CAS: 4169-04-4; 2-Phenoxypropanol

上下游产品

CAS号940-31-8 2-苯氧基丙酸 | CAS号75-56-9 环氧丙烷 | CAS号108-95-2 苯酚 | CAS号42412-84-0 ethyl 2-phenoxy... | CAS号29279-27-4 t-butyl 2-pheno... | CAS号1129-46-0 (R)-2-苯氧基丙酸 | CAS号18099-45-1 diborane(4) | CAS号57-55-6 丙二醇 | CAS号108-94-1 环己酮 | CAS号28899-97-0 bis(acetato-O)t... | CAS号69333-61-5 4-methylbenzene... | CAS号61687-10-3 methanesulfonic...

2-Phenoxy-Propionic Acid-(N-Methyl-Anilide)置于c44H50N2P2Ru,Potassium Tert-Butylate,氢气体系中,用 四氢呋喃 作为反应溶剂,22.0 °C,405.33 Kpa 条件下,反应生成 2-苯氧基丙醇
参考文献:Catalysts And Processes For The Hydrogenation Of Amides
标题:Catalysts And Processes For The Hydrogenation Of Amides
摘要:提供了一种过程,用于在存在或不存在碱的条件下,将化合物与氢气和过渡金属催化剂接触,以还原一个或多个酰胺基团.目前描述的这些过程可以在低催化剂负载下进行,使用相对温和的温度和压力,并且可以选择在存在或不存在碱或高催化剂负载下使用低温和低压以及高负载碱的条件下,实现不对映体酰胺的动态动力学分辨.

专利信息

专利号:US-5110961-A
优先权日:1989-12-21
标 题:Catalytic process for the synthesis of an alcohol, new metal complexes and process for the synthesis of these complexes
发明人：LECOLIER SERGE; MORTREUX ANDRE; PETIT FRANCIS; SAMAIN HENRI
权利人:POUDRES & EXPLOSIFS STE NALE
摘要:The invention relates to a catalytic process for the synthesis of an alcohol by reaction of an epoxide with a nucleophilic compound containing a labile hydrogen, such as an alcohol, a phenol, a primary amine or a carboxylic acid. n The catalyst is a metal complex of general formula (I) n [M[Co(CO) 4 ] 2 ] x in which x is equal to 1 or 2 and M denotes tin, lead and cadmium. n The reaction preferably takes place in the presence of carbon monoxide. n This process makes it possible to increase the yield and the selectivity of the reaction and the stereoselectivity for alcohol in the case of which the hydroxyl formed is attached to the least hindered carbon atom of the epoxide. n The invention also relates to the new complexes of formula (I) in which x equals 2. n It also relates to a process for the electrosynthesis of these new compounds by electroreduction of Co 2 (CO) 8 in an organic solvent medium in a cell in which the anode consists of the metal M, followed by isolation of the complex, the temperature of the reaction mixture and that at which the complex is isolated being lower than 25° C.

专利号:US-7015344-B2
优先权日:2004-06-29
标题 :Synthesis of organometallic cyclometallated group viiib metal complexes
发明人：DEATON JOSEPH C
权利人:EASTMAN KODAK CO
摘要:A process for forming an organometallic cyclometallated Group viiib metal complex comprises reacting a Group viiib metal compound with a heterocyclic compound capable of forming an organometallic cyclometallated complex in the presence of a solvent comprising an aromatic oxygen containing compound.

专利号:US-4123465-A
优先权日:1975-10-16
标 题 :Chiral tertiary phosphines
发明人：VALENTINE JR DONALD H
权利人:HOFFMANN LA ROCHE
摘要:A method for the homogeneous catalytic enantioselective hydrogenation of alkyl and alkenyl substituted acrylic acids wherein these acids are selectively hydrogenated at the double bond alpha,beta to the acid function, said hydrogenations are catalyzed by rhodium complexes of chiral tertiary phosphines. This method provides a route to chiral dihydrogeranic acid and other intermediates useful in the synthesis of chiral vitamin E, citronellal, and menthol. Novel chiral tertiary phosphines are also disclosed.

专利号:US-2005288506-A1
优先权日:2004-06-29
标题:Synthesis of organometallic cyclometallated group viiib metal complexes

专利号:DE-4041400-A1
优先权日:1989-12-21
标题 :CATALYTIC METHOD FOR THE SYNTHESIS OF ALCOHOLS AND NEW METAL COMPLEXES AND THEIR PRODUCTION

专利号:JP-H04108740-A
优先权日:1989-12-21
标 题:Method of catalyzing alcohol synthesis, new metal complex and its synthesis