物理性质
- 熔点-58 °C
- 沸点167.8±7.0 °C at 760 mmHg
- 闪点34.4±0.0 °C
- 密度0.9±0.1 g/cm3
- pKa:14 (Schwarzenbach et al., 1993)>>14 (Schwarzenbach et al., 1993)
- PSA:0.0
- LogP:3.91
- 折射率1.484
- 蒸汽压2.2±0.1 mmHg at 25°C
- 溶解性29.5毫克/升
- 敏感性1.避免与氧化剂接触。易燃,接触氧化剂有燃烧危险。对皮肤有刺激性,避免与眼睛、皮肤接触。2.本品微毒。大鼠经口LD505000mg/kg。3. 存在于烟气中。
- 外观形态透明无色透明液体
- 储存条件储存于阴凉、通风的库房。远离火种、热源。应与氧化剂分开存放,切忌混储。采用防爆型照明、通风设施。禁止使用易产生火花的机械设备和工具。储区应备有泄漏应急处理设备和合适的收容材料。
本品易燃,遇高热,明火,或接触氧化剂有燃烧危险。贮运见异丙苯。
- 产品应用用于有机合成,也用作溶剂.
- 性质描述无色液体.熔点-57.85°C,沸点169°C,50.7°C(1.33kPa),相对密度0.8665(20/4°C),折射率1.492,闪点(开杯)60°C,自燃点450°C.不溶于水,能与醇,醚,酮,苯等有机溶剂混溶.易燃.
欧盟法规
REACH注册ECHA物质ECHA物质C&L通报REACH预注册上下游产品
CAS号103-65-1 正丙苯溶液标准物质 | CAS号98-82-8 异丙基苯 | CAS号71-43-2 苯 | CAS号115-11-7 2-甲基丙烯合成工艺路线路线简述
- 939-97-9 = 98-06-6 + 15796-82-4
反应条件:1.1C:492-22-8,C:Co Diacetylacetonate,C:72914-19-3,S:Mecn,5 H,28°C
标题:Decarbonylation Of Benzaldehydes By Dual Photoorgano-Cobalt Catalysis
作者:By Kolb,Daniel Et Al
参考文献:Chemical Communications (Cambridge 日期:2023 卷标:59(55) 页码:8592-8595]
3972-56-3 = 98-06-6
反应条件:1.1R:T-Buok,R:Etoh,C:2271302-90-8,S:96-47-9,1 H,Rt1.2R:H2O
标题:Pd-Catalysed Hydrodehalogenation Of Aryl Chlorides: A Mild Method For Deuteration And Detoxification
作者:By Burhenn,Angela Et Al
参考文献:Catalysis Science & Technology 日期:2023 卷标:13(12) 页码:3545-3550]
35779-04-5 = 98-06-6
反应条件:1.1R:Etn(Pr-I)2,C:2034190-81-1,S:Mecn,12 H,35°C
标题:Reductive Cleavage Of C-X Or N-S Bonds Catalyzed By Super Organoreductant Cbz6
作者:By Wang,Si-Da Et Al
参考文献:Organic Letters 日期:2023 卷标:25(5) 页码:816-820]
2764862-44-2 = 98-06-6 + 262-20-4
反应条件:1.1S:Dmso,20 H,Rt
标题:A General Arene C-H Functionalization Strategy Via Electron Donor-Acceptor Complex Photoactivation
作者:By Dewanji,Abhishek Et Al
参考文献:Nature Chemistry 日期:2023 卷标:15(1) 页码:43-52]
35779-04-5 + 3396-11-0 = 98-06-6 + 3056-64-2
反应条件:1.1R:Bu4Ncl,C:Pd(Dba)2,C:2848647-34-5,S:Acnme2,48 H,35°C1.2R:Nahco3,S:H2O2.1C:2848647-35-6,C:42196-31-6,S:Acnme2,36 H,60°C2.2R:Nahco3,S:H2O
标题:Shining Visible Light On Reductive Elimination: Acridine-Pd-Catalyzed Cross-Coupling Of Aryl Halides With Carboxylic Acids
作者:By Toriumi,Naoyuki Et Al
参考文献:Journal Of The American Chemical Society 日期:2022 卷标:144(42) 页码:19592-19602]
137203-34-0 + 1104637-40-2 = 98-06-6
反应条件:1.1R:(T-Bu-O)2,C:1403671-86-2,S:Phme,5 Min,Rt2.1R:(T-Bu-O)2,C:1403671-86-2,Rt -> -40°C; -40°C -> Rt; 2 Min,Rt; Rt -> 100°C; 16 H,100°C; 100°C -> Rt2.2R:O2,Rt3.1R:(T-Bu-O)2,C:1403671-86-2,Rt -> -40°C; -40°C -> Rt; 2 Min,Rt; Rt -> 100°C; 16 H,100°C; 100°C -> Rt3.2R:O2,Rt
标题:Copper-Catalyzed C(Sp3)-H Methylation Via Radical Relay
作者:By Figula,Bryan C. Et Al
参考文献:Acs Catalysis 日期:2022 卷标:12(19) 页码:11854-11859]
98-29-3 = 98-06-6
反应条件:1.1R:H2,C:Nb2O5,C:Ir,S:544-76-3,10 H,200°C,10 Bar
标题:Selective Hydrodeoxygenation Of Lignin-Derived Phenols To Aromatics Catalyzed By Nb2O5-Supported Iridium
作者:By Jeantelot,Gabriel Et Al
参考文献:Acs Omega 日期:2022 卷标:7(35) 页码:31561-31566]
206877-36-3 = 98-06-6 + 206877-37-4
反应条件:1.1C:Alcl3,S:Benzene,S:Meno2,12 H,50°C1.2R:H2O,Cooled
标题:Synthesis And Dft Conformational Analysis Of Trimethyl-Functionalized [2.2]Metacyclophanes And Their Lewis-Acid Assisted Reactions
作者:By Islam,Md. Monarul Et Al
参考文献:Journal Of Molecular Structure 日期:2022 卷标:1266 页码:133523]
98-29-3 = 98-06-6
反应条件:1.1R:H2,C:Ir,C:Nb2O5,S:544-76-3,3 H,80°C; 2 H,250°C,10 Bar
标题:Selective Hydrodeoxygenation Of Lignin-Derived Phenols To Aromatics Catalyzed By Nb2O5-Supported Iridium
作者:By Jeantelot,Gabriel Et Al
参考文献:Chemrxiv 日期:2022 卷标:From Chemrxiv 页码:1-4]
= 98-06-6
反应条件:1.1C:12069-32-8,S:T-Buome,24 H,Reflux
标题:The Use Of Boron Carbide Powder As An Efficient Green Catalyst For Friedel-Crafts Chemistry
作者:By Dumas,Philip E. And Hunt,David A.
参考文献:Organic Communications 日期:2021 卷标:14(2) 页码:157-162]
623-26-7 + 35779-04-5 = 98-06-6 + 2919755-76-1 + 2227355-48-6
反应条件:1.1R:Tmbac,S:Mecn,3 H,Rt
标题:Electroreduction Enables Regioselective 1,2-Diarylation Of Alkenes With Two Electrophiles
作者:By Yu,Weijie Et Al
参考文献:Angewandte Chemie 日期:2023 卷标:62(17) 页码:E202219166]
3972-65-4 = 98-06-6
反应条件:1.1R:Etoh,R:T-Buok,C:2000210-47-7,S:Phme,16 H,120°C
标题:Manganese-Catalyzed Transfer Hydrodebromination Of Aryl Bromides With Ethanol
作者:By Wen,Xiaoting Et Al
参考文献:European Journal Of Organic Chemistry 日期:2023 卷标:26(8) 页码:E202201376]
3972-65-4 = 98-06-6
反应条件:1.1R:S:Acnme2,16 H
标题:Oxy-Borylenes As Photoreductants: Synthesis And Application In Dehalogenation And Detosylation Reactions
作者:By Lenz,Philipp Et Al
参考文献:Angewandte Chemie 日期:2022 卷标:61(42) 页码:E202209391]
3972-56-3 = 98-06-6
反应条件:1.1R:Hco2- na+,C:1846598-27-3,C:1569-69-3,S:Dmso,20 H,Rt1.2R:H2O,Rt
标题:Non-Innocent Radical Ion Intermediates In Photoredox Catalysis: Parallel Reduction Modes Enable Coupling Of Diverse Aryl Chlorides
作者:By Chmiel,Alyah F. Et Al
参考文献:Journal Of The American Chemical Society 日期:2021 卷标:143(29) 页码:10882-10889
8-羟基喹啉 以 N-甲基乙酰胺,水 作为反应溶剂,以62%的收率获得产物叔丁基苯
参考文献:Cation Carrier
标题:Cation Carrier
摘要:具有以下一般公式的新型聚醚:##str1## 其中r.Sub.1,R.Sub.2和r.Sub.3各代表氢原子或烷基团.当与含有阳离子的水性碱性液体接触时,该聚醚可以捕获阳离子,特别是碱金属离子,并且可以将这些阳离子释放到水性酸性液体中,因此可以作为阳离子载体.
专利信息
专利号:US-11926589-B2
优先权日:2019-07-09
标 题 :Process for the synthesis of non-racemic cyclohexenes
发明人:REISMAN SARAH; ROMBOLA MICHAEL; LADD CAROLYN L; MCLAUGHLIN MARTIN JOHN; ZUEND STEPHAN; GOETZ ROLAND
权利人:BASF CORP; CALIFORNIA INST OF TECHN
摘要:This invention relates to a process for the synthesis of a non-racemic cyclohexene compound of formula (I) by a Diels-Alder reaction of a compound of formula (II) with a compound of formula (III) wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 and Y have the meanings as defined in the description in the presence of a catalyst comprising at least one m-valent metal cation M m+ wherein the metal M is selected from Scandium (Sc), Yttrium (Y), Lanthanum (La), Cerium (Ce), Praseodymium (Pr), Neodymium (Nd), Promethium (Pm), Samarium (Sm), Europium (Eu), Gadolinium 15 (Gd), Terbium (Tb), Dysprosium (Dy), Holmium (Ho), Erbium (Er), Thulium (Tm), Ytterbium (Yb), Lutetium (Lu), Gallium (Ga) and Indium (In), and m is an integer of 1, 2 or 3, and a chiral ligand of the formula (IV) wherein R 10a , R 10b , R 10c , R 10d , R 10a′ , R 10b′ , R 10c′ , R 10d′ , Z and Z′ have the meanings as defined in the description.
专利号:US-5760237-A
优先权日:1995-08-25
标 题 :Synthesis of l-azatyrosine using pseudoephedrine as a chiral auxiliary
发明人:MYERS ANDREW G
权利人:CALIFORNIA INST OF TECHN
摘要:A practical synthesis of the potential chemotherapeutic agent L-azatyrosine is described. The key step involved the alkylation of (R,R)-(-)-pseudoephedrine glycinamide with 5-benzenesulfonyloxy-2-iodomethylpyridine and proceeded in 70-95% yield and 89-95% de. Simultaneous hydrolysis of the auxiliary and the benzenesulfonate protecting group afforded L-azatyrosine of ≧99% ee in 73% yield on multigram scale (recovery yield of (R,R)-(-)-pseudoephedrine: 90%).
专利号:US-10308588-B2
优先权日:2014-12-15
标 题 :Synthesis of amides and amines from aldehydes or ketones by heterogeneous metal catalysis
发明人:CÓRDOVA ARMANDO; PALO-NIETO CARLOS; AFEWERKI SAMSON
权利人:ORGANOFUEL SWEDEN AB
摘要:A mild and efficient synthesis of primary amines and amides from aldehydes or ketones using a heterogeneous metal catalyst and amine donor is disclosed. The initial heterogeneous metal-catalyzed reaction between the carbonyl and the amine donor components is followed by the addition of a suitable acylating agent component in one-pot, thus providing a catalytic one-pot three-component synthesis of amides. Integration of enzyme catalysis allows for eco-friendly one-pot co-catalytic synthesis of amides from aldehyde and ketone substrates, respectively. The process can be applied to asymmetric synthesis or to the co-catalytic one-pot three-component synthesis of capsaicin and its analogues from vanillin or vanillyl alcohol. A co-catalytic reductive amination/dynamic kinetic resolution (dkr) relay sequence for the asymmetric synthesis of optically active amides from ketones is disclosed. Implementation of a catalytic reductive amination/kinetic resolution (kr) relay sequence produces the corresponding optically active amide product and optical active primary amine product with the opposite stereochemistry from the starting ketones.
专利号:WO-2009018504-A1
优先权日:2007-08-01
标题 :Process for the synthesis of diaminopyridine and related compounds
发明人:RITTER JOACHIM C
权利人:DU PONT; RITTER JOACHIM C
摘要:A process is provided for the synthesis of a diaminopyridine, such as 2,6-diaminopyridine and related compounds, which are used industrially as compounds and as components in the synthesis of a variety of useful materials. The synthesis proceeds by means of a chlorine-ammonia displacement in the presence of a copper source.
专利号:US-2010143980-A1
优先权日:2007-02-22
标题:Synthesis of novel xylosides and potential uses thereof
发明人:BALAGURUNATHAN KUBERAN; MANIVANNAN ETHIRAJAN; XYLOPHONE V VICTOR; TRAN VY MY; NGUYEN KHIEM
权利人:BALAGURUNATHAN KUBERAN; MANIVANNAN ETHIRAJAN; XYLOPHONE V VICTOR; TRAN VY MY; NGUYEN KHIEM
摘要:The present invention includes a xyloside for use in inducing synthesis of a glycosaminoglycan in a cell, the xyloside having a chemical structure of one of Formula (1), Formula (2), Formula (3), Formula (4), Formula (5), Formula (6), Formula (7), Formula (8), Formula (9), or Formula (10) as shown herein. Also, the present invention includes a method of making a xyloside for use in inducing synthesis of a glycosaminoglycan in a cell, wherein the method is performed with “Clickâ€? chemistry. Additionally, the present invention includes a method of administering a xyloside so as to induce synthesis of a glycosaminoglycan in a cell.
专利号:US-10253153-B2
优先权日:2015-04-24
标题 :Linker and support for solid phase synthesis of nucleic acid, and production method of nucleic acid using said support
发明人:MAETA ERI; MORI KENJIRO; HORIE SHOHEI; ITO TAKAHIKO; SAITO SHOICHIRO; NAGAO RYUHEI
权利人:NITTO DENKO CORP
摘要:The present invention provides a linker for solid phase synthesis of nucleic acid, which consists of a compound represented by the formula (I) or the formula (II), a support for solid phase synthesis of nucleic acid, which has a structure represented by the formula (III), and a production method of a nucleic acid, which uses the support: n nwherein each symbol is as defined in the SPECIFICATION.