CAS: 87-73-0; (2R,3S,4S,5S)-2,3,4,5-Tetrahydroxyhexanedioic Acid

• 英文名称(2R,3S,4S,5S)-2,3,4,5-Tetrahydroxyhexanedioic Acid
• 中文名称(2R,3S,4S,5S)-2,3,4,5-四羟基己二酸
• IUPAC名称(2R,3S,4S,5S)-2,3,4,5-tetrahydroxyhexanedioic acid
• 其它别名(2S,3S,4S,5R)-2,3,4,5-Tetrahydroxyhexanedioic Acid; D-Glucarate; D-Saccharic Acid; (2R,3S,4S,5S)-2,3,4,5-Tetrahydroxyhexanedioate; D-Tetrahydroxyadipate; L-Gularate; D-(+)-Saccharate; D-(+)-Sa
• CAS编号87-73-0
• MFCD编号:MFCD09752094
• EINECS号:201-768-1
• 分子式:C6H10O8
• 分子量:210.14
• 产品CID: 1885842
• 产品分类有机原料→分子砌块→手性化合物→手性砌块

• 相似结构搜索
• 产品信息参考;;;;
• InChIKey: DSLZVSRJTYRBFB-LLEIAEIESA-N
• InChI=1S/C6H10O8/c7-1(3(9)5(11)12)2(8)4(10)6(13)14/h1-4,7-10H,(H,11,12)(H,13,14)/t1-,2-,3-,4+/m0/s1…
• 计算化学: 氢键受体数6.0氢键供体数6.0可旋转键数5.0

相似化合物

物理性质

• 熔点125-126 °C
• 沸点269.65 °C at 760 mmHg
• 闪点431.2±29.4 °C
• 密度1.9±0.1 g/cm3
• PH:D19 +6.86° +20.60° (H2O)
• pKa:2.99±0.35(预测)
• PSA:155.52
• LogP:-3.4008
• 折射率1.638
• 蒸汽压0.0±5.9 mmHg at 25°C
• 溶解性Easily Soluble (Water, Ethanol)
• 外观形态白色至类白色固体
• 储存条件密封干燥,2-8°C
• 产品应用该化合物是一种葡萄糖衍生物; 2004年,美国能源部(DOE)将它确定为"生物物质中12种增值化学品"之一,作为合成各种高效和无害环境的新兴生物基燃料的原料,显示了巨大的潜在经济价值.
• 性质描述白色结晶.熔点124-126°C.

MSDS等安全信息

• GHS象形图
• GHS符号GHS02 & GHS05;
  注释: Flame & Corrosion
• 危险类别易燃固体 类别2
  皮肤腐蚀 类别1A
  严重眼损伤 类别1
• 警示词Danger(危险)
• 危险描述H228 |易燃固体.
  H314 |造成严重皮肤灼伤和眼损伤.
  H318 |造成严重眼损伤.
• 防范说明P260-P264-P280-P301+P330+P331-P304+P340-P363-P405-P501
• 危险等级8
• UN编号3261.0
• 危险品标志C
• 包装等级Ⅲ
• WGK Germany3.0

欧盟法规

上下游产品

合成工艺路线路线简述

• 合成目标产物 D-Glucaric Acid 主要起始原料 D-Glucose
• 50-99-7 = 87-73-0
  反应条件:1.1 Reagents: Sulfuric Acid Catalysts: Manganese Oxide (Mno2),Ytterbium Solvents: Water; 24 H,Rt
  标题:Efficiently Coupled Glucose Oxidation For High-Value D-Glucaric Acid With Ultradurable Hydrogen Via Mn(Iii) In Acidic Solution
  作者:Li,Junhua; Et Al
  参考文献:Nano Research 日期:2023 卷标:16(8) 页码:10748-10755]
  
  5328-37-0 + 50-99-7 = 87-73-0
  反应条件:1.1 Solvents: Water; 30 °C
  标题:Combinatorial Synthetic Pathway Fine-Tuning And Cofactor Regeneration For Metabolic Engineering Of Escherichia Coli Significantly Improve Production Of D-Glucaric Acid
  作者:Su,Hui-Hui; Et Al
  参考文献:New Biotechnology 日期:2020 卷标:59 页码:51-58]
  
  526-95-4 = 87-73-0
  反应条件:1.1 Reagents: Sodium Nitrite,Oxygen
  标题:Oxidation Of D-Glucose To D-Gluconic And D-Glucaric Acids Catalyzed By Sodium Nitrite
  作者:Grigor'Eva,I. A.; Et Al
  参考文献:Russian Journal Of Applied Chemistry (Translation Of Zhurnal Prikladnoi Khimii) 日期:2001 卷标:74(12) 页码:2021-2026]
  
  5328-37-0 = 87-73-0
  反应条件:1.1 Solvents: Water; 30 °C
  标题:Combinatorial Synthetic Pathway Fine-Tuning And Cofactor Regeneration For Metabolic Engineering Of Escherichia Coli Significantly Improve Production Of D-Glucaric Acid
  作者:Su,Hui-Hui; Et Al
  参考文献:New Biotechnology 日期:2020 卷标:59 页码:51-58]
  
  56-81-5 = 87-73-0
  反应条件:1.1 Solvents: Water; 30 °C
  标题:Combinatorial Synthetic Pathway Fine-Tuning And Cofactor Regeneration For Metabolic Engineering Of Escherichia Coli Significantly Improve Production Of D-Glucaric Acid
  作者:Su,Hui-Hui; Et Al
  参考文献:New Biotechnology 日期:2020 卷标:59 页码:51-58]
  
  58-86-6 = 87-73-0
  反应条件:1.1 Solvents: Water; 30 °C
  标题:Combinatorial Synthetic Pathway Fine-Tuning And Cofactor Regeneration For Metabolic Engineering Of Escherichia Coli Significantly Improve Production Of D-Glucaric Acid
  作者:Su,Hui-Hui; Et Al
  参考文献:New Biotechnology 日期:2020 卷标:59 页码:51-58]
  
  576-42-1 = 87-73-0 [标题:Reaction Conditions
  标题:Transition-Metal-Free Decarboxylation Of D-Glucaric Acid To Furan Catalyzed By Sncl4 In A Biphasic System
  作者:Li,Teng; Et Al
  参考文献:Molecular Catalysis 日期:2021 卷标:516]
  
  576-42-1 = 87-73-0
  反应条件:1.1 Reagents: Dowex 50Wx8-100
  标题:Nanoparticulate Poly(Glucaramide)-Based Hydrogels For Controlled Release Applications
  作者:Johnston,Erik R.; Et Al
  参考文献:Gels 日期:2017 卷标:3(2) 页码:17/1-17/14]
  
  519054-19-4 = 87-73-0
  反应条件:1.1 Reagents: Potassium Bicarbonate,Nitric Acid Solvents: Water
  标题:Derivatives Of D-Glucaric Acid
  作者:Totton,Ezra L.; Et Al
  参考文献:Journal Of Organic Chemistry 日期:1957 卷标:22]
  
  36439-43-7 = 87-73-0
  反应条件:1.1 Reagents: Dowex 50Wx Solvents: Water; 15 Min,Rt
  标题:Modulating Electromagnetic Interference Shielding Performance Of Ultra-Lightweight Composite Foams Through Shape Memory Function
  作者:Zhu,Shu; Et Al
  参考文献:Composites 日期:2021 卷标:204]
  
  50-99-7 + 56-81-5 = 87-73-0
  反应条件:1.1 Solvents: Water; 30 °C
  标题:Combinatorial Synthetic Pathway Fine-Tuning And Cofactor Regeneration For Metabolic Engineering Of Escherichia Coli Significantly Improve Production Of D-Glucaric Acid
  作者:Su,Hui-Hui; Et Al
  参考文献:New Biotechnology 日期:2020 卷标:59 页码:51-58]
  
  58-86-6 + 50-99-7 = 87-73-0
  反应条件:1.1 Solvents: Water; 30 °C
  标题:Combinatorial Synthetic Pathway Fine-Tuning And Cofactor Regeneration For Metabolic Engineering Of Escherichia Coli Significantly Improve Production Of D-Glucaric Acid
  作者:Su,Hui-Hui; Et Al
  参考文献:New Biotechnology 日期:2020 卷标:59 页码:51-58

海关参考信息

• 2905122000-异丙醇
  2905310000-1,2-乙二醇
  2905320000-1,2-丙二醇
  2905399001-1,3-丙二醇
• 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
• 详情请参考：📖 海关编码查询和海关进出口税则

其他信息查阅

• ➥ 象形图和危险代码
• ➥ 防范代码详解
• ➥ 危险代码说明
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• ➥ REACH监管