专利号:US-10676423-B2 优先权日:2017-02-21 标题 :Structure and synthesis of highly fluorinated amino acid derivatives 发明人:WEAVER JIMMIE DEAN; TEEGARDIN KIP ALLEN; ARORA AMANDEEP 权利人:UNIV OKLAHOMA STATE 摘要:Methods of synthesizing polyfluorinated amino acid derivatives are disclosed, along with polyfluorinated amino acid derivatives produced from said methods, as well as compositions containing same. The synthesis methods utilize an oxazolone and a perfluoroarene to produce the polyfluorinated amino acid derivatives.
专利号:WO-9714698-A1 优先权日:1995-10-18 标题:Synthesis of perfluoroaryl-substituted compounds 发明人:FRAZIER KEVIN A 权利人:DOW CHEMICAL CO 摘要:Perfluoroaryl-substituted compounds are prepared from perfluoroaryl compounds, particularly tris pentafluorophenyl borane is prepared from hexafluorobenzene. The method comprises contacting a perfluoroaryl compound with an organomagnesium reagent in the presence of a catalyst to form a perfluoroaryl magnesium compound, and contacting the perfluoroaryl magnesium compound with a trihalide element to form a tris perfluoroaryl-substituted compound.
专利号:US-5026929-A 优先权日:1990-02-08 标题:Synthesis of highly fluorinated aromatic compounds 发明人:MARSELLA JOHN A; PEZ GUIDO P; COUGHLIN ANNE M 权利人:AIR PROD & CHEM 摘要:A process is disclosed for making a highly fluorinated aromatic compound by contacting a perfluorocycloalkane, such as perfluorodecahydronaphthalene, with a complex of a metal from Groups IA and IIA of the Periodic Table and an organic electron acceptor. The reaction is carried out in an organic solvent and under reducing conditions which are relatively moderate. Best results are obtained using a perfluorocycloalkane having 2-4 condensed rings and a complex of either sodium or lithium and benzophenone thereby making a perfluorinated condensed ring aromatic compound such as perfluoronaphthalene or perfluorophenanthrene.
专利号:US-2020123099-A1 优先权日:2017-02-21 标题 :Structure and Synthesis of Highly Fluorinated Amino Acid Derivatives
专利号:WO-2018156500-A1 优先权日:2017-02-21 标题 :Structure and synthesis of highly fluorinated amino acid derivatives
专利号:CN-117585647-B 优先权日:2023-11-24 标 题:Application of molecular eutectic material in photocatalytic synthesis of hydrogen peroxide
[参考文献]: Leila Hejazi, Et Al. Gas Chromatography With Parallel Hard And Soft Ionization Mass Spectrometry. Rapid Commun Mass Spectrom. 2015 Jan 15;29(1):91-9.
合成参考文献
摘要:Zhang, F.-L.; Wang, Y.-F., Science of Synthesis, (2021) , 387. 摘要:S25 | OECDPFAS | List of PFAS from the OECD | DOI:10.5281/zenodo.2648775