CAS: 22031-12-5; (2-((Diphenylphosphino)Methyl)-2-Methylpropane-1,3-Diyl)Bis(Diphenylphosphine)

该化合物是一个化学化合物,其独特的结构是将一个中心乙基结合成三组二苯基甲基组,该化合物在协调化学和催化方面的潜在应用值得注意,特别是在形成金属复合体方面,由于磷的捐献原子的存在,该化合物在化学和化学特性方面可能具有潜在用途;二苯基磷基组对其性能和电子特性起到了作用,使它在各种化学反应中成为多种异同体.这种化合物在有机溶剂中表现出良好的热稳定性和溶性,这提高了其在合成工艺中的效用.此外,多种磷基组的存在可以促进金属结构的过渡性稳定,从而在催化方面发挥关键作用.总的来说,1,1,1-Tris(二苯基甲基甲基)乙烷是有机金属化学领域的一个重要化合物,对开发新的催化系统和材料具有影响.

结构式图片

欧盟法规

ECHA物质C&L通报

上下游产品

1,3-dichloro-2-(chloromethyl)-2-methylpropane diphenylphosphane methanesulfonic acid 3-methyloxetan-3-ylmethyl ester -3-methyloxetan3-(Diphenylphosphanyl)methyl-3-methyloxetan 1,1,1-tris(diphenylphosphinomethyl)ethane trisulphide 3C(CH2P(Se)(C6H5)2)3][CH3C(CH2P(Se)(C6H5)2)3] 1,1,1-tris(dicyclohexylphosphinomethyl)ethane

合成工艺路线路线简述

    1,1,1-三氯甲基乙烷置于sodium体系中,用 二丁醚 用作溶剂,化学反应 4.0H,以87%的收率获得1,1,1-三(二苯基膦甲基)乙烷
    参考文献:Wo2006/84878
    标题:Wo2006/84878

    海关参考信息

    专利信息


    专利号:US-2022219156-A1
    优先权日:2019-04-29
    标题:Catalyst for the catalytic synthesis of urea
    发明人:GLOTZBACH CHRISTOPH; TENHUMBERG NILS; EL HAWARY TAREK; MAKHYNYA YEVGENY; LEITNER WALTER; KLANKERMAYER JÜRGEN; SCHUMACHER HANNAH
    权利人:THYSSENKRUPP IND SOLUTIONS AG; THYSSENKRUPP AG
    摘要:A ruthenium-phosphine complex can be used as a catalyst in a method for the catalytic synthesis of urea. The method may comprise more particularly a reaction of formamide or of formamide with ammonia in the presence of the catalyst to form urea and hydrogen. Through the use of the ruthenium-phosphine complex as the catalyst, catalytic preparation of urea from formamide or from formamide with ammonia is provided for the first time. This allows for synthesis under mild conditions and virtually no formation of byproducts. Further, using an acid as a cocatalyst in the catalytic synthesis or the reaction can lead to an improvement in urea yield.

    专利号:US-2024368099-A1
    优先权日:2022-01-18
    标 题:Methods for the synthesis of di(hydroxymethyl)tetrahydrofuran and its application in polyesters and polyurethanes
    发明人:SPIEGELBERG BRIAN; BRANDT ADRIAN; BECK HORST; KUX ALEXANDER; TIN SERGEY; DE VRIES JOHANNES GERARDUS
    权利人:HENKEL AG & CO KGAA
    摘要:The present invention relates to the synthesis of di(hydroxymethyl)tetrahydrofuran (DHMTHF) and the preparation of trans-enriched mixtures of DHMTHF. The invention further refers to polyester polyols which are obtained by reaction of cis/trans DHMTHF mixtures with a dicarboxylic acid. The invention further relates to polyurethanes and compositions containing a polyester polyol comprising DHMTHF, in particular to such polyurethane-containing (adhesive) compositions.

    专利号:US-11407993-B2
    优先权日:2017-02-14
    标 题 :Method for the synthesis of DNA conjugates by micellar catalysis
    发明人:BHAT AVINASH SHASHIDHAR; KLIKA SKOPIC MATEJA; BRUNSCHWEIGER ANDREAS; WEBERSKIRCH RALF
    权利人:UNIV DORTMUND TECH
    摘要:A method for the synthesis of a chimeric conjugate molecule by micellar catalysis that may form part of DNA-encoded compound libraries. A DNA-coupled organic starter molecule may be reacted with another organic compound, using a catalyst located within a micelle, to form a conjugate of an organic candidate compound coupled to a DNA identifier tag.

    专利号:US-4891442-A
    优先权日:1987-03-09
    标 题 :Process for synthesis of β-phenylalanine
    发明人:LIN JIANG-JEN; KNIFTON JOHN F
    权利人:TEXACO INC
    摘要:N-acetyl-β-phenylalanine is synthesized by reacting phenylacetaldehyde, acetamide and synthesis gas with a catalyst comprising a cobalt-containing compound in conjunction with a cocatalyst that may be either a Group VB or VIB containing ligand, or a rhodium compound optionally bonded to one or more Group VB or VIB donor ligands, at a temperature of at least 50° C. and a pressure of at least 500 psi.

    专利号:WO-2019020508-A1
    优先权日:2017-07-26
    标 题 :PROCESS FOR THE PREPARATION OF HIGH-PURITY RUCAPARIB
    发明人:BELOGI GIANLUCA; MAZZONI ANDREA; SERRA STEFANO; NOVO BARBARA
    权利人:OLON SPA
    摘要:The present invention relates to a new low environmental impact method for the synthesis of rucaparib with high yield and purity, said process comprising a regioselective coupling reaction between indole and iodo-aryl, carried out in water in the presence of a catalyst. The process of the invention is industrially advantageous because in the key coupling step, high regioselectivity is achieved without the use of complex intermediates or potentially toxic and environmentally harmful solvents.

    专利号:US-8877977-B2
    优先权日:2011-11-25
    标题 :Synthesis of polyalkylenepolyamines having a low color index by homogeneously catalyzed alcohol amination in the presence of hydrogen
    发明人:STRAUTMANN JULIA; SCHAUB THOMAS; HUEFFER STEPHAN; MAAS STEFFEN; PACIELLO ROCCO
    权利人:STRAUTMANN JULIA; SCHAUB THOMAS; HUEFFER STEPHAN; MAAS STEFFEN; PACIELLO ROCCO; BASF SE
    摘要:Process for the preparation of polyalkylenepolyamines by homogeneously catalyzed alcohol amination, in which aliphatic amino alcohols are reacted with one another or aliphatic diamines or polyamines are reacted with aliphatic diols or polyols with the elimination of water in the presence of a homogeneous catalyst and in the presence of hydrogen gas. Polyalkylenepolyamines obtainable by such processes and polyalkylenepolyamines comprising hydroxy groups, secondary amines or tertiary amines. Uses of such polyalkylenepolyamines as adhesion promoters for printing inks, adhesion promoters in composite films, cohesion promoters for adhesives, crosslinkers/curing agents for resins, primers for paints, wet-adhesion promoters for emulsion paints, complexing agents and flocculating agents, penetration assistants in wood preservation, corrosion inhibitors, immobilizing agents for proteins and enzymes.
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    主要参考文献

    参考标题:Homogeneous Catalytic Hydrogenation Of Amides To Amines
    作者:Jacorien Coetzee,Deborah L. Dodds,Jürgen Klankermayer,Sandra Brosinski,Walter Leitner,Alexandra M. Z. Slawin,David J. Cole-Hamilton |发布日期:2013.8.12
    摘要:Hydrogenation Of Amides In The Presence Of [ru(Acac)3] (Acach=2,4‐pentanedione), Triphos [1,1,1‐tris‐ (Diphenylphosphinomethyl)Ethane] And Methanesulfonic Acid (Msa) Produces Secondary And Tertiary Amines With Selectivities As High As 93 % Provided That There Is At Least One Aromatic Ring On N. The System Is Also Active For The Synthesis Of Primary Amines. In An Attempt To Probe The Role Of Msa And

    合成参考文献


    摘要:Stanforth, S. P., Science of Synthesis Knowledge Updates, (2014) 3, 5.
    摘要:Demchuk, O. M.; Stankevič, M.; Pietrusiewicz, K. M., Science of Synthesis Knowledge Updates, (2015) 1, 364.
    摘要:Nahra, F.; Cazin, C. S. J., Science of Synthesis: Catalytic Reduction in Organic Synthesis, (2017) 1, 310.
    摘要:Shi, Y.; Cole-Hamilton, D. J.; Kamer, P. C. J., Science of Synthesis: Catalytic Reduction in Organic Synthesis, (2017) 2, 204.
    摘要:Shi, Y.; Cole-Hamilton, D. J.; Kamer, P. C. J., Science of Synthesis: Catalytic Reduction in Organic Synthesis, (2017) 2, 239.
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