CAS: 1591-31-7; 4-Iodo-1,1'-Biphenyl

相似化合物

3001-15-8 20442-79-9 105946-82-5

上下游产品

CAS号92-52-4 联苯 | CAS号92-66-0 4-溴联苯 | CAS号5122-94-1 4-联苯硼酸 | CAS号140-29-4 苯乙腈 | CAS号92-67-1 4-氨基联苯 | CAS号624-38-4 1,4-二碘苯 | CAS号71-43-2 苯 | CAS号1514-50-7 4-Iodobenzenedi... | CAS号98-80-6 苯硼酸 | CAS号3073-05-0 对五联苯 | CAS号135-70-6 对四联苯 | CAS号4499-83-6 对六联苯 | CAS号5122-94-1 4-联苯硼酸 | CAS号92-93-3 4-硝基联苯 | CAS号92-69-3 4-苯基苯酚 | CAS号92-66-0 4-溴联苯 | CAS号210885-00-0 3-联苯-4-丙炔-1-醇 | CAS号21326-80-7 1,2-二([1,1'-联苯]... | CAS号92-92-2 4-苯基苯甲酸

联苯置于nickel(II) Chloride Hexahydrate,三氟乙酸酐,Sodium Iodide,锌体系中,用 N,N-二甲基乙酰胺,乙腈 用作溶剂,化学反应 16.0H,反应生成4-碘联苯
参考文献:镍遇到芳基噻蒽盐:Ni(I)-催化的芳烃卤化
标题:镍遇到芳基噻蒽盐:Ni(I)-催化的芳烃卤化
摘要:在此,报道了一种区域选择性的后期两步芳烃卤化方法.我们提出了如何通过芳基噻蒽和 Ni 氧化还原特性的组合实现不寻常的 Ni(I)/(III) 催化,这是迄今为止其他(伪)卤化物无法实现的.该催化剂可从廉价的 Nicl 2 .6(H 2 O) 和锌原位获得,无需支持配体.
Doi:10.1021/jacs.3C02611

专利信息

专利号:US-2015239796-A1
优先权日:2014-02-19
标题:One pot synthesis of 18f labeledtrifluoromethylated compounds with difluoro(iodo)methane
发明人：RüHL THOMAS; RISS PATRICK; RAFIQUE WAQAS
权利人:UNIV OSLO
摘要:The present invention relates to compositions and methods for the synthesis of 18 F labeled compounds. In particular, the present invention relates to a copper (I) mediated one pot method for 18 F-trifluoromethylation of aromatic- or heteroaromatic halides with difluoro(iodo)methane (e.g., for use at PET imaging agents).

专利号:WO-2017051326-A1
优先权日:2015-09-23
标 题 :New processes and intermediates useful in synthesis of nep inhibitors
发明人：MARTIN BENJAMIN; PENN GERHARD; SCHENKEL BERTHOLD; BOURNE SAMUEL; LAU SHING-HING; LEY Steven
权利人:NOVARTIS AG; MARTIN BENJAMIN; PENN GERHARD; SCHENKEL BERTHOLD; BOURNE SAMUEL; LAU SHING-HING; LEY Steven
摘要:The invention relates to a novel process, novel process steps and novel intermediates useful in the synthesis of pharmaceutically active compounds, in particular neutral endopeptidase (NEP) inhibitors such as sacubitril, and prodrugs thereof.

专利号:US-2016317682-A1
优先权日:2015-04-30
标题:PREPARATION OF Ag18F AND ITS USE IN THE SYNTHESIS OF PET RADIOTRACERS
发明人：SCOTT PETER J H; BROOKS ALLEN F; ICHIISHI NAOKO; SANFORD MELANIE S
权利人:UNIV MICHIGAN REGENTS; THE REGENTS OFTHE UNIV OF MICHIGAN
摘要:Copper-catalyzed radiofluorination of aryl iodides using Ag 18 F, methods of preparing Ag 18 F, and compounds obtained by copper-catalyzed radiofluorination of aryl iodides using Ag 18 F are disclosed. Diagnostic and therapeutic methods involving such compounds also are disclosed.

专利号:US-4348525-A
优先权日:1981-04-09
标题 :Composition and a process for the preparation of [hydroxy(organosulfonyloxy)iodo]arenes and their use in a regiospecific synthesis of diaryliodonium salts
发明人：KOSER GERALD F; WETTACH RICHARD H
权利人:UNIV AKRON
摘要:[Hydroxy(organosulfonyloxy)iodo]arenes are synthesized in neutral organic solvents by the reaction of ring-substituted [hydroxy(organosulfonyloxy)iodo]benzenes with iodoarenes via ligand transfer. The produced compounds are reacted with (triorganosilyl) arenes or (trihalosilyl)arenes in neutral organic solvents to produce diaryliodonium salts. The diaryliodonium salt synthesis proceeds in regiospecific fashion, aryliodination occurring at the point of attachment of the silicon atom in the silylarenes.

专利号:US-4826635-A
优先权日:1981-04-09
标题:Composition and a process for the preparation of (hydroxy (organosulfonyloxy)iodo)arenes and their use in a regiospecific synthesis of diaryliodonium salts
发明人：KOSER GERALD F; WETTACH RICHARD H
权利人:UNIV AKRON
摘要:[Hydroxy(organosulfonyloxy)iodo]arenes are synthesized in neutral organic solvents by the reaction of ring-subsituted [hydroxy(organosulfonyloxy)iodo]benzenes with iodoarenes via ligand transfer. The produced compounds are reacted with (triorganosilyl) arenes or (trihalosilyl)arenes in neutral organic solvents to produce diaryliodonium salts. The diaryliodonium salt synthesis proceeds in regiospecific fashion, aryliodination occurring at the point of attachment of the silicon atom in the silylarenes.

专利号:US-10865163-B2
优先权日:2017-12-20
标题:Carbon dioxide as a directing group for C—H functionalization reactions involving Lewis basic amines, alcohols, thiols, and phosphines for the synthesis of compounds
发明人：YOUNG MICHAEL C; KAPOOR MOHIT
权利人:UNIV TOLEDO
摘要:Methods of synthesizing compounds using CO 2 as a directing group for C—H functionalization, and compounds made thereby, are described.