专利号:US-3978140-A 优先权日:1974-09-23 标题 :Process for the preparation of carbinols 发明人:LANE CLINTON FISHER; MYATT HAL LESLIE 权利人:ALDRICH BORANES INC 摘要:Organic compounds containing a carboxylic acid or carboxylic acid anhydride group are reduced when contacted with an alkali metal borohydride and a boron trihalide in a liquid medium in which diborane is soluble in the form of a labile borane adduct. Hydrolysis of the reaction mixture then provides a useful synthesis of the corresponding carbinols. n The alkali metal borohydride-boron trihalide reagent may either be preformed and reacted subsequently with an organic compound containing a carboxylic acid or anhydride group, or the alkali metal borohydride-boron trihalide reagent may be produced in the presence of an organic compound containing a carboxylic acid or anhydride group. This development makes it possible to synthesize a wide variety of carbinols which are valuable and useful intermediates in organic synthesis.
专利号:EP-3219701-B1 优先权日:2016-03-17 标 题:Isomer-selective synthesis of methanofullerenes
专利号:US-11192908-B2 优先权日:2018-08-17 标题:Octamolybdate compounds exhibiting bright emission 发明人:DANIELS STEVEN; PICKETT NIGEL; SAVJANI NICKY; GAVRILIUC VIRGIL 权利人:NANOCO 2D MAT LIMITED; UNIV MANCHESTER 摘要:Methods for the synthesis of a polyoxometalate compounds include heating a metal precursor in the presence of an organic salt. The polyoxometalate compounds produced herein display high photoluminescence quantum yields and photoluminescence maximums in the blue and/or violet regions of the electromagnetic spectrum.
专利号:CN-107200688-B 优先权日:2016-03-17 标 题 :Isomer-Selective Synthesis of Methylenefullerenes
专利号:EP-3219701-A1 优先权日:2016-03-17 标题:Isomer-selective synthesis of methanofullerenes
专利号:CN-107200688-A 优先权日:2016-03-17 标题:Isomer-Selective Synthesis of Methylenefullerenes
[参考文献]: Chiann-Tyng Chou, Et Al. Preparation And Evaluation Of Nickelmesogen For Micropacked Gas Chromatography. J Chromatogr A. 2004 Jul 23;1043(2):255-63.
合成参考文献
摘要:Tsuboi, S., Science of Synthesis, (2004) 7, 248. 摘要:García Ruano, J. L.; Cid, M. B.; Martín-Castro, A. M.; Alemán, J., Science of Synthesis, (2008) 39, 289.