CAS: 7575-23-7; Pentaerythritol Tetra(3-Mercaptopropionate)

该化合物是一种化学化合物,其结构特征包括多硫醇(Euros-SH)组,其产物为聚氨酯酸,是五烯基苯丙酸的衍生物,一种多元醇,以其参与硫醇-内反应的能力而著称,使其在聚合物化学和材料科学中具有价值.它一般是液态或固态,取决于温度和配方.多硫醇组的存在允许聚合物基质的交叉连接,增强机械特性和热稳定性.五甲苯基苯基苯基丁基四(3-负对丙磷酸)经常用于涂层,粘合物和密封剂的生产,因为它有助于提高耐受力和对环境因素的抗力.此外,它可能表现出低毒性,并且被认为在各种应用中比较安全,尽管由于该物质的反应性质,应当始终观察到适当的处理和安全措施.

结构式图片

欧盟法规

REACH注册ECHA物质C&L通报REACH预注册

上下游产品

CAS号115-77-5 季戊四醇 | CAS号107-96-0 3-巯基丙酸 | CAS号126-58-9 双季戊四醇

合成工艺路线路线简述

  • 合成目标产物 Pentaerythritol Tetra(3-Mercaptopropionate) 主要起始原料 Pentaerythritol And Methyl 3-Mercaptopropionate
  • (文献来源)合成步骤主要原料 Pentaerythritol 和 Methyl 3-Mercaptopropionate

海关参考信息

专利信息


专利号:US-2019211134-A1
优先权日:2016-08-19
标 题 :Thiourethane polymers, method of synthesis thereof and use in fused filament fabrication printing
发明人:ELLSON GREGORY T; LUND BENJAMIN R; VOIT WALTER
权利人:BOARD OF REGENTS THE UNIV OF TEXAS; ADAPTIVE 3D TECH
摘要:A thermoplastic thiourethane polymer comprising a sequential chain of a first type of monomer covalently bonded to a second type of monomer via thiourethane linkages. The first type of monomer includes two or more thiol functional groups and the type of monomer includes two or more isocyanate functional groups. The first and second types of monomers are polymerized together in an anhydrous aprotic solvent-dissolved anionic step-growth polymerization reaction that is catalyzed by a non-nucleophillic base having a pKa greater than 7.

专利号:US-2024158826-A1
优先权日:2022-11-16
标 题 :Preparation method of synthetase for continuous monitoring of blood glucose
发明人:ZHANG SHAODA; QIU ZHIPENG; ZHENG XINGYU
权利人:ZHANG SHAODA; QIU ZHIPENG; ZHENG XINGYU
摘要:The present invention discloses a preparation method of a synthetase for continuous monitoring of blood glucose. The method includes the preparation steps of step S1: hydroxylation of a glass bead; step S2: silanization of the glass bead; step S3: bonding of the glass bead to glucose; step S4: synthesis of a polymer particle on the surface of the glass bead to form a glucose synthetase; and step S5: separation of the highly specific glucose synthetase. According to the preparation method of a synthetase for continuous monitoring of blood glucose provided by the present invention, the glass bead is bonded to the glucose by activating the surface of the glass bead, and then bonded to a polymer to form the glucose synthetase. The artificial synthetase prepared by the method has low sensitivity to temperature and pH value, and can be directly used in a blood glucose electrochemical sensor.

专利号:US-10899072-B2
优先权日:2016-03-15
标题:Thiourethane polymers, method of synthesis thereof and use in additive manufacturing technologies
发明人:ELLSON GREGORY T; LUND BENJAMIN R; VOIT WALTER
权利人:UNIV TEXAS; ADAPTIVE 3D TECH; BOARD OF RESENTS THE UNIV OF TEXAS SYSTEM
摘要:A semi-crystalline thiourethane polymer. The semi-crystalline thiourethane polymer comprises a sequential chain of a first type of monomer covalently bonded to a second type of monomer via thiourethane linkages. Each of the first type of monomer includes two or more thiol functional groups and each of the second type of monomer includes two or more isocyanate functional groups. The first and second types of monomers are polymerized together in an anionic step-growth polymerization reaction that is catalyzed by a non-nucleophillic base having a pKa greater than 7, produced by photo-initiated decomposition of a photolatent base. A method of synthesizing, and polymer jetting and stereolithography methods of manufacturing a polymer part, are also disclosed.

专利号:US-9505880-B2
优先权日:2013-06-04
标题 :Synthesis of polyfunctional polyol acrylates
发明人:MCCARTHY KEVIN ROBERT; NIU WEIJUN; SCHISSEL DAVID NEAL; WALLACE ARTHUR LAWRENCE
权利人:CORNING INC
摘要:A method of synthesizing urethane-free polyfunctional acrylate compounds. The method includes reaction of a polyol with acrylic acid in the presence of an inhibitor. A catalyst may also be present. The catalyst may be an acid and the inhibitor may be a substituted phenol compound. Excess acid may be removed by adding a salt and excess water may be removed by adding a drying agent. The reaction converts alcohol groups of the polyol to acrylate groups to provide a radiation-curable polyfunctional acrylate compound. The reaction is applicable to polyols generally and provides a scalable high yield process for forming urethane-free polyfunctional acrylates over a wide range of molecular weights. Coatings made from the acrylate products exhibit modulus and tensile strength characteristics favorable for primary fiber coatings.

专利号:US-2021238374-A1
优先权日:2020-02-04
标 题 :Templated synthesis of nanovoided polymers
发明人:YE SHENG; LANDIG RENATE EVA KLEMENTINE; DIEST KENNETH ALEXANDER; OUDERKIRK ANDREW JOHN; BOWMAN CHARLES ROBERT; BOWMAN ROBERT G; HENDRICKSON WILLIAM ARTHUR; RUEB CHRISTOPHER J; PURVIS II LAFE JOSEPH; SUN WENMO; LI RYAN; YAROSHCHUK OLEG; RAO TINGLING; BOROMAND ARMAN; ZHAO CHURNING; Khaleghimeybodi Morteza
权利人:FACEBOOK TECH LLC
摘要:A method of forming a voided polymer includes forming a polymerizable composition containing a polymer precursor and a solid templating agent, forming a coating of the polymerizable composition, processing the coating to form a cured polymer material having a solid phase in a plurality of defined regions, and removing at least a portion of the solid phase from the cured polymer material to form a voided polymer layer.

专利号:US-3886201-A
优先权日:1971-11-17
标 题:Perfluoroalkyl esters of mercapto- and thio-carboxylic acids
发明人:FALK ROBERT ALLAN; KLEINER EDUARD KARL
权利人:CIBA GEIGY CORP
摘要:Novel perfluoroalkyl group containing mercaptans and sulfides are disclosed having soil repellent properties if applied to substrates such as textiles, paper and leather and being useful as intermediates for the synthesis of soil repellent polymers. The adducts are obtained by the base or free radical catalyzed addition of hydrogen sulfide or mono- or polymercaptans to perfluoroalkyl group containing esters of fumaric, maleic, citraconic, mesaconic, itaconic, methylene malonic or aconitic acid.
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合成参考文献


参考文献:10.1021/la060625w
摘要:Perl A, Péter M, Ravoo BJ, Reinhoudt DN, Huskens J. Heavyweight dendritic inks for positive microcontact printing. Langmuir. 2006 Aug 29;22(18):7568–73. doi: 10.1021/la060625w.
参考文献:10.1002/jbm.b.31539
摘要:Blakely B, Hoon Lee B, Riley C, McLemore R, Pathak CP, Vernon BL. Formulation and characterization of radio-opaque conjugated in situ gelling materials. J Biomed Mater Res B Appl Biomater. 2010 Apr;93(1):9–17. doi: 10.1002/jbm.b.31539.
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