专利号:US-5629394-A 优先权日:1992-12-17 标 题 :Direct synthesis by living cationic polymerization of nitrogen-containing polymers 发明人:CHERADAME HERVE M; CHEN FRANK J; STANAT JON E R; NGUYEN HUNG A; TABAR BEHROOZ R 权利人:EXXON CHEMICAL PATENTS INC 摘要:A method is provided for the direct synthesis by living cationic polymerization of novel polymeric materials functionalized with desirable nitrogen-containing functional groups such as terminal azido, cyano, carbonylamino, cyanato, thiocyanato or thiocarbonylamino groups. Polymerization and functionalization occur in a substantially simultaneous manner. All necessary reactants for the functionalization are present when polymerization is initiated. The nitrogen-containing functional group is provided as a part of a molecule having a release moiety which is preferably resonance stabilized or a tertiary alkyl type and which acts to aid the nitrogen-containing species in functioning as a leaving group.
专利号:US-5336745-A 优先权日:1988-06-28 标题 :Terminally-substituted polymeric compositions from cationically polymerizable monomers and initiators 发明人:CHERADAME HERVE M; LUNDBERG ROBERT D; CHEN FRANK J; HABIMANA JEAN DE LA CROIS 权利人:EXXON CHEMICAL PATENTS INC 摘要:A method is provided for the direct synthesis of novel polymeric materials functionalized with desirable nitrogen-containing functional groups such as terminal azido, cyano, carbonylamino or thiocarbonylamino groups. Polymerization and functionalization occur in a substantially simultaneous manner. All necessary reactants for the functionalization are present when polymerization is initiated. The nitrogen-containing functional group is provided as a part of a molecule having a release moiety which is preferably resonance stabilized or of tertiary alkyl type and which acts to aid the nitrogen-containing species in functioning as a leaving group.
专利号:WO-2023065714-A1 优先权日:2021-10-20 标题:Pyrimidine- and cyano group-based bifunctional conjugated microporous polymer, and preparation method therefor and application thereof 发明人:CHEN FEIHONG; LIN JUQIN; REN SHIBIN 权利人:ZHEJIANG SHIJIAN NEW MAT CO LTD; UNIV TAIZHOU 摘要:The present invention relates to the technical field of organic synthesis, and provides a pyrimidine- and cyano group-based bifunctional conjugated microporous polymer, and a preparation method therefor and an application thereof. The pyrimidine- and cyano group-based bifunctional conjugated microporous polymer in the present invention has a structural unit as shown in the following formula. According to the pyrimidine- and cyano group-based bifunctional conjugated microporous polymer in the present invention, bifunctionalization based on both a pyrimidine and a cyano group is carried out, and substance types of conjugated microporous polymers are increased. Moreover, the pyrimidine- and cyano group-based bifunctional conjugated microporous polymer contains a pyrimidine group and a cyano group, and thus has excellent catalytic activity on photolysis of water to produce hydrogen.
专利号:CN-113200887-B 优先权日:2021-05-17 标题:A kind of 'D-A-D' type organic hole transport material with cyanostyrene as core and its synthesis method and application
专利号:CN-113200887-A 优先权日:2021-05-17 标题 :A kind of 'D-A-D' type organic hole transport material with cyanostyrene as core and its synthesis method and application
专利号:EP-0349195-B1 优先权日:1988-06-28 标 题:Direct synthesis by cationic polymerization of nitrogen-containing polymers
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