物理性质
- 熔点176-178 °C
- 沸点56.7 °C
- 闪点89 °C
- 密度1.615
- PSA:117.66
- LogP:2.7128
- 折射率1.679
- 蒸汽压13 mbar @ 20°C
- 溶解性Insoluble
- 敏感性2,4-DINITROANILINE may decompose violently at elevated temperatures. This compound can react with oxidizing materials, i.e. chlorine/hydrochloric acid. (NTP, 1992). In mixture with powdered charcoal ignited upon heating, [Cahiers, 1980, (99), 278].
- 外观形态黄色粉末固体
- 储存条件1. 储存注意事项:应储存于阴凉,通风的库房中,并远离火种和热源.需密封包装,避免与氧化剂,酸类及食用化学品混放.配备相应种类和数量的消防器材.储区还应准备合适的材料以处理泄漏物. 2. 采用铁桶内衬塑料袋或纸板桶进行包装,每桶容量为40公斤或50公斤.贮运过程中需保持干燥,并按有毒危险品的相关规定进行贮存与运输.
- 产品应用用作偶氮染料中间体,腐蚀抑制剂,分析试剂.
- 性质描述黄色针状结晶,易燃.熔点188°C(180°C),闪点223.9°C,相对密度1.615.微溶于乙醇,不溶于水,溶于酸溶液.与稀无机酸不能形成盐类.
欧盟法规
统一分类与标签压力设备指令-第1组危险流体ECHA物质工作场所安全标识要求ECHA物质C&L通报REACH预注册废弃物危险特性清单上下游产品
pyridine 1-Amino-1-deoxy-D-glucitol 1-chloro-2,4-dinitro-benzene acetamide furan-2-carboxylic acid-(2,4-dinitro-anilide) N-2,4-Dinitrobenzol-phthalimid 6-nitroquinazolone 5-nitro-furan-2-carboxylic acid-(2,4-dinitro-anilide) 2,4-二硝基酚置于氨,水体系中,化学反应生成 2,4-二硝基苯胺
参考文献:Salkowski,Chemische Berichte,1872,Vol. 5,P. 874
标题:Salkowski,Chemische Berichte,1872,Vol. 5,P. 874
专利信息
专利号:US-2006052577-A1
优先权日:2001-02-06
标题:Methods of synthesis of polymers and copolymers from natural products
发明人:SWIFT GRAHAM; WESTMORELAND DAVID G; HUGHES KATHLEEN
权利人:SWIFT GRAHAM; WESTMORELAND DAVID G; HUGHES KATHLEEN
摘要:Described are polymers and copolymers containing sorbitol, citric acid, starch, aspartic acid, succinic anhydride, adipic acid mixtures thereof, methods of their synthesis and their uses.
专利号:US-2007249803-A1
优先权日:2004-04-28
标题:Synthesis Of Polyaniline
发明人:MATTES BENJAMIN R; GOERING RUSSELL M; ADAMS PHILLIP N; ZUCCARELLO GUIDO
权利人:SANTA FE SCIENCE AND TECHNOLOG
摘要:Methods are described for preparing substantially defect-free, adjustable molecular-weight, aniline-based polymers at sub-freezing temperatures in the absence of salts effective for lowering the freezing point of the reacting solutions, and in the absence of inorganic acids containing chlorine atoms.
专利号:US-11834389-B2
优先权日:2020-06-11
标 题 :Synthesis of n-(2,4-dinitrophenyl)-4-nitrobenzamide (TNBA) using solid acid catalysts
发明人:SCHULTZ JAMES A; SENGUPTA SOURAV KUMAR; SURISETTY VENKATESWARA RAO
权利人:DUPONT SAFETY & CONSTRUCTION INC
摘要:A method of making N-(2,4-dinitrophenyl)-4-nitrobenzamide from a mixture of 2,4-dinitroaniline, 4-nitrobenzoyl chloride, and solid acid catalyst in an organic solvent, wherein the solid acid catalyst is not soluble in the organic solvent, the solid acid catalyst being an acidic clay, an ion exchange resin, a beta zeolite, a sulfonated tetrafluoroethylene-based fluoropolymer-copolymer, or some mixture of these.
专利号:US-4411995-A
优先权日:1981-09-28
标题 :Synthesis of nicotinamide cofactors
发明人:WHITESIDES GEORGE; WALT DAVIS R
权利人:MASSACHUSETTS INST TECHNOLOGY
摘要:Nicotinamide cofactors are prepared in a process of reacting ribose -5- phosphate with a basic material selected from the group consisting of ammonia, primary and secondary amines in a polar non-aqueous solvent, reacting the resultant 1-ribosylamine -5- phosphate with a pyridinium salt and reacting the resultant nicotinamide mononucleotide with adenosine triphosphate in the presence of nicotinamide adenine dinucleotide pyrophosphorase to produce nicotinamide adenine dinucleotide which can be used directly in crude form without further purification in co-factor - requiring enzymatic reactions. The nicotinamide adenine dinucleotide pyrophosphorase may be immobilized on a solid support.
专利号:US-9643932-B2
优先权日:2011-09-26
标 题:Process for the preparation of bendamustine hydrochloride
发明人:MISHRA BHUWAN BHASKAR; KACHHADIA NIKUNJ SHAMBHUBHAI; TOMAR VINOD SINGH; LAHIRI SASWATA
权利人:FRESENIUS KABI ONCOLOGY LTD
摘要:The present invention relates to an improved process for the synthesis of bendamustine, in particular, bendamustine hydrochloride of the formula (VI) and its intermediate 1-methyl-5-[bis(2-chloroethyl)amino]-1H-benzimidazol-2-yl]lithium butanoate of formula (V), both having a purity of ≧99%, which is simple, convenient, economical, does not use hazardous chemicals and is industrially viable.
专利号:US-4257942-A
优先权日:1977-10-06
标题:New water-insoluble azo dyes
发明人:DEFEO FRANCESCO; CIPOLLI ROBERTO
权利人:ACNA
摘要:The present invention relates to the synthesis of new dyes having the following general formula: wherein: D is the residue of a diazotizable component of the carbocyclic or heterocyclic series X is an ethylene group, optionally substituted by halogen-methyl, alkyl C1-C4, aryl, aralkyl or CH2OCO(HN)nR (wherein R and n have the meanings hereinafter defined); R is alkyl C1-C8 optionally substituted by halogen, CN,COOH; aryl optionally substituted by one or more atoms of halogen, alkyl C1-C4, alkoxyl C1-C4; alkoxyl C1-C4; alkoxyl C1-C8; Aryloxy; aralkoxy; cycloalkoxy; aralkyl; naphthyl optionally substituted by halogen; alkenyl C2-C8, optionally substituted by halogen, CN, COOH; R1 and R2, either like or unlike each other, may be alkyl C1-C4 optionally substituted by halogen or CN groups; aralkyl; R3 is H; halogen, alkyl C1-C4; alkoxyl C1-C4, optionally substituted. n is 0 or 1.