CAS: 86-28-2; 9-Ethyl-9H-Carbazole

• 英文名称9-Ethyl-9H-Carbazole
• 中文名称9-乙基-9H-咔唑
• IUPAC名称9-ethyl-9H-carbazole
• 其它别名9乙基咔唑; N-Ethylcarbazole
• CAS编号86-28-2
• MFCD编号:MFCD00004967
• EINECS号:201-660-4
• FDA UNII编号:6AK165L0RO
• 分子式:C14H13N
• 分子量:195.26
• 产品CID: 1863988
• 产品分类有机原料→分子砌块→芳杂环类化合物→咔唑类化合物

• 相似结构搜索
• InChIKey: PLAZXGNBGZYJSA-UHFFFAOYSA-N
• InChI=1S/C14H13N/c1-2-15-13-9-5-3-7-11(13)12-8-4-6-10-14(12)15/h3-10H,2H2,1H3…
• 计算化学: 氢键受体数1.0氢键供体数0.0可旋转键数1.0

相似化合物

物理性质

• 熔点66-70°C
• 沸点348.3°C at 760 mmHg
• 闪点164.4°C
• 密度1.0590
• PSA:4.93
• LogP:3.8144
• 折射率1.6394
• 蒸汽压0.041-14.665Pa at 36.9-100.7°C
• 溶解性Insoluble
• 外观形态白色至灰色至棕色粉末
• 储存条件密封, 常温干燥保存
• 产品应用用作染料中间体,农业化学品,试剂.在染料工来中用来生产永固紫RL,青光海昌蓝等.
• 性质描述白色针状结晶.熔点68°C(104-105°C),沸点190°C(1.33kPa),175°C(0.67kPa).溶于热乙醇和乙醚,不溶于水.

MSDS等安全信息

• GHS象形图
• GHS符号GHS09;
  注释: Environment
• 危险类别水生慢性毒性 类别2
  特定目标器官毒性 - 单次接触 类别3
  皮肤腐蚀/刺激 类别2
  严重眼刺激 类别2
  严重眼刺激 类别2A
• 警示词Warning
• 危险描述H411 |对水生生物有毒并具有长期持续影响.
  H335 |可能引起呼吸道刺激.
  H315 |造成皮肤刺激.
  H319 |造成严重眼刺激.
• 防范说明P273-P391-P501
• 危险等级9
• UN编号3077.0
• 危险品标志Xi
• 包装等级Ⅲ
• 安全声明26-36
• 危险类别码36/37/38
• WGK Germany2

欧盟法规

上下游产品

合成工艺路线路线简述

• 合成目标产物 N-Ethylcarbazole 主要起始原料 Carbazole
• 146900-30-3 = 86-28-2
  反应条件:1.1 Catalysts: Boron Nitride; 16 H,Heated
  标题:Construction Of A Nanoporous Highly Crystalline Hexagonal Boron Nitride From An Amorphous Precursor For Catalytic Dehydrogenation
  作者:Chen,Hao; Et Al
  参考文献:Angewandte Chemie 日期:2019 卷标:58(31) 页码:10626-10630]
  
  146900-30-3 = 86-28-2
  反应条件:1.1 Catalysts: Alumina,Palladium,Rhodium,Silica; 1 H,Heated
  标题:Interheteromolecular Hyperconjugation Boosts (De)Hydrogenation For Reversible H2 Storage
  作者:Xue,Wenjie; Et Al
  参考文献:Chemsuschem 日期:2023 卷标:16(1)]
  
  1484-13-5 = 86-28-2
  反应条件:1.1 Reagents: Methanol,Sodium Hydroxide Catalysts: Platinum Solvents: Methanol; 24 H,150 °C
  标题:Methanol As A Potential Hydrogen Source For Reduction Reactions Enabled By A Commercial Pt/c Catalyst
  作者:Goyal,Vishakha; Et Al
  参考文献:Journal Of Organic Chemistry 日期:2023 卷标:88(4) 页码:2245-2259]
  
  1484-13-5 = 86-28-2
  反应条件:1.1 Catalysts: Sodium Tert-Butoxide,Iridium,[9-[[bis(1,1-Dimethylethyl)Phosphino-Kp]Oxy]Benzo[h]Quinolin-10-Yl-Kc,K... Solvents: Ethanol; 3 H,60 °C1.2 Reagents: Oxygen
  标题:Transfer Hydrogenation Of Alkenes Using Ethanol Catalyzed By A Ncp Pincer Iridium Complex: Scope And Mechanism
  作者:Wang,Yulei; Et Al
  参考文献:Journal Of The American Chemical Society 日期:2018 卷标:140(12) 页码:4417-4429]
  
  36368-72-6 = 86-28-2
  反应条件:1.1 Reagents: Lithium,Sodium Solvents: Tetrahydrofuran; Rt; Rt -> Reflux; 24 H,Reflux1.2 Reagents: Methanol; Rt
  标题:Ring Contracting Sulfur Extrusion From Oxidized Phenothiazine Ring Systems
  作者:Farmer,Steven C.; Et Al
  参考文献:Molecules 日期:2008 卷标:13(6) 页码:1345-1352]
  
  37391-52-9 = 86-28-2
  反应条件:1.1 Catalysts: Iodine Solvents: Dimethyl Sulfoxide; 8 H,100 °C1.2 Reagents: Hydrochloric Acid Solvents: Water; 1 H1.3 Reagents: Sodium Thiosulfate Solvents: Water; Overnight,5 °C
  标题:Iodine-Catalyzed Aromatization Of Tetrahydrocarbazoles And Its Utility In The Synthesis Of Glycozoline And Murrayafoline A: A Combined Experimental And Computational Investigation
  作者:Humne,Vivek; Et Al
  参考文献:Organic & Biomolecular Chemistry 日期:2014 卷标:12(27) 页码:4832-4836]
  
  = 86-28-2
  反应条件:1.1 Reagents: Sodium Hydroxide Catalysts: Benzyltributylammonium Chloride Solvents: Benzene,Water; Rt; 3 - 4 H,Reflux
  标题:Synthesis Of N-Alkyl-Carbazole-3,6-Dicarbaldehyde
  作者:Hu,Bin-Bin; Et Al
  参考文献:Huaxue Shiji 日期:2013 卷标:35(7) 页码:589-592]
  
  = 86-28-2
  反应条件:1.1 Reagents: Potassium Hydroxide Solvents: Acetone; 4 H,Reflux
  标题:Push-Pull Fluorophores With Viscosity Dependent And Aggregation Induced Emissions Insensitive To Polarity
  作者:Telore,Rahul D.; Et Al
  参考文献:Dyes And Pigments 日期:2015 卷标:122 页码:359-367]
  
  1637-16-7 = 86-28-2
  反应条件:1.1 Reagents: Lithium Solvents: Tetrahydrofuran
  标题:Lithium Cleavages Of Some Heterocycles In Tetrahydrofuran. Ii
  作者:Gilman,Henry; Et Al
  参考文献:Journal Of The American Chemical Society 日期:1958 卷标:80 页码:380-3]
  
  77989-56-1 = 86-28-2
  反应条件:1.1 Catalysts: Palladium Diacetate Solvents: Toluene; 1 H,Rt1.2 Reagents: Iodobenzene Diacetate; 3 H,Rt
  标题:Rh(Iii)-Catalyzed N-Nitroso Directed C-H Arylation For Facile Construction Of Diverse N-Hetero Biaryl Compounds
  作者:Wang,Pei-Long; Et Al
  参考文献:Chemistry - An Asian Journal 日期:2020 卷标:15(22) 页码:3825-3828]
  
  606-99-5 = 86-28-2
  反应条件:1.1 Reagents: Oxygen Catalysts: Iron(2+),Tris(1,10-Phenanthroline-Kn1,Kn10)-,(Oc-6-11)-,Salt With 1,1,1-Trifl... Solvents: Tetrahydrofuran; 0.77 H,40 Psi,Rt; 3.33 H,40 Psi,Rt1.2 Reagents: Silica
  标题:Photochemical Synthesis Of Carbazoles Using An [fe(Phen)3](Ntf2)2/o2 Catalyst System: Catalysis Toward Sustainability
  作者:Parisien-Collette,Shawn; Et Al
  参考文献:Organic Letters 日期:2016 卷标:18(19) 页码:4994-4997]
  
  606-99-5 = 86-28-2
  反应条件:1.1 Reagents: (+/-)-Propylene Oxide,Iodine Catalysts: (T-4)-(2,9-Dimethyl-1,10-Phenanthroline-Kn1,Kn10)[1,1′-(9,9-Dimethyl-9H-Xanthene... Solvents: Tetrahydrofuran; 20 H,Rt
  标题:Cu(Xantphos)(Dmp)Bf4
  作者:Hernandez-Perez,Augusto Cesar; Et Al
  参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2014 卷标:1 页码:1-3]
  
  146900-30-3 = 86-28-2
  反应条件:1.1 Catalysts: Palladium,Copper,Graphene (Oxide); 7 H,453 K
  标题:Component Controlled Synthesis Of Bimetallic Pdcu Nanoparticles Supported On Reduced Graphene Oxide For Dehydrogenation Of Dodecahydro-N-Ethylcarbazole
  作者:Wang,Bin; Et Al
  参考文献:Applied Catalysis 日期:2019 卷标:251 页码:261-272]
  
  = 86-28-2
  反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Toluene,Water; 10 Min,Rt1.2 Catalysts: Tetrabutylammonium Iodide; Reflux
  标题:Macrophage Migration Inhibitory Factor Acts As The Potential Target Of A Newly Synthesized Compound,1-(9'-Methyl-3'-Carbazole)-3,4-Dihydro-Beta-Carboline
  作者:Ko,Pin-Hao; Et Al
  参考文献:Scientific Reports 日期:2019 卷标:9(1) 页码:1-12]
  
  = 86-28-2
  反应条件:1.1 Reagents: Sodium Hydroxide Catalysts: Triethylamine Solvents: 1,2-Dichlorobenzene,Water
  标题:Process For Production Of N-Substituted Carbazoles Using Amine Catalysts
  参考文献:European Patent Organization]
  
  = 86-28-2
  反应条件:1.1 Catalysts: Potassium Methoxide
  标题:Preparation Of N-Ethylcarbazole
  参考文献:Germany]
  
  = 86-28-2
  反应条件:1.1 Reagents: Potassium Hydroxide Solvents: Dimethylformamide; 0.5 H,Rt1.2 12 H,Rt
  标题:Design And Synthesis Of Aryl-Functionalized Carbazole-Based Porous Coordination Cages
  作者:Rowland,Casey A.; Et Al
  参考文献:Chemical Communications (Cambridge 日期:2020 卷标:56(65) 页码:9352-9355]
  
  = 86-28-2
  反应条件:1.1 Catalysts: Sodium Hydroxide Solvents: Dimethylformamide,Water; 5 Min,Rt1.2 4 - 5 H,Rt
  标题:Novel Carbazole-Stilbene Hybrids As Multifunctional Anti-Alzheimer Agents
  作者:Patel,Dushyant V.; Et Al
  参考文献:Bioorganic Chemistry 日期:2020 卷标:101]
  
  146530-09-8 = 86-28-2
  反应条件:1.1 Reagents: Sodium Borohydride
  标题:New Synthesis Of Amines And Amides Mediated By Additions Of Benzotriazole To Enamines And Enamides And Transformations Of The Adducts
  作者:Katritzky,Alan R.; Et Al
  参考文献:Synthesis 日期:1992 卷标:(12) 页码:1295-8]
  
  77035-48-4 = 86-28-2
  反应条件:1.1 Reagents: Lithium,Sodium Solvents: Tetrahydrofuran; Rt; Rt -> Reflux; 24 H,Reflux1.2 Reagents: Methanol; Rt
  标题:Ring Contracting Sulfur Extrusion From Oxidized Phenothiazine Ring Systems
  作者:Farmer,Steven C.; Et Al
  参考文献:Molecules 日期:2008 卷标:13(6) 页码:1345-1352]
  
  = 86-28-2
  反应条件:1.1 Reagents: Sodium Borohydride
  标题:Reductive Aminations Of Carbonyl Compounds With Borohydride And Borane Reducing Agents
  作者:Baxter,Ellen W.; Et Al
  参考文献:Organic Reactions (Hoboken 日期:2002 卷标:59]
  
  = 86-28-2
  反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Acetone,Water; 2 H,Rt
  标题:Synthesis Of A Novel Carbazole Photoinitiator 1-[6-(2-Chlorobenzoyl)-9-Ethyl-9H-Carbazol-3-Yl]Ethanone Oxime
  作者:Chen,Qiurong; Et Al
  参考文献:Huaxue Yanjiu Yu Yingyong 日期:2008 卷标:20(5) 页码:603-605]
  
  = 86-28-2
  反应条件:1.1 Reagents: Sulfuric Acid Solvents: Acetone,Water; 5 Min,Rt; 2 H,Rt
  标题:Synthesis Of 3-Acetyl-6-Benzoyl-N-Ethylcarbazole
  作者:Feng,Yan; Et Al
  参考文献:Huaxue Yanjiu Yu Yingyong 日期:2007 卷标:19(10) 页码:1162-1165]
  
  608534-41-4 = 86-28-2
  反应条件:1.1 Reagents: Phenyllithium Solvents: Diethyl Ether,Butyl Ether; Rt -> 0 °C; 30 Min,0 °C -> Rt1.2 Reagents: Thiophenol Catalysts: Iridium(1+),[4,4′-Bis(1,1-Dimethylethyl)-2,2′-Bipyridine-Kn1,Kn1′]Bis[3,5-Diflu... Solvents: Methanol,Acetone; 16 H,Rt
  标题:Catalytic Protodeboronation Of Pinacol Boronic Esters: Formal Anti-Markovnikov Hydromethylation Of Alkenes
  作者:Clausen,Florian; Et Al
  参考文献:Chemical Science 日期:2019 卷标:10(24) 页码:6210-6214]
  
  1637-16-7 = 86-28-2
  反应条件:1.1 Reagents: Lithium,Sodium Solvents: Tetrahydrofuran; Rt; Rt -> Reflux; 24 H,Reflux1.2 Reagents: Methanol; Rt
  标题:Ring Contracting Sulfur Extrusion From Oxidized Phenothiazine Ring Systems
  作者:Farmer,Steven C.; Et Al
  参考文献:Molecules 日期:2008 卷标:13(6) 页码:1345-1352]
  
  = 86-28-2
  反应条件:1.1 Catalysts: P-Toluenesulfonic Acid Solvents: Toluene; 3 H,80 °C
  标题:Synthesis Of Carbazole Alkaloids By Ring-Closing Metathesis And Ring Rearrangement-Aromatization
  作者:Dhara,Kalyan; Et Al
  参考文献:Angewandte Chemie 日期:2015 卷标:54(52) 页码:15831-15835]
  
  606-99-5 = 86-28-2
  反应条件:1.1 Reagents: (+/-)-Propylene Oxide,Iodine Catalysts: (T-4)-(2,9-Dimethyl-1,10-Phenanthroline-Kn1,Kn10)[1,1′-(9,9-Dimethyl-9H-Xanthene... Solvents: Tetrahydrofuran; 20 H,Heated1.2 Reagents: Sodium Thiosulfate Solvents: Water
  标题:A Visible-Light-Mediated Synthesis Of Carbazoles
  作者:Hernandez-Perez,Augusto C.; Et Al
  参考文献:Angewandte Chemie 日期:2013 卷标:52(48) 页码:12696-12700

海关参考信息

• 2902200000-苯
  2901100000-饱和无环烃
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• ➥ 象形图和危险代码
• ➥ 防范代码详解
• ➥ 危险代码说明
• ➥ Globally Harmonized System
• ➥ REACH监管