CAS: 6386-38-5; Methyl 3-(3,5-Di-Tert-Butyl-4-Hydroxyphenyl)Propanoate

该化合物是一种阻塞苯酚抗氧化剂,通常用于抑制聚合物,润滑剂和其他有机材料中的氧化降解,其主要优点包括高热稳定性和有效基清除特性,因为存在与苯基氢氧基组相邻的异丁基组;这一结构特征增强了其终止自由电链反应的能力,从而扩大了易感材料的使用寿命;该化合物与各种子体的波动性低,而且适合高温应用;其酯性功能还有助于提高非极性基体的溶性.

结构式图片

欧盟法规

REACH注册ECHA物质C&L通报REACH预注册

上下游产品

CAS号67-56-1 甲醇 | CAS号20170-32-5 3,5-二叔丁基-4-羟基苯基丙酸 | CAS号128-39-2 2,6-二叔丁基苯酚 | CAS号292638-85-8 丙烯酸甲酯 | CAS号141-32-2 丙烯酸丁酯(BA) | CAS号6683-19-8 抗氧剂1010 | CAS号24676-69-5 potassium 2,6-d... | CAS号186581-53-3 重氮甲烷 | CAS号3852-09-3 3-甲氧基丙酸甲酯 | CAS号57559-03-2 | CAS号501-97-3 对羟基苯丙酸 | CAS号719-22-2 2,6-二叔丁基苯醌 | CAS号82304-66-3 7,9-二叔丁基-1-氧杂螺[... | CAS号81056-28-2 7-tert-Butyl-2-... | CAS号131692-74-5 4-hydroxy-4-(2-... | CAS号2082-79-3 抗氧剂1076 | CAS号32687-77-7 3-(3,5-二叔丁基-4-羟... | CAS号5597-50-2 对羟基苯丙酸甲酯 | CAS号36837-50-0 3-(3-叔丁基-4-羟基)苯丙酸甲酯

合成工艺路线路线简述

  • 合成目标产物 Methyl 3-(3,5-Di-Tert-Butyl-4-Hydroxyphenyl)Propionate 主要起始原料 Methanol And 3-(3,5-Di-Tert-Butyl-4-Hydroxyphenyl)Propionic Acid
  • (文献来源)合成步骤主要原料 Methanol 和 3-(3,5-Di-Tert-Butyl-4-Hydroxyphenyl)Propionic Acid
2,6-二叔丁基苯酚置于potassium Tert-Butylate,Silver Nitrate,丙烯腈体系中,化学反应生成 3,3',5,5'-四叔丁基-4,4'-联苯醌,3-(3,5-二叔丁基-4-羟基苯基)丙酸甲酯
参考文献:Baik,Woonphil; Min,Byeong Cheol; Lee,Ki Chang,Journal Of Chemical Research-Part S,1995,# 9,P. 366-367
标题:Baik,Woonphil; Min,Byeong Cheol; Lee,Ki Chang,Journal Of Chemical Research-Part S,1995,# 9,P. 366-367

海关参考信息

专利信息


专利号:US-10189951-B2
优先权日:2014-04-25
标题 :Aliphatic polyimides from a 1:2 molar ration of diamine and unsaturated monoanhydride or unsaturated diacid
发明人:DUAN YANNAN; AVAKIAN ROGER W
权利人:POLYONE CORP
摘要:Aliphatic polyimides are synthesized by a 2:1 molar ratio reaction of an unsaturated monoanhydride or an unsaturated diacid with a diamine. Bio-derived monomers are particularly useful in the synthesis of the aliphatic polyimides.

专利号:US-2017044320-A1
优先权日:2014-04-25
标题 :Aliphatic polyimides from a 1:1 molar ratio of diamine and unsaturated monoanhydride or unsaturated diacid
发明人:DUAN YANNAN; AVAKIAN ROGER W
权利人:POLYONE CORP
摘要:Aliphatic polyimides are synthesized by a 1:1 molar ratio reaction of an unsaturated monoanhydride or an unsaturated diacid with a diamine. Bio-derived monomers are particularly useful in the synthesis of the aliphatic polyimides.

专利号:EP-1633799-B1
优先权日:2003-06-03
标 题 :Production of polyether alcohols by using dmc catalysis
发明人:OSTROWSKI THOMAS; RUPPEL RAIMUND; BAUM EVA; HARRE KATHRIN
权利人:BASF SE
摘要:The present invention relates to polyetherols are prepared by a process comprising the reaction of at least one alkylene oxide with at least one initiator compound in the presence of at least one double metal cyanide compound to give a polyetherol and the treatment of the resulting polyetherol with steam or with an inert gas and steam, and the polyetherols obtainable by such a process as well as the use thereof for the synthesis of polyurethanes.

专利号:US-7504543-B2
优先权日:2004-03-18
标 题:Polyether alcohols and method for the production of polyether alcohols for polyurethane synthesis
发明人:RUPPEL RAIMUND; BAUM EVA; OSTROWSKI THOMAS; HARRE KATHRIN; BLEUEL ELKE
权利人:BASF AG
摘要:The invention relates to polyether alcohols, to a process for preparing polyether alcohols by reacting alkylene oxides in the presence of a double metal cyanide (DMC) catalyst with at least one saturated OH component which may, if appropriate, have previously been reacted with an alkylene oxide, wherein an antioxidant is added before or during the reaction, and also to the further processing of the polyether alcohols to form polyurethanes.

专利号:US-4659863-A
优先权日:1985-09-12
标 题 :Phenolic ester synthesis
发明人:BURTON LESTER P J
权利人:ETHYL CORP
摘要:A process which enhances conversion and speeds the reaction rate for the preparation of esters. Methyl acrylate and a hindered phenol are reacted (i) in the presence of an alkali metal alkaline catalyst that provides a phenolate anion and (ii) in the presence of an agent which solubilizes the phenolate to enhance the reaction rate. Excellent yields of methyl ester are obtained in a rapid reaction and by-products are minimal. The invention includes a preparation of methyl beta -(3,5-dialkyl-4-hydroxyphenyl)propionates by reaction of a hindered phenol with methyl acrylate in the presence of an alkaline catalyst and dimethyl sulfoxide present in an amount sufficient to advance the reaction rate.

专利号:CN-110452518-B
优先权日:2018-04-27
标 题:Star-like molecular structure hindered phenol compound and application thereof in synthesis of polyesteramide
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合成参考文献


摘要:Bergsträßer, U.; Hartung, J., Science of Synthesis, (2009) 38, 96.
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