CAS: 2439-99-8; Glyphosine
该化合物是一种化学化合物,在结构上与广泛使用的除草剂 ----甘硫酸有联系,其特征是它作为甘硫酸的代谢物的作用,这意味着当甘硫酸在环境中或生物体内分解时会生产.甘硫素通常比甘硫酸毒性低,而且经常在土壤和水系统中研究其环境影响和行为.该化合物在水中溶解,影响其在环境中的流动性.该化合物的化学结构包括一个磷酸组,有助于其再活性和与生物系统的互动.关于甘硫酸的研究侧重于其对非目标生物的潜在影响及其在农业环境中的持久性.了解甘硫酸的特性对于评估甘硫酸的使用对生态的后果和制定减轻对生态系统任何不利影响的战略至关重要.
- 英文名称Glyphosine
- 中文名称N-双(膦羟甲基)甘氨酸
- IUPAC名称2-[bis(phosphonomethyl)amino]acetic acid
- 其它别名增甘磷; Glycinedimethanephosphonic Acid; C 9552; Cp 41845; Gdmp; Polaris; Nitrilomonomethylcarbonyldimethylphosphonic Acid
- CAS编号2439-99-8
- MFCD编号:MFCD00056670
- EINECS号:219-468-4
- FDA UNII编号:2U96121SKR
- 分子式:C4H11NO8P2
- 分子量:263.08
- 产品CID: 1191458
- 产品分类有机原料→分子砌块→脂肪链类化合物
相似化合物
5994-61-6 24569-83-3 1071-83-6物理性质
- 熔点263 °C
- 沸点668.4 °C at 760 mmHg
- 闪点358.0±34.3 °C
- 密度2.0±0.1 g/cm3
- pKa:pK1 1.42; pK2 2.10; pK3 5.02; pK4 6.40; pK5 11.19(at 25°C)
- PSA:155.6
- LogP:-1.3566
- 折射率1.594
- 蒸汽压0.0±4.4 mmHg at 25°C
- 溶解性Pbs (Ph: 7.2):5.0(Max Conc. mg/mL);19.01(Max Conc. Mm)
- 敏感性常温常压下稳定，避免氧化物接触对眼睛有强烈刺激性，对皮肤有中等刺激性。
- 外观形态白色固体
- 储存条件+2C to +8C
- 产品应用增甘磷是一种叶面施用的植物生长调节剂,亦可作收获前的脱叶剂.主要用途是甘蔗和甜菜催熟并增加糖分.它是美国第一个商品化的甘蔗催熟剂,1972年开始投入市场.最佳用药时间是甘蔗收获前9周,用量为2.4-4.5kg(有效成分),hm2.可使甘蔗提前成熟15-40d,增加蔗糖1左右,用于甜菜可在收获前30d施药,每亩38g,可增产糖10.用于棉花脱叶,在吐絮期喷洒每亩38g,7d内有75-99棉叶脱落.
- 性质描述白色结晶.熔点200°C(分解).在20°C水中溶解度为248g/L.在常温几乎没有挥发性.
MSDS等安全信息
欧盟法规
统一分类与标签ECHA物质ECHA物质工作场所安全标识要求C&L通报REACH预注册废弃物危险特性清单上下游产品
CAS号50-00-0 甲醛 | CAS号56-40-6 甘氨酸 | CAS号17261-34-6 亚氨基二(甲基磷酸) | CAS号79-11-8 氯乙酸 | CAS号65886-96-6 2-(dimethoxypho... | CAS号3926-62-3 氯乙酸钠 | CAS号35404-71-8 methylaminometh... | CAS号83315-67-7 hydrated phosph... | CAS号1071-83-6 草甘膦 | CAS号17261-34-6 亚氨基二(甲基磷酸) | CAS号5995-25-5 [(methylimino)d...合成工艺路线路线简述
O-Trimethylsilyl N,N-Bis[bis(Trimethylsiloxy)Phosphorylmethyl]Glycine 以 甲醇,乙醚 用作溶剂,以95%的收率获得增甘膦
参考文献:用 Pch2N 片段合成双和三有机磷取代的胺和氨基酸
标题:用 Pch2N 片段合成双和三有机磷取代的胺和氨基酸
摘要:三价有机磷酸衍生物(含有 Ph 和 Posime3 片段与各种双和三(烷氧基甲基)胺和双(烷氧基甲基)氨基酸)的氨基甲基化被提议作为合成新的双和三磷酸化胺的便捷方法和氨基酸以及它们与四和五配位磷的衍生物.此外,通过用双(三甲基甲硅烷基)胺处理反应混合物,对亚磷酸,多聚甲醛和胺的三组分体系进行了彻底研究.© 2010 Wiley Periodicals,Inc. 杂原子化学 21:430-440,2010;置于wileyonlinelibrary.Com 上在线查看这篇文章.Doi 10.1002/hc.20616
Doi:10.1002/hc.20616
海关参考信息
- 2912110000-甲醛
2912120000-乙醛
2915110000-甲酸
2915211900-乙酸 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
专利信息
专利号:EP-4151643-A1
优先权日:2021-09-16
标题 :Improved process for production of phosphoesters of glufosinate precursors
发明人：LAUTENSCHÃœTZ LUDGER; BRAUNE SASCHA; PÖTTER MARKUS
权利人:EVONIK OPERATIONS GMBH
摘要:SummaryThe present invention relates to a method for production of a compound according to formula (I):wherein R is alkyl, aryl, alkaryl, aralkyl,and wherein X is selected from the following structures (I-A), (I-B):wherein R1, R2 are independently selected from the group consisting of alkyl, aryl, alkaryl, aralkyl.The compounds according to formula (I) are important precursors in the synthesis of glufosinate, in particular L-glufosinate. In the method according to the present invention, easily accessible starting materials are employed. Thus, the method overcomes the disadvantages of prior art syntheses of L-glufosinate and its intermediates.
专利号:BR-102013018473-B1
优先权日:2012-07-24
标题 :HERBICIDAL COMPOSITIONS COMPENDIENT 4-AMINO-3-CHLORO-5-FLUORO-6- (4-CHLORO-2-FLUORO-3-ETOXYPHENYL) PYRIDINE-2-CARBOXYLIC ACID OR A DERIVATIVE OF THE SAME AND HERBICIDES INHIBITING THE SYNTHESIS OF VLCFA AND SYNTHESIS OF GRAIN ACID / LIPID, AND METHOD FOR UNDESIRABLE VEGETATION CONTROL
专利号:TW-I655905-B
优先权日:2012-07-24
标题 :Contains 4-amino-3-chloro-5-fluoro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylic acid or a derivative thereof and very long chain fatty acid (VLCFA) Synthesis of herbicidal compositions with fatty acid/fat synthesis inhibiting herbicides
专利号:US-9644469-B2
优先权日:2012-07-24
标题 :Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6-(4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid or a derivative thereof and VLCFA and lipid synthesis inhibiting herbicides
发明人：YERKES CARLA N; MANN RICHARD K; SHIRAISHI IKUO; YANAGIYAMA SHINGO; SATCHIVI NORBERT M
权利人:DOW AGROSCIENCES LLC
摘要:A synergistic herbicidal composition containing (a) a compound of formula (I): n nor an agriculturally acceptable salt or ester thereof and (b) VLCFA and fatty acid/lipid synthesis inhibiting herbicides, including but not limited to, acetochlor, alachlor, anilofos, benfuresate, cafenstrole, dimethenamid-P, fentrazamide, indanofan, flufenacet, mefenacet, s-metolachlor, molinate, pethoxamid, pretilachlor, prosulfocarb, pyroxasulfone, thenylchlor and thiobencarb, or a salt or ester thereof, provide synergistic weed control of undesirable vegetation in direct-seeded, water-seeded and transplanted rice, cereals, wheat, barley, oats, rye, sorghum, corn or maize, sugarcane, sunflower, oilseed rape, canola, sugar beet, soybean, cotton, pineapple, pastures, grasslands, rangelands, fallowland, turf, tree and vine orchards, aquatics, plantation crops, vegetables, industrial vegetation management (IVM) or rights-of-way (ROW).
专利号:RU-2014320-C1
优先权日:1987-09-15
标题:Method of synthesis of propenoic acid derivatives and their stereoisomers
专利号:BR-102013018473-A2
优先权日:2012-07-24
标题 :HERBICIDE COMPOSITIONS UNDERSTANDING 4-AMINO-3-CHLORINE-5-FLUORO-6- (4-CHLORO-2-FLUORO-3-METOX IFENYL) PYRIDINE-2-CARBOXYLIC ACID OR AN INHIBITION OF SAME INHIBITION AND SYNTHESIS OF FATTY ACID / LIPID
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主要参考文献
[参考文献]: Aaron W Michels, Et Al. Structure-Based Selection Of Small Molecules To Alter Allele-Specific Mhc Class Ii Antigen Presentation. J Immunol. 2011 Dec 1;187(11):5921-30.[参考文献]: Eva Orejuela, Et Al. Rapid And Sensitive Determination Of Phosphorus-Containing Amino Acid Herbicides In Soil Samples By Capillary Zone Electrophoresis With Diode Laser-Induced Fluorescence Detection. Electrophoresis. 2005 Dec;26(23):4478-85.
[参考文献]: L J Olson, Et Al. Influence Of Feeding Chlorocholine Chloride And Glyphosine On Selected Immune Parameters In Deer Mice, Peromyscus Maniculatus. Toxicology. 1984 Mar;30(2):103-14.
[参考文献]: Mathea Sophia Galanski, Et Al. Synthesis, Characterization, And In Vitro Antitumor Activity Of Osteotropic Diam(M)Ineplatinum(Ii) Complexes Bearing A N,N-Bis(Phosphonomethyl)Glycine Ligand. J Med Chem. 2003 Nov 6;46(23):4946-51.
[参考文献]: W R Harris, Et Al. Binding Of Phosphonate Chelating Agents And Pyrophosphate To Apotransferrin. Biochemistry. 1991 Jul 16;30(28):6930-6.
合成参考文献
摘要:Agricultural Chemicals, Thomson, W.T., 4 vols., Fresno, CA, Thomson Publications, 1976/77 revision, 3(60), 1976/1977
摘要:S. Westerback, K. S. Rajan and A. E. Martell, J. Am. Chem. Soc. 87, 2567 (1965).
参考文献:10.1155/bca.2005.179
摘要:Galanski M, Slaby S, Jakupec MA, Keppler BK. Synthesis and in vitro Antitumor Potency of(Cyclohexane‐1,2‐Diamine)Platinum(II) Complexeswith Aminotris(Methylenephosphonic Acid) as Bone‐Seeking Ligand. Bioinorganic Chemistry and Applications. 2005 Jan;3(3-4):179–90. doi: 10.1155/bca.2005.179.
参考文献:10.1021/ic9025014
摘要:Pereira GA, Peters JA, Almeida Paz FA, Rocha J, Geraldes CFGC. Evaluation of [Ln(H2cmp)(H2O)] Metal Organic Framework Materials for Potential Application as Magnetic Resonance Imaging Contrast Agents. Inorg. Chem. 2010 Feb 12;49(6):2969–74. doi: 10.1021/ic9025014.
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