CAS: 55-38-9; Fenthion

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CAS号3761-41-9 倍硫磷亚砜 | CAS号14086-35-2 倍硫磷氧砜 | CAS号14143-28-3 Phenol, 3-methy... | CAS号6552-12-1 倍硫磷-氧 | CAS号6552-13-2 倍硫磷氧亚砜

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    Dimethyl-(3-Methyl-4-Methylthiophenyl)Phosphite置于sulfur体系中,化学反应 3.0H,以73%的收率获得产物倍硫磷
    参考文献:Synthesis Of [35S]Phosphorothionate Insecticides : The Example Of [35S] Fenthion
    标题:Synthesis Of [35S]Phosphorothionate Insecticides : The Example Of [35S] Fenthion
    摘要:以 [35S]Fenthion 为例,提出了合成 [35S]Phosphorothionates 的一般方法.该方法包括使分子 35S 与相应的膦酸盐反应,这些膦酸盐很容易从商用前体中制备出来.
    DOI:10.1002/jlcr.2580340110

    海关参考信息

    专利信息


    专利号:US-5635155-A
    优先权日:1993-04-02
    标 题:Hydrothermal synthesis of octahedral molecular sieve
    发明人:O'YOUNG CHI-LIN; SHEN YAN-FEI; ZERGER RICHARD P; SUIB STEVEN L
    权利人:TEXACO TEXACO INC
    摘要:A process of synthesizing synthetic manganese oxide hydrates having various structures including hollandite and todorokite structure by hydrothermal synthesis. The products have a high degree of crystallinity, and thermal stability.

    专利号:WO-2025056767-A1
    优先权日:2023-09-15
    标题 :Process for the preparation of enantiomerically enriched aliphatic amines
    发明人:BOU HAMDAN FARHAN; GODINEAU EDOUARD; SMEJKAL TOMAS; DUMEUNIER RAPHAEL; BOUSSEMGHOUNE MOHAMED ABDELOUAHAB; BLUM MATHIAS
    权利人:SYNGENTA CROP PROTECTION AG
    摘要:The present invention relates to a process for the preparation of enantiomerically enriched cyclobutylamines of formula (I) from α-tertiary cyclobutanones and reacting said enantiomerically enriched cyclobutylamines to enantiomerically enriched cyclobutylamides. Such compounds are useful intermediates in the synthesis of microbiocidal thiazole compounds.

    专利号:US-9468207-B2
    优先权日:2012-04-12
    标 题 :Insecticide and acaricide paints that inhibit chitin synthesis, regulate insect juvenile hormone and repel arthropods, for controlling endemic diseases, pests and allergens
    发明人:MATEO HERRERO MARIA PILAR
    权利人:MATEO HERRERO MARIA PILAR
    摘要:The present invention relates to insecticide and acaricide paints that inhibit chitin synthesis, regulate insect juvenile hormone and repel arthropods, for controlling endemic diseases, pests and allergens. The paints comprise at least the following compounds (in any combination): 1%-100% water, 0.0001%-20% insecticides, 0.0001%-20% chitin inhibitor, 0.0001%-20% juvenile hormone regulator, 1%-50% polymers, 0%-40% pigments, 0%-60% fillers, 0%-60% natural repellents, and 0.01%-20% stabilizers. The composition of the paints allows the active ingredients to be encapsulated in an aqueous polymer with or without the incorporation of fillers and pigments, and therefore the range of use thereof is increased.

    专利号:US-2007232495-A1
    优先权日:2006-03-24
    标题:Compositions and methods to add value to plant products, increasing the commercial quality, resistance to external factors and polyphenol content thereof
    发明人:NAPPA ALVARO O; LORENZINI FELIPE C; SANHUEZA ANDRES L
    权利人:NAPPA ALVARO O; LORENZINI FELIPE C; SANHUEZA ANDRES L
    摘要:The invention is related to compositions and methods that naturally protect plant tissues against ultraviolet radiation and temperature, thus giving protection against sunburn to plants, plant parts, fruits and/or flowers during their development. The invention is also related to compositions and methods to naturally improve the color of plants, plant parts, fruits and/or flowers by inducing the natural synthesis of flavonoids and anthocyanins present in plants. Likewise, the present invention is directed to improving the nutritional value of plants, plant parts, fruits and/or flowers by increasing the normal levels of polyphenolic compounds, especially flavonoids, present therein. Additionally, the present invention is related to compositions and methods that give more resistance to plants, plant parts, fruits and/or flowers against pathogens as bacteria and fungi. Finally, the present invention is related to plants, plant parts, fruits, flowers and/or propagating material treated with the compositions described in the present document.

    专利号:WO-2021074309-A1
    优先权日:2019-10-16
    标 题:1-(3-quinolyl)-3,4-dihydroisoquinoline derivatives as fungicides for combating specific phytopathogens
    发明人:WEISS MATTHIAS; QUARANTA LAURA; BOU HAMDAN FARHAN; MAHAJAN ATUL; WILLIAMS SIMON; KILARU JAGADEESH; SEN INDIRA; BIERI STEPHANE; DIGGELMANN MARTIN
    权利人:SYNGENTA CROP PROTECTION AG
    摘要:1-(3-quinolyl)-3,4-dihydroisoquinoline derivatives of formula (I) as well as a method of combating, preventing or controlling the phytopathogens Mycosphaerella graminicola (Septoria tritici), Fusarium culmorum, Gibberella zeae (Fusarium graminearum) and Monographella nivalis (Microdochium nivale), which comprises applying to the phytopathogen, to the locus of the phytopathogen, or to a plant susceptible to attack by the phytopathogen, or to propagation material thereof, a fungicidally effective amount of a 1-(3-quinolyl)-3,4-dihydroisoquinoline derivative of formula (I). The present description discloses the synthesis of exemplary compounds, formulation examples, relevant biological data (antifungal activity against Mycosphaerella graminicola (Septoria tritici), Fusarium culmorum, Gibberella zeae (Fusarium graminearum) and Monographella nivalis (Microdochium nivale) when spayed on plants), as well as comparative data against three prior art compounds (e.g. pages 52 to 85; formulation examples; examples A1 to A3; table E; compounds E.01 to E.187; biological examples). Exemplary compounds are e.g.: 5-bromo-1-(8-fluoro-3-quinolyl)spiro[4H-isoquinoline-3,1'- cyclopropane] (example A1) 5-bromo-1-(8-fluoro-3-quinolyl)-3,3-dimethyl-4H-isoquinoline (example A2) 1-(8-fluoro-3-quinolyl)-3,3-dimethyl-4H-isoquinoline-5-carbonitrile (example A3)

    专利号:WO-2021074311-A1
    优先权日:2019-10-16
    标题:1-(3-quinolyl)-1,2,3,4-tetrahydroisoquinoline derivatives as fungicides for combating specific phytopathogens
    发明人:WEISS MATTHIAS; QUARANTA LAURA; BOU HAMDAN FARHAN; MAHAJAN ATUL; WILLIAMS SIMON; KILARU JAGADEESH; BIERI STEPHANE; DIGGELMANN MARTIN
    权利人:SYNGENTA CROP PROTECTION AG
    摘要:1-(3-quinolyl)-1,2,3,4-tetrahydroisoquinoline derivatives of formula (I) as well as a method of combating, preventing or controlling the phytopathogens Mycosphaerella graminicola (Septoria tritici), Fusarium culmorum, Gibberella zeae (Fusarium graminearum) and Monographella nivalis (Microdochium nivale), which comprises applying to the phytopathogen, to the locus of the phytopathogen, or to a plant susceptible to attack by the phytopathogen, or to propagation material thereof, a fungicidally effective amount of a 1-(3-quinolyl)-1,2,3,4-tetrahydroisoquinoline derivatives of formula (I). The present description discloses the synthesis of exemplary compounds, formulation examples, relevant biological data (antifungal activity against Mycosphaerella graminicola, Monographella nivalis, Fusarium culmorum and/or Gibberella zeae when spayed on plants) (e.g. pages 47 to 55; examples A1 and A2; compounds E.01 to E.17; table E). An exemplary compounds is e.g.: 3-(5-bromo-3,3-dimethyl-2,4-dihydro-1 H-isoquinolin-1-yl)-8-fluoro- quinoline (example A1)
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    主要参考文献


    1: Li X, Zhang S, Yu Z, Yang T. Surface-enhanced Raman spectroscopic analysis of phorate and fenthion pesticide in apple skin using silver nanoparticles. Appl Spectrosc. 2014;68(4):483-7. doi: 10.1366/13-07080. Erratum in: Appl Spectrosc. 2015 Mar;69(3):417. doi: 10.1002/jbt.21539. Epub 2013 Nov 12. doi: 10.1016/j.talanta.2014.03.020. Epub 2014 Mar 20. doi: 10.4149/gpb_2013047. Epub 2013 Aug 12. doi: 10.1016/j.aca.2014.01.037. Epub 2014 Jan 19. doi: 10.1177/0748233711412426. Epub 2011 Aug 22. doi: 10.1016/j.jhazmat.2009.11.086. doi: 10.3109/01480541003734048. doi: 10.1177/0748233710387009. Epub 2010 Oct 14. Epub 2007 Jan 25. doi: 10.1016/j.chemosphere.2011.12.031. Epub 2012 Jan 5. doi: 10.1002/em.20652. Epub 2011 Apr 27. doi: 10.1016/j.taap.2008.11.017. Epub 2008 Dec 9.
    18: Kitamura S, Suzuki T, Ohta S, Fujimoto N. Antiandrogenic activity and metabolism of the organophosphorus pesticide fenthion and related compounds. Environ Health Perspect. 2003 Apr;111(4):503-8.
    19: Lavado R, Schlenk D. Microsomal biotransformation of chlorpyrifos, parathion and fenthion in rainbow trout (Oncorhynchus mykiss) and coho salmon (Oncorhynchus kisutch): mechanistic insights into interspecific differences in toxicity. Aquat Toxicol. 2011 Jan 17;101(1):57-63. doi: 10.1016/j.aquatox.2010.09.002. Epub 2010 Sep 16.

    合成参考文献


    摘要:Toxicology and Applied Pharmacology., 6(86), 1964
    摘要:Toxicology and Applied Pharmacology., 20(57), 1971 []
    摘要:Veterinary Medical Review. No.1, 1964- No.1/2, 1975. For Publisher information, see: VVMRDI, (2-3)(273), 1967
    摘要:Veterinariya. Veterinary Science., 54(12)(94), 1978
    摘要:Documentation of the Threshold Limit Values and Biological Exposure Indices, 5th ed., Cincinnati, OH, American Conference of Governmental Industrial Hygienists, Inc., 1986, 5(267), 1986
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