CAS: 1516-32-1; 1-Butylthiourea

该化合物是一种硫尿素衍生物,其特征是丁基替代成分,它增强了有机溶剂中的溶性,同时保留了强大的铬化和复杂特性;该化合物广泛用于金属离子的化学协调,特别是在分析和工业应用中;在不同的pH条件下保持稳定,并且有能力形成与过渡金属相稳定的复合体,因此在催化,腐蚀抑制和化学合成方面很有价值;硫尿素运动的存在确保了核感化替代和添加反应中的高度再活性;其明确界定的结构和一贯纯度进一步支持其在研究和专门制造过程中的使用.

结构式图片

相似化合物

109-46-6 26536-60-7 927-67-3

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ECHA物质ECHA物质C&L通报REACH预注册

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CAS号54660-80-9 6-氨基-1,3-二甲基-2,... | CAS号6276-20-6 Pseudourea,2,2'...

合成工艺路线路线简述

  • 合成目标产物 N-Butylthiourea 主要起始原料 Butyl Isothiocyanate
  • (文献来源)合成步骤主要原料 Butyl Isothiocyanate
N-Butylcarbamodithioate;Triethylazanium置于碘苯二乙酸,氨体系中,用 水,乙腈 用作溶剂,化学反应 0.5H,反应生成正丁基硫脲
参考文献:由高价碘(III)试剂促进的胺有效合成氰胺
标题:由高价碘(III)试剂促进的胺有效合成氰胺
摘要:在单罐策略中,我们已经获得了一种从二硫代氨基甲酸盐/胺开始合成有机氰胺的有效方法.在这种策略中,原位生成的烷基或芳基异硫氰酸酯是通过将二硫代氨基甲酸盐与二乙酰氧基碘苯(dib)脱硫而获得的,与氨水反应生成烷基或芳基硫脲,随后再用dib进行氧化脱硫,从而形成了相应的氰胺.产量.温和的反应条件,较短的反应时间,对环境有益的方案以及所需产物的容易分离,使得本方法学成为制备各种有机氰胺的合适替代方法.
Doi:10.1016/j.Tetlet.2009.03.017

海关参考信息

专利信息


专利号:US-10118833-B2
优先权日:2014-10-02
标 题 :Dimensionally focused nanoparticle synthesis methodology
发明人:ROBINSON RICHARD D; HANRATH TOBIAS; WILLIAMSON CURTIS; NEVERS DOUGLAS
权利人:UNIV CORNELL
摘要:A methodology for synthesizing a nanoparticle batch, such as but not limited to a metal chalcogenide nanoparticle batch and further such as but not limited to a metal sulfide nanoparticle batch is predicated upon an expectation and observation that at elevated concentrations of at least one reactant material within a heat-up nanoparticle batch synthesis method, the resulting nucleated batch comprises nanoparticles that may be dimensionally focused to provide a substantially monodisperse nanoparticle batch. The embodied methodology is also applicable to a continuous reactor. The embodied methodology also considers viscosity as a dimensionally focusing result effective variable.

专利号:US-2008004415-A1
优先权日:2004-05-03
标题 :Non-linear optically active molecules, their synthesis, and use
发明人:MCGINNISS VINCENT D; RISSER STEVEN M; DROTLEFF ELIZABETH; JIANG EDWARD; SPAHR KEVIN B
权利人:OPTIMER PHOTONICS INC
摘要:In one aspect, the present invention provides a hyperpolarizable organic chromophore. The chromophore is a nonlinear optically active compound that includes a Ï€-donor conjugated to a Ï€-acceptor through a Ï€-electron conjugated bridge. In other aspects of the invention, donor structures and acceptor structures are provided. In another aspect of the invention, a chromophore-containing polymer is provided. In one embodiment, the chromophore is physically incorporated into the polymer to provide a composite. In another embodiment, the chromophore is covalently bonded to the polymer, either as a side chain polymer or through crosslinking into the polymer. In other aspects, the present invention also provides a method for making the chromophore, a method for making the chromophore-containing polymer, and methods for using the chromophore and chromophore-containing polymer.

专利号:WO-2012010644-A1
优先权日:2010-07-23
标 题:Process for the synthesis of isothiocyanates and derivatives thereof and uses of same

专利号:US-2012059163-A1
优先权日:2005-04-28
标题 :Non-linear opticaly active molecules, their synthesis, and use
发明人:MCGINNISS VINCENT D; RISSER STEVEN M; DROTLEFF ELIZABETH; JIANG EDWARD; SPAHR KEVIN B
权利人:MCGINNISS VINCENT D; RISSER STEVEN M; DROTLEFF ELIZABETH; JIANG EDWARD; SPAHR KEVIN B; OPTIMER PHOTONICS INC
摘要:In one aspect, the present invention provides a hyperpolarizable organic chromophore. The chromophore is a nonlinear optically active compound that includes a Ï€-donor conjugated to a Ï€-acceptor through a Ï€-electron conjugated bridge. In other aspects of the invention, donor structures and acceptor structures are provided. In another aspect of the invention, a chromophore-containing polymer is provided. In one embodiment, the chromophore is physically incorporated into the polymer to provide a composite. In another embodiment, the chromophore is covalently bonded to the polymer, either as a side chain polymer or through crosslinking into the polymer. In other aspects, the present invention also provides a method for making the chromophore, a method for making the chromophore-containing polymer, and methods for using the chromophore and chromophore-containing polymer.

专利号:EP-2595953-A1
优先权日:2010-07-23
标题 :Process for the synthesis of isothiocyanates and derivatives thereof and uses of same

专利号:US-5684026-A
优先权日:1994-11-22
标 题:Aminocyclopentane derivative
发明人:OGAWA SEIICHIRO; UCHIDA CHIKARA; KIMURA HIROSHI; INOKUCHI JIN-ICHI
权利人:SEIKAGAKU KOGYO CO LTD
摘要:The present invention provides aminocyclopentane derivatives which are saccharide analogs having extremely high alpha -glucosidase inhibitory effects and novel structures and expected to be usable or applicable to drugs or agricultural chemicals. An aminocyclopentane derivative represented by the formula (1), wherein R1 represents H while R2 represents CH2OH, or R1 represents CH2OH while R2 represents H and R3 represents a substituted or unsubstituted aryl group or an alkyl, alkenyl, alkynyl or hydroxyalkyl group having 1 to 10 carbon atoms, intermediates for the synthesis of the same, a process for producing the intermediates and a process for producing the aminocyclopentane derivative.
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主要参考文献

参考标题:A One-Pot Preparation Of Cyanamide From Dithiocarbamate Using Molecular Iodine
作者:Jayashree Nath,Bhisma K. Patel,Latonglila Jamir,Upasana Bora Sinha,K. V. V. V. Satyanarayana
摘要:Method For The Synthesis Of Cyanamides From Dithiocarbamate Salts Via A Double Desulfurization Strategy Using Molecular Iodine Is Disclosed. Dithiocarbamates, By The Action Of Iodine Yield Isothiocyanates In Situ, Which On Treatment With Aqueous Nh3 Give Thioureas. The Thioureas So Generated Undergo Further Oxidative Desulfurization With I2 Giving Corresponding Cyanamides In Good Yields. Environmental

合成参考文献


摘要:National Technical Information Service., AD277-689
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