CAS: 25309-64-2; 1-Ethyl-4-Iodobenzene

上下游产品

CAS号13329-40-3 4'-碘代苯乙酮 | CAS号100-41-4 乙苯 | CAS号589-16-2 4-乙基苯胺 | CAS号98-69-1 4-乙基苯磺酸 | CAS号2351-50-0 4-碘苯乙烯 | CAS号7553-56-2 碘 | CAS号7697-37-2 硝酸 | CAS号64-19-7 冰醋酸 | CAS号40307-11-7 4-乙基苯乙炔 | CAS号92-52-4 联苯 | CAS号5707-44-8 4-乙基联苯 | CAS号937-30-4 对乙基苯乙酮 | CAS号139-66-2 苯硫醚 | CAS号132260-92-5 bis(4-ethylphen... | CAS号29778-20-9 1-ethyl-4-(2-ph... | CAS号96220-15-4 3-(4-乙基苯基))-3-氧丙腈 | CAS号591-50-4 碘苯

4-碘代苯乙酮置于三乙基硅烷,Indium(III) Bromide体系中,用 氯仿 用作溶剂,化学反应 1.0H,以96%的收率获得1-乙基-4-碘苯
参考文献:Inbr 3催化的氢化硅烷还原酮:芳族酮的脱氧和由脂肪族酮选择性合成仲醇和对称醚
标题:Inbr 3催化的氢化硅烷还原酮:芳族酮的脱氧和由脂肪族酮选择性合成仲醇和对称醚
摘要:开发了inbr 3-Et 3 Sih还原系统,以中等至非常好的收率选择性地将脂肪族酮转化为多种仲醇.最初混合inbr 3和phsih 3,然后添加脂族酮和溶剂,得到对称的醚衍生物.
Doi:10.1016/j.Tetlet.2011.04.029

专利信息

专利号:US-7102023-B2
优先权日:1999-11-24
标 题:Protecting groups useful in the synthesis of polysaccharides, natural products, and combinatorial libraries
发明人：BUCHWALD STEPHEN L; PLANTE OBADIAH J; SEEBERGER PETER H
权利人:MASSACHUSETTS INST TECHNOLOGY
摘要:One aspect of the present invention relates to optionally substituted halogenated benzyl halides and the like. These compounds are useful as halogenated benzyl ether-based protecting groups for a variety of functional groups. Another aspect of the present invention relates to use of said protecting groups in an orthogonal protecting group strategy for the synthesis of complex molecules that comprise a number of suitable functional groups. Another aspect of the present invention relates to saccharides bearing various arrays of protecting groups of the present invention. Another aspect of the present invention relates to a method of synthesizing an oligosaccharide or glycoconjugate, comprising the steps of: using a saccharide bearing at least one protecting group of the present invention to glycosylate a second molecule to give a product comprising said saccharide; and removing a protecting group of the present invention from said product.

专利号:US-6608196-B2
优先权日:2001-05-03
标题 :Process for solid supported synthesis of pyruvate-derived compounds
发明人：WANG BING; JANAGANI SATYANARAYANA; CALLAWAY WYETH B; SESSLER JONATHAN L
权利人:GALILEO PHARMACEUTICALS INC
摘要:Provided are processes for synthesizing structurally diverse pyruvate-derived compounds using a parallel approach on a solid phase support. Examples of such a solid phase support include resins which have also been used in solid phase peptide synthesis.

专利号:US-6359144-B1
优先权日:1997-02-04
标 题 :Combinatorial libraries of bicyclic guanidine derivatives and compounds therein
发明人：OSTRESH JOHN M; MEYER JEAN-PHILIPPE; DOOLEY COLETTE T; BLONDELLE SYLVIE E; SCHONER CHRISTA C; HOUGHTEN RICHARD A
权利人:LION BIOSCIENCE AG
摘要:The invention provides a rapid approach for combinatorial synthesis and screening of combinatorial libraries of bicyclic guanidine compounds. The present invention further provides the compounds made by the combinatorial synthesis and individually as well as methods of using the same.

专利号:US-9475756-B2
优先权日:2012-03-05
标题:Difluoromethylation of aryl and vinyl iodides
发明人：HARTWIG JOHN; FIER PATRICK
权利人:UNIV CALIFORNIA
摘要:Selectively fluorinated molecules are important as materials, pharmaceuticals, and agrochemicals, but their synthesis by simple, mild, laboratory methods is challenging. We report a straightforward method for the cross-coupling of a difluoromethyl group with readily available reagents to form difluoromethylarenes. The reaction of electron-neutral, electron rich, and sterically hindered aryl and vinyl iodides with the combination of CuI, CsF and TMSCF 2 H leads to the formation of difluoromethylarenes in high yield with good functional group compatibility. This transformation is surprising, in part, because of the prior observation of the instability of CuCF 2 H.

专利号:US-6482921-B1
优先权日:1999-01-28
标题:Uridyl peptide antibiotic (UPA) derivatives, their synthesis and use
发明人：BOOJAMRA CONSTANTINE G; LEMOINE REMY C; HECKER SCOTT; LEE VING J; LEGER ROGER
权利人:ESSENTIAL THERAPEUTICS INC
摘要:The present invention relates to dihydro derivatives of the uridyl peptide antibiotics mureidomycin, pacidimycin and napsamycin which have antibiotic activity against a number of bacterial strains including strains resistant to current therapeutic antibiotics.

专利号:CN-107954908-B
优先权日:2017-12-10
标 题:Under a kind of microwave radiation in water phase benzene thiocarbamide catalytic synthesis of diaryl thioether method