专利号:US-2024075466-A1 优先权日:2021-04-09 标 题:One-Pot Synthesis of Transition Metal-Promoted Chabazites 发明人:VAN TENDELOO LEEN; SCHUETZE FRANK-WALTER; VERHEYEN ELKE JANE JUNE 权利人:UMICORE AG & CO KG 摘要:The invention provides methods for a one-pot synthesis of molecular sieves of the CHA-type. The method uses molecular and non-molecular sieves as sources of silicon and aluminum. A first OSDA is selected from tetraethylenepentamine (TEPA) and triethy-lenepentamine (TETA). The synthesis mixture comprises a first metal selected from copper, iron and zinc. Optionally, the synthesis mixture may furthermore comprise a second OSDA and/or a second metal selected from manganese, cesium, magnesium, calcium, strontium, barium, yttrium, titanium, zirconium, niobium, iron, zinc, silver, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium and mixtures thereof. The molecular sieves of the CHA-type obtainable by the method can be used as SCR-catalytically active substances for the removal of nitrogen oxides from exhaust gases of combustion engines.
专利号:US-11548898-B2 优先权日:2017-07-06 标题 :Synthesis of halichondrins 发明人:KISHI YOSHITO; AI YANRAN; YE NING; WANG QIAOYI; YAHATA KENZO; ISO Kentaro; NAINI SANTHOSH REDDY; YAMASHITA SHUJI; LEE JIHOON; OHASHI ISAO; FUKUYAMA TAKASHI 权利人:HARVARD COLLEGE; EISAI R&D MAN CO LTD 摘要:The present invention provides methods for the synthesis of ketones involving a Ni/Zr-mediated coupling reaction. The Ni/Zr-mediated ketolization reactions can be used in the synthesis of halichondrins (e.g., halichondrin A, B, C; homohalichondrin A, B, C; norhalichondrin A, B, C), and analogs thereof. Therefore, the present invention also provides synthetic methods useful for the synthesis of halichondrins, and analogs thereof. Also provided herein are compounds (i.e., intermediates) useful in the synthesis of halichondrins, and analogs thereof. In particular, the present invention provides methods and compounds useful in the synthesis of compound of Formula (H3-A).
专利号:US-11851338-B2 优先权日:2019-04-19 标 题:Method for fast synthesis of an AFX-structure zeolite with a FAUjasite source 发明人:MARTINEZ FRANCO RAQUEL; HARBUZARU BOGDAN; LLIDO ERIC; BERTHOUT DAVID 权利人:IFP ENERGIES NOW 摘要:The present invention relates to a process for the rapid synthesis of an AFX-structure zeolite comprising at least:n i) mixing, in an aqueous medium, a FAU-structure zeolite having an SiO 2 (FAU) /Al 2 O 3 (FAU) molar ratio of between 2.00 and 100, a nitrogen-containing organic compound R, at least one source of at least one alkali and/or alkaline-earth metal M of valence n,n with the following molar composition: (SiO 2 (FAU) )/(Al 2 O 3 (FAU) ) between 2.00 and 100, H 2 O/(SiO 2 (FAU) ) between 1 and 100, R/(SiO 2 (FAU) ) between 0.01 and 0.6, M 2/n O/(SiO 2(FAU) ) between 0.005 and 0.45, wherein SiO 2 (FAU) denotes the amount of SiO 2 provided by the FAU zeolite and Al 2 O 3 (FAU) denotes the amount of Al 2 O 3 provided by the FAU zeolite, until a homogeneous precursor gel is obtained; n ii) hydrothermally treating said precursor gel obtained at the end of step i) under autogenous pressure at a temperature of between 120° C. and 250° C., for 4 to 12 hours.
专利号:US-2023402618-A1 优先权日:2020-10-27 标 题:Method for synthesis of porous monoliths of transition-metal-doped-noble-metal 发明人:SINGH KIRANPAL; BHAT YASH RAJESH; CHARAYA HEMANT; CHAUDHARI VIJAY RAMAN 权利人:LOG 9 MATERIALS SCIENT PRIVATE LIMITED 摘要:The embodiment herein provides a simple, one-pot and scalable methodology for the synthesis of porous monoliths of Transition-metal-doped-noble-metal nanoparticles for cathode catalyst in a metal-air battery, PEMFCs, AFCs, and anode catalyst in water electrolysers. Silver is used as a base material on which doping is done with the transition metals selected from Cu, Co, Mn, Fe, and Ni.
专利号:US-11548793-B2 优先权日:2016-10-19 标题:Synthesis of aerosol gels comprising macro-aggregates in a buoyancy-opposed flame reactor by a diffusion-limiting cluster aggregating process 发明人:CHAKRABARTY RAJAN K; LIU PAI 权利人:WASHINGTON UNIVERSITY ST LOUIS 摘要:A process for gas-phase synthesis of titanium dioxide aerosol gels with controlled monomer size and crystalline phase using a diffusion flame aerosol reactor operated in a buoyancy-opposed configuration is disclosed. The process includes introducing a precursor stream into a diffusion flame aerosol reactor, introducing a fuel stream into the reactor, combusting the precursor stream and the fuel stream in a flame to form at least one nanoparticle, and operating the reactor in a down-fired buoyancy-opposed configuration to produce the aerosol gel.
专利号:US-12054508-B1 优先权日:2019-04-16 标 题 :Compositions and methods for sulfation of carbohydrates and peptides via electron-deficient aryl sulfate diesters 发明人:NIU JIA; LIU CHAO; YANG CANGJIE 权利人:THE TRUSTEES OF BOSTON COLLEGE 摘要:In one aspect, the disclosure relates to a facile strategy to introduce electron-deficient aryl sulfate diesters to silylated hydroxyl groups of carbohydrates and amino acids, among other substrates, wherein selective hydrolysis and the removal of an electron-deficient aromatic group allows for the efficient generation of sulfated carbohydrates, peptides, and other compounds. The incorporation of electron-deficient aryl sulfate diesters in the early stage of the synthesis of glycans, peptides, and the like, disclosed herein avoids time-consuming protecting group manipulations, simplifies the purification of sulfated products, and improves the overall yield and efficiency. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present disclosure.
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