专利号:WO-2025079070-A1 优先权日:2023-10-11 标题:Preparation of lithium bromide and li-argyrodite 发明人:ELAZARI RAN; MASARWA MOHAMAD; KOMPANIETS IGOR; DIAMANT YISHAY; SHANDALOV ELIZABETA 权利人:BROMINE COMPOUNDS LTD 摘要:The invention provides a process for preparing anhydrous lithium bromide, comprising the steps of converting an aqueous suspension of lithium carbonate with hydrobromic acid into a solution of lithium bromide; removing residual carbon dioxide from the solution by gas-stripping, wherein the solution has acidic pH; neutrali zing the acidic lithium bromide solution by addition of lithium hydroxide to form lithium bromide brine with a nearly neutral pH; and recovering anhydrous lithium bromide from the brine. The so- formed anhydrous lithium bromide is used as a starting material in the mechanochemical synthesis of bromide-containing Li-argyrodite, which is useful in the fabrication of all-solid-state battery.
专利号:US-2012168686-A1 优先权日:2009-09-03 标 题:Continuous Synthesis of Carbon-Coated Lithium-Iron-Phosphate 发明人:METZ HANS JOACHIM; WASER OLIVER; BUECHEL ROBERT; PRATSINIS SOTIRIS E 权利人:METZ HANS JOACHIM; WASER OLIVER; BUECHEL ROBERT; PRATSINIS SOTIRIS E; CLARIANT FINANCE BVI LTD 摘要:The invention relates to a continuous process for preparing carbon-coated lithium-iron-phosphate particles, wherein the carbon-coated lithium-iron-phosphate particles have a mean (d 50 ) particle size of 10 to 150 nm, and wherein the carbon-coating is an acetylene-black coating, comprising performing in a reactor a flame-spray pyrolysis step (i) in a particle formation zone of the reactor, and a carbon-coating step (ii) in a carbon-coating zone of the reactor, wherein inn (i) a combustible organic solution containing a mixture of lithium or a lithium compound; iron or an iron compound; and phosphorus or a phosphorous compound in an organic solvent, is fed through at least one nozzle where said organic solution is dispersed, ignited and combusted, to give a flame spray thereby forming an aerosol of lithium iron phosphate particles; (ii) acetylene gas is injected into said aerosol thereby forming an acetylene-black coating on the lithium iron phosphate particles; (iii) the coated particles are cooled by an inert quench gas and collected on a filter.
专利号:US-4347254-A 优先权日:1978-04-14 标 题 :Tricyclic cage compounds, their synthesis and use as antiviral agents 发明人:KATSUBE JUNKI; SHIMOMURA HIROMI; INOKUMA SHUN; SUGIE AKIHIKO 权利人:SUMITOMO CHEMICAL CO 摘要:A compound of the formula: ##STR1## wherein A 1 is a single bond or a C 1 -C 5 alkylene group bonding at the 2-, 2'- or 3-position, A 2 is a C 1 -C 3 alkylene group, A 3 is a C 1 -C 4 alkylene group, X is --O-- or --SO n -- and B is a carboxy group, a C 2 -C 5 alkoxycarbonyl group, a cyano group, an amino group of the formula: ##STR2## or a carbamoyl group of the formula: ##STR3## which is useful as an antiviral agent with no side effect.
专利号:US-4344888-A 优先权日:1980-08-05 标题:24,25-Dihydroxycholestans and process for preparing the same 发明人:TAKAYAMA HIROAKI; YAMADA SACHIKO; OHMORI MASAYUKI 权利人:CHUGAI PHARMACEUTICAL CO LTD 摘要:A 24,25-dihydroxycholestane derivatives of the formula ##STR1## wherein A is a steroid residue and R is an aryl group and a process for preparation of the same are disclosed. The derivatives are an intermediate for synthesis of 24,25-dihydroxycholecalciferol having useful physicological activity like that of vitamin D 3 . 24,25-Dihydroxycholecalciferol can be produced in an industrially advantageous method via the intermediate which is easily prepared from commercially available starting compounds.
专利号:WO-2011026581-A1 优先权日:2009-09-03 标题:Continuous synthesis of carbon-coated lithium-iron-phosphate
专利号:CN-105693801-A 优先权日:2016-02-19 标题 :Synthesis of 3β-hydroxy-16-arylandrost-5(6),8(14),15(16)-trien-17-one
参考文献:10.1140/epje/i2019-11850-7 摘要:Fernandez de Arroiabe P, Martinez-Urrutia A, Peña X, Martinez-Agirre M, Mounir Bou-Ali M. On the thermodiffusion effect in vertical plate heat exchangers. Eur Phys J E Soft Matter. 2019 Jul 08;42(7):85. doi: 10.1140/epje/i2019-11850-7.