CAS: 3112-88-7; (Benzylsulfonyl)Benzene

上下游产品

Benzyl phenyl sulfide ethanol sodium benzenesulfonate benzyl chloride(E)-1,2-diphenyl-ethene α-benzenesulfonyl-phenylacetic acid 4-benzenesulfonyl-4-phenyl-heptanedinitrile Phenylsulfonyl-1-phenyl-1-pentanol-3

N,N-二甲基苄胺置于copper(I) Oxide,Potassium Carbonate体系中,用 乙醚,N,N-二甲基甲酰胺 作为反应溶剂,化学反应 24.0H,反应生成 苄基苯基砜
参考文献:Cu 2 O催化的季铵盐与链烷烃/亚芳基亚磺酸钠的c-s偶联
标题:Cu 2 O催化的季铵盐与链烷烃/亚芳基亚磺酸钠的c-s偶联
摘要:已经开发了一种新的协议,该协议通过烷烃/芳烃亚磺酸盐和(对映体富集的)苄基季铵盐的cu 2 O催化的c-s键交叉偶联来合成(对映体富集的)苄基砜.获得的苄基砜产品收率非常好至高(75-96%).在cu 2 O和1,1'-双-(二苯基膦基)二茂铁(dppf)存在下,还合成了具有高对映体过量(90-94%ee)的手性芳基甲基砜.
DOI:10.1016/j.Tetlet.2020.152320

专利信息

专利号:US-5175302-A
优先权日:1987-07-13
标 题 :Nucleophilic fluoroalkylation of aldehydes
发明人：STAHLY G PATRICK
权利人:ETHYL CORP
摘要:Aryl difluoromethyl sulfone adds to aldehydes under phase transfer conditions to give novel substituted alcohols of the general formula n n RCH(OH)CF.sub.2 SO.sub.2 Ar (I) n n wherein R is an aryl, cycloaliphatic, sec- or tert-aliphatic, or heterocyclic group and Ar is an aryl group. The substituted alcohols of formula I are of particular utility as intermediates in the synthesis of a variety of useful end products. For example, the products of formula I may be utilized in desulfonylation reactions, oxidation reactions and fluorination reactions.

专利号:US-4837327-A
优先权日:1987-07-13
标 题 :Process for nucleophilic fluoroalkylation of aldehydes
发明人：STAHLY G PATRICK
权利人:ETHYL CORP
摘要:Aryl difluoromethyl sulfone adds to alkehydes under phase transfer conditions to give novel substituted alcohols of the general formula n n RCH(OH)CF.sub.2 SO.sub.2 Ar (I) n n wherein R is an aryl, cycloaliphatic, sec- or tert-aliphatic, or heterocyclic group and Ar is an aryl group. The substituted alcohols of formula I are of particular utility as intermediates in the synthesis of a variety of useful end products. For example, the products of formula I may be utilized in desulfonylation reactions, oxidation reactions and fluorination reactions.

专利号:US-4999429-A
优先权日:1989-01-09
标 题 :Process for the preparation of α,α,β-1-trifluoro-1-olefinic derivatives
发明人：STAHLY G PATRICK
权利人:ETHYL CORP
摘要:Aryl difluoromethyl sulfone adds to aldehydes under phase transfer conditions to give novel substituted alcohols of the general formula n n RCH(OH)CF.sub.2 SO.sub.2 Ar (I) n n wherein R is an aryl, cycloaliphatic, sec- or tert-aliphatic, or heterocyclic group and Ar is an aryl group. The substituted alcohols of formula I are of particular utility as intermediates in the synthesis of a variety of useful end products. For example, the products of formula I may be utilized in desulfonylation reactions, oxidation reactions and fluorination reactions.

专利号:CN-109705002-B
优先权日:2018-12-18
标 题 :A kind of method of photocatalytic synthesis of sulfur sulfone compound

专利号:KR-102325534-B1
优先权日:2019-10-11
标题 :Synthesis of Sulfones and Sulfonyl Derivatives using Sodium (tert-butyldimethylsilyl)oxymethanesulfinate

专利号:CN-111925308-A
优先权日:2020-08-13
标 题:A kind of method for photocatalytic synthesis of N-substituted sulfonediimide