CAS: 123-05-7; 2-Ethylhexanal

上下游产品

2-乙基-己酸稀土盐 2-Ethylhexanoic Acid 149-57-5
2-乙基己酰氯 2-Ethylhexanoic Acid Chloride 760-67-8

2-乙基己醇置于barium Permanganate体系中,用 乙腈 用作溶剂,化学反应 3.0H,以40%的收率获得2-乙基已基醛
参考文献:高锰酸钡,Ba(mno 4)2,一种在质朴和非水条件下使用的通用轻度氧化剂
标题:高锰酸钡,Ba(mno 4)2,一种在质朴和非水条件下使用的通用轻度氧化剂
摘要:高锰酸钡是一种易于制备,稳定且用途广泛的氧化试剂.用这种试剂,将不同类型的伯羟基和仲羟基化合物转化为它们的羰基衍生物.醛可以转化为其羧酸.氯化苄和溴化物被转化为醛和羧酸.苄基羰基化合物的氨基脲和2,4-二硝基苯肼衍生物选择性地进行碳-氮键裂解,并生成预期的羰基化合物.对苯二酚转化为对苯二酚-苯并胍基酮和芳族胺形成其偶氮化合物.蒽和菲产生它们的9,10-醌.二苯基乙炔和反式二苯乙烯生成苯甲酰,而苯乙烯生成苯甲醛.发生仲苄基碳氢键的选择性氧化,并以高收率生产相应的羰基化合物.
Doi:10.1016/s0040-4020(01)87874-1

专利信息

专利号:US-2010099894-A1
优先权日:2006-10-09
标 题 :Method for the Synthesis of Cyclic Acetals by the Reactive Extraction of a Polyol in a Concentrated Solution
发明人：DUBOIS JEAN-LUC; IBORRA CHORNET SARA; VELTY ALEXANDRA I LUCIENNE; CORMA CANOS AVELINO
权利人:DUBOIS JEAN-LUC; IBORRA CHORNET SARA; VELTY ALEXANDRA I LUCIENNE; CORMA CANOS AVELINO
摘要:A method for the synthesis of cyclic acetals comprises reacting at least one carbonyl-function compound selected from aldehydes, ketones, and/or linear acetals, on a polyol in a concentrated aqueous solution exceeding 20 wt % in a reactor containing an acidic catalyst. The carbonyl-function compound is selected so that the cyclic acetal obtained has a water solubility lower than 20000 mg/kg. During the catalytic reaction for the cyclic acetal synthesis, at least one portion of the organic phase containing the cyclic acetal is separated. The acidic catalysis is either homogeneous when using a water-soluble strong acid, or heterogeneous when using a solid acid such as a resin, a zeolite, or any appropriately acidified solid. The extractive reaction method can be used for obtaining high conversions and selectivity.

专利号:US-5484949-A
优先权日:1993-01-29
标题:Method for the synthesis of α β-unsaturated ketones
发明人：TSUKASHIMA KEIICHI; NAKAJIMA MASASHI; FUJIMARU MASAYOSHI; SUZUKI KENJI
权利人:NIPPON SODA CO
摘要:The present invention relates to a method for the synthesis of alpha , beta -unsaturated ketones which comprises, in the method for the synthesis of alpha , beta -unsaturated ketones represented by general formula reacting aldehydes represented by general formula R1CHO (where R1 is as defined above) with alkali metal salt of acetoacetic acid represented by general formula sence as a catalyst of 3-azabicyclo[3,2,2]nonane, a cyclic secondary amine represented by general formula (1) (1) a cyclic secondary amine represented by general formula (2) (2) (where, l is 1 or more and up to 6, a ring with N is a 6-membered, 7-membered or 8-membered ring, the two neighbors of N are methylene, R3 is a lower alkyl group, its substitution position is at a carbon atom other than two those adjacent to N, and is an alicyclic group or a phenol group), or a secondary amine represented by general formula (3) CH3NHCH2R4(3) in a mixuture solvent of water and water-insoluble organic solvent, while keeping the pH constant with mineral acid, and by adjusting an amount of water.

专利号:US-2023287032-A1
优先权日:2020-08-14
标 题:Synthesis of fluorinated nucleotides
发明人：CHUNG CHEOL KEUN; LIU ZHIJIAN; MALIGRES PETER E; MAO EDNA; OBLIGACION JENNIFER V; PHILLIPS ERIC M; PIRNOT MICHAEL; POIRIER MARC; SONG ZHIGUO JAKE; WANG TAO
权利人:CHUNG CHEOL KEUN; LIU ZHIJIAN; MALIGRES PETER E; MAO EDNA; OBLIGACION JENNIFER V; PHILLIPS ERIC M; PIRNOT MICHAEL; POIRIER MARC; SONG ZHIGUO JAKE; WANG TAO; MERCK SHARP & DOHME LLC
摘要:The present invention relates to efficient processes useful in the preparation of fluorinated nucleosides, such as (O—{[(2R,3R,4S,5R)-5-(6-amino-9H-purin-9-yl)-4-fluoro-3-hydroxyoxolan-2-yl]methyl}O,O-dihydrogen phosphorothioate, also known as 2′-(S)-fluoro-thio-adenosine monophosphate or 2′-F-thio-AMP. Such fluorinated nucleosides may be useful as a biologically active compound and or as an intermediate for the synthesis of more complex biologically active compounds. The present invention also encompasses intermediates useful in the disclosed synthetic processes and the methods of their preparation.

专利号:US-6800783-B2
优先权日:2000-03-04
标题:Method for the synthesis of aliphatic carboxylic acids from aldehydes
发明人：SPRINGER HELMUT; LAPPE PETER
权利人:CELANESE CHEM EUROPE GMBH
摘要:The invention relates to a method for the synthesis of aliphatic carboxylic acids by the catalytic oxidation of aldehydes with oxygen, or oxygen-containing gas mixtures. Metals of groups 5 11 of the periodic table of elements, or the compounds thereof are used as catalyst, in amounts of up to 5 ppm, based upon the amount of aldehyde used.

专利号:US-5504229-A
优先权日:1993-08-10
标题 :Synthesis of aliphatic C2 -C22 carboxylic acids
发明人：FISHER KARL; FRITZ GERHARD
权利人:BASF AG
摘要:Synthesis of aliphatic C 2 -C 22 carboxylic acids by oxidation of relevant aldehydes with oxygen in the presence of alkali metal compounds or alkaline earth metal compounds in the liquid phase and separation of the reaction mixture by distillation, in which the bottom product formed during distillation and containing an alkali metal salt or alkaline earth metal salt is recycled to the oxidation stage.

专利号:US-6680395-B2
优先权日:2000-03-04
标 题:Method for the synthesis of straight-chain aliphatic carboxylic acids from aldehydes
发明人：SPRINGER HELMUT
权利人:CELANESE CHEM EUROPE GMBH
摘要:The invention relates to a non-catalysed method for the synthesis of straight-chain aliphatic carboxylic acids by oxidation of straight-chain aldehydes with oxygen-containing gas mixtures. The invention is characterised in that during the novel process of oxidation branched aldehydes are present in the reaction mixture.