CAS: 105365-50-2; 4-Hexylphenylboronic Acid

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1-bromo-4-n-hexylbenzene hydrogenchloride Trimethyl borate 4-hexyl-4'-trityloxymethyl-2'-nitro-1,1'-biphenyl 4',6'-bis-(p-(dodecyloxy)phenylethynyl)-4,4''-dihexyl-[1,1':3',1'']terphenyl 4-(n-hexyl)phenylboronic acid sodium salt ethyl 2-(3,6-bis(4-hexylphenyl)-9H-carbazol-9-yl)acetate

二甲基(4-己基苯基)硼酸酯置于盐酸,水体系中,用 四氢呋喃,正己烷 用作溶剂,化学反应 0.5H,反应生成4-N-己基苯硼酸
参考文献:Microwave Accelerated Synthesis And Evaluation Of Conjugated Oligomers Based On 2,5-Di-Thiophene-[1,3,4]Thiadiazole
标题:Microwave Accelerated Synthesis And Evaluation Of Conjugated Oligomers Based On 2,5-Di-Thiophene-[1,3,4]Thiadiazole
摘要:一系列基于π共轭的2,5-二噻吩-[1,3,4]噻二唑的五聚体通过微波促进的钯催化交叉偶联反应合成而成.终止每个五聚体的芳香基团对观测到的光学,电化学和液晶特性具有深远的影响.在五聚体外围逐渐替换为电子富集程度较低的芳香基团,减小了基态与第一激发态之间的能量间隔,同时也降低了边际轨道的能量,足以阻碍氧化并促进还原.热致液晶梅索材料2,5-双-[5-(4-己基-苯基)-噻吩-2-基]-[1,3,4]噻二唑7在向列相,层状相和结晶相中表现出无分散的双极电荷输运.随着介相分子有序性的增加,电荷迁移率也相应提高,在最高有序的层状相中达到最大值(µhole ~ 4 x 10−3 Cm2 V−1 S−1,µelectron ~ 8 x 10−3 Cm2 V−1 S−1).
Doi:10.1039/b922714H