CAS: 94108-97-1; Di(Trimethylolpropane)Tetraacrylate

该化合物是一种多功能丙烯酸单体,通常用于涂层,粘合剂和墨水的配制,因为其能够加强交叉联系和改善机械特性,其特点是四种丙烯酸盐功能组,在紫外线或热固化条件下可以快速聚合;该化合物通常具有低粘度,易于融入各种配方;二甲基丙烯四丙烯酸盐的特点是其极佳的粘合性,化学抗药性和耐久性,适合需要强性性的应用;此外,它经常用于生产需要高硬性和刮痕抗力的聚合材料;然而,与许多丙烯酸盐一样,它可能刺激皮肤和眼睛,在操作过程中需要适当的安全防范;其再活性和多功能性使其成为涂料和聚合物工业先进材料开发中的宝贵组成部分.

英文名称Di(Trimethylolpropane)Tetraacrylate
中文名称二(三羟甲基丙烷)四丙烯酸
IUPAC名称(oxybis(methylene))bis(2-ethylpropane-2,1,3-triyl) tetraacrylate
其它别名2-Propenoic Acid, 1,1'-(2-((2,2-Bis(((1-Oxo-2-Propen-1-yl)Oxy)Methyl)Butoxy)Methyl)-2-Ethyl-1,3-Propanediyl) Ester; Xrmbqhtwubgqdn-Uhfffaoysa-N; Bistrimethylolpropane Tetraacrylate; Acrylic Acid [oxybis(Methylene)]Bis(2
CAS编号94108-97-1
MFCD编号:MFCD00192118
EINECS号:302-434-9
FDA UNII编号:00Z96A58MN
分子式:C24H34O9
分子量:466.53
产品CID: 1987582
产品分类有机原料 → 羧酸类化合物及衍生物

相似结构搜索
InChIKey: XRMBQHTWUBGQDN-UHFFFAOYSA-N
InChI=1S/C24H34O9/c1-7-19(25)30-15-23(11-5,16-31-20(26)8-2)13-29-14-24(12-6,17-32-21(27)9-3)18-33-22(28)10-4/h7-10H,1-4,11-18H2,5-6H3…
计算化学: 氢键受体数9.0氢键供体数0.0可旋转键数22.0

物理性质

熔点-56 °C
沸点540.4 °C at 760mmHg
闪点228.2 °C
密度1.096g/cm3
PSA:114.43
LogP:2.7126
折射率n20/D 1.479(文献)
溶解性15 Mg/l At 25°c
敏感性避免接触强氧化剂，惰性气体
外观形态无色至浅橙色至黄色透明液体
储存条件密封干燥, 室温
产品应用该化合物用于稀释剂,有机合成材料,油漆和涂料添加剂,摄影化学剂和溶剂(作为产品配制或混合物的一部分).

MSDS等安全信息

GHS象形图
GHS符号GHS07;
注释: Exclamation mark
危险类别特定目标器官毒性 - 单次接触类别3
皮肤腐蚀/刺激类别2
严重眼刺激类别2
水生慢性毒性类别2
急性毒性类别4(经皮)
警示词Warning(警告)
危险描述H335 |可能引起呼吸道刺激.
H315 |造成皮肤刺激.
H319 |造成严重眼刺激.
H411 |对水生生物有毒并具有长期持续影响.
H312 |皮肤接触有害.
防范说明P264-P273-P280-P305+P351+P338-P337+P313-P391
UN编号NONH for all modes of transport
危险品标志Xi
安全声明26-36
危险类别码43
WGK Germany3

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

二(三羟甲基丙烷) 3,3,7,7-Tetra(Hydroxymethyl)-5-Oxanonane 23235-61-2

合成工艺路线路线简述

23235-61-2 = 94108-97-1
反应条件:1.1 Reagents: Sulfuric Acid Catalysts: Lanthanum Sesquioxide,Titania Solvents: Water; 14 H,Rt1.2 Catalysts: 4-Methoxyphenol; 2 H,Rt
标题:Preparation Of Polyol Acrylates
参考文献:China]

94108-97-1 = 94108-97-1
反应条件:1.1 Catalysts: Triethylamine Solvents: Dichloromethane; Rt
标题:Synthesis And Photopolymerization Properties Of Self-Initiated Photopolymerized Acrylate Oligomers
作者:Zhang,Yong; Shi,Wen-Fang
参考文献:Gaodeng Xuexiao Huaxue Xuebao 日期:2012 卷标:33(3) 页码:635-639]

3121-61-7 + 23235-61-2 = 94108-97-1 + 115633-58-4
反应条件:1.1 Reagents: 4-Methoxyphenol Catalysts: Dabco,Zinc Acetate; 24 H,250 - 760 Mm Hg,120 - 145 °C
标题:Method For Manufacturing Polyalcohol (Meth)Acrylate Esters
参考文献:World Intellectual Property Organization]

23235-61-2 = 94108-97-1
反应条件:1.1 Reagents: 4-Methoxyphenol,Phosphinic Acid Catalysts: P-Toluenesulfonic Acid Solvents: Toluene,Cyclohexane; Rt -> 95 °C; 9 - 10 H,85 - 95 °C; 95 - 105 °C; 105 °C -> 40 °C1.2 Reagents: Sodium Hydroxide Solvents: Water; 30 Min
标题:Clean Production Method For Bis(Trimethylolpropane) Tetraacrylate Or Pentaerythritol Tetraacrylate
参考文献:China]

23235-61-2 = 94108-97-1
反应条件:1.1 Reagents: Hydroquinone,Oxygen Catalysts: Carbon,12-Tungstosilicic Acid Solvents: Benzene; 4 H,Heated
标题:Catalytic Synthesis Of Ditrimethylol Propane Tetraacrylate (Di-Tmpta) Over H4Siw12O40/c
作者:Jiang,Wei; Ding,Guo-Rong; Cao,Jing; Li,Wei; Zhang,Ji-Bo
参考文献:Tanxingti 日期:2010 卷标:20(5) 页码:50-52]

23235-61-2 = 94108-97-1
反应条件:1.1 Reagents: Phenothiazine,Hydroquinone Catalysts: P-Toluenesulfonic Acid Solvents: Toluene; Rt -> 116 °C; 4 H,116 °C
标题:Research On The Synthesis Of Ditrimethylolpropane Tetraacrylate (Di-Tmpta)
作者:Song,Yan; Zhang,Chaoqun; Yang,Qingbiao; Wang,Hengguo; Li,Yaoxian; Et Al
参考文献:Yingyong Huagong 日期:2008 卷标:37(9) 页码:1002-1005]

23235-61-2 = 94108-97-1
反应条件:1.1 Reagents: Phenothiazine Catalysts: P-Toluenesulfonic Acid Solvents: Toluene; Reflux; Reflux -> 25 °C1.2 Reagents: Sodium Hydroxide Solvents: Water; Ph 81.3 Reagents: 2,6-Di-Tert-Butyl-4-Methylphenol
标题:Method For Preparing Bistrimethylolpropane Tetraacrylate
参考文献:China]

23235-61-2 = 94108-97-1
反应条件:1.1 Reagents: Phosphinic Acid Catalysts: Phenothiazine,P-Toluenesulfonic Acid Solvents: Toluene; 6 H,Rt -> 105 °C; 105 °C -> Rt1.2 Reagents: Sodium Carbonate,Sodium Hydroxide Solvents: Hexane,Water; Ph 7.6,Rt1.3 Solvents: Water; Ph 7
标题:Preparation Of Ditrimethylolpropane Tetraacrylate
参考文献:China]

23235-61-2 = 94108-97-1 [标题:Reaction Conditions
标题:Acrylate Compounds
参考文献:Japan]

77-99-6 = 94108-97-1 + 37275-47-1 + 15625-89-5
反应条件:1.1 Reagents: 4-Methoxyphenol Catalysts: Cuprous Chloride,Phosphonic Acid,2-Acrylamido-2-Methylpropanesulfonic Acid Solvents: Toluene,Heptane; Reflux
标题:Curable Material And Continuous Production Method
参考文献:China

二(三羟甲基丙烷),丙烯酸反应生成二(三羟甲基丙烷)四丙烯酸
参考文献:Kamiideh,Kadzuo;Simomura,Takatosi;Yamadzaki,Takehsi;Moriyuki,Masatosi
标题:Kamiideh,Kadzuo;Simomura,Takatosi;Yamadzaki,Takehsi;Moriyuki,Masatosi

海关参考信息

2901210000-乙烯
2901220000-丙烯
2905121000-正丙醇
2905399001-1,3-丙二醇
💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
详情请参考：📖 海关编码查询和海关进出口税则

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