Technology. 3rd ed., Volumes 1-26. New York, NY: John Wiley and Sons, 1978-1984., p. 19(81) 454
    摘要:Nikifirova AA, Taskaev II; Reakt Plast Epiteliya Soedin Tkani Norm Eksp Patol Usloviyakh, Dokl Mezhvuz Gistol Konf: 196-9 (1974)
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