148-24-3 = 84-88-8 反应条件:1.1 Reagents: Fuming Sulfuric Acid; Overnight,Rt 标题:New Trick For An Old Ligand! The Sensing Of Zn(Ii) Using A Lanthanide Based Ternary Yb(Iii)-Cyclen-8-Hydroxyquinoline System As A Dual Emissive Probe For Displacement Assay 作者:Comby,Steve; Tuck,Sarah A.; Truman,Laura K.; Kotova,Oxana; Gunnlaugsson,Thorfinnur 参考文献:Inorganic Chemistry 日期:2012 卷标:51(19) 页码:10158-10168]
148-24-3 = 84-88-8 反应条件:1.1 Reagents: Sulfur Trioxide,Sulfuric Acid 标题:Synthesis Of 7-(2-Carboxy-4-Bromobenzeneazo)-8-Hydroxyquinoline-5-Sulfonic Acid And Spectrophotometric Determination Of Molybdenum In Foods 作者:Yu,Ying; Peng,Shanshan; Huang,Jianfeng 参考文献:Huaxue Shiji 日期:1992 卷标:14(6) 页码:337-9]
98-37-3 = 84-88-8 反应条件:1.1 Reagents: Hydrochloric Acid Solvents: Water; 1 H,Reflux1.2 Reagents: Sodium Bicarbonate Solvents: Water; Neutralized,Rt1.3 Reagents: Hydrochloric Acid Solvents: Water; Ph 4,Rt 标题:Development Of New Cathepsin B Inhibitors: Combining Bioisosteric Replacements And Structure-Based Design To Explore The Structure-Activity Relationships Of Nitroxoline Derivatives 作者:Sosic,Izidor; Mirkovic,Bojana; Arenz,Katharina; Stefane,Bogdan; Kos,Janko; Et Al 参考文献:Journal Of Medicinal Chemistry 日期:2013 卷标:56(2) 页码:521-533]
148-24-3 + 302-17-0 = 84-88-8 + 23218-68-0 反应条件:1.1 Reagents: Sulfuric Acid Solvents: Water; Rt; Rt -> 80 °C; 12 H,80 °C1.2 Reagents: Water; Cooled 标题:Study On The Process Of Joint Production Of 8-Hydroxyquinoline-5-Carbaldehyde And 8-Hydroxyquinoline-5-Sulphonic Acid 作者:Qi,Jiajuan; Li,Shuan; Zhang,Zhenming; Wang,Ting; Zhao,Hongbo 参考文献:Huagong Shikan 日期:2013 卷标:27(10) 页码:1-5
专利号:US-8735586-B2 优先权日:2007-06-26 标 题 :Regioselective copper catalyzed synthesis of benzimidazoles and azabenzimidazoles 发明人:ALONSO JORGE; LINDENSCHMIDT ANDREAS; NAZARÉ MARC; URMANN MATTHIAS; HALLAND NIS; RKYEK OMAR 权利人:ALONSO JORGE; LINDENSCHMIDT ANDREAS; NAZARÉ MARC; URMANN MATTHIAS; HALLAND NIS; RKYEK OMAR; SANOFI SA 摘要:The present invention relates to a process for the regioselective synthesis of compounds of the formula I, n nwherein R0; R1; R2; R3; R4; R5; A1; A2; A3; A4, Q and J have the meanings indicated in the claims. The present invention provides a direct copper catalyzed regioselective process to a wide variety of unsymmetrical, multifunctional N-substituted benzimidazoles or azabenzimidazoles of formula I starting from 2-halo-nitroarenes and N-substituted amides.
专利号:EP-2173747-B1 优先权日:2007-06-26 标 题:A regioselective metal catalyzed synthesis of annelated benzimidazoles and azabenzimidazoles 发明人:ALONSO JORGE; LINDENSCHMIDT ANDREAS; NAZARE MARC; R KYEN OMAR; URMANN MATHIAS; HALLAND NIS 权利人:SANOFI SA 摘要:The present invention relates to a process for the regioselective synthesis of compounds of the formula I, wherein R1; R2; R3; R4; J1; J2; J3; J4 and G have the meanings indicated in the claims. The present invention provides a direct metal, e.g. palladium or copper, catalyzed, regioselective process to a wide variety of unsymmetrical, multifunctional N-substituted benzimidazoles or azabenzimidazoles of formula I starting from 2-halo-nitroarenes and N-substituted amides.
专利号:US-7105617-B2 优先权日:2003-02-06 标题:Metal 8-hydroxyquinoline-functionalized polymers and related materials and methods of making and using the same 发明人:WECK MARCUS; MEYERS AMY 权利人:GEORGIA TECH RES INST 摘要:This invention relates to the synthesis of Mq n -containing monomeric compounds, comprising a polymerizable moiety, an Mq n -moiety, and an optional chemical spacer therebetween, wherein q, in each instance, comprises an 8-hydroxyquinoline residue, M is a metal such as Mg, Zn, Al, Ga, or In, and n is 2 or 3 as the valence of the metal requires. For example, the polymerization of Znq 2 - or Alq 3 -containing monomers, in the presence or absence of a co-monomer, provided a Znq 2 - or Alq 3 -containing polymer, which retained the optical properties of Znq 2 or Alq 3 in solution, respectively. The Mq n -containing polymers may be used in, among other things, the fabrication of light-emitting diodes (LEDs).
专利号:US-4707500-A 优先权日:1979-11-07 标 题:Synthetic crystalline ferroborosilicate compositions, the preparation thereof and their use in the conversion of synthesis gas to low molecular weight hydrocarbons 发明人:HINNENKAMP JAMES A; WALATKA VERNON V 权利人:NAT DISTILLERS CHEM CORP 摘要:Crystalline ferroborosilicate compositions are prepared from a silica containing mixture by digesting a reaction mixture comprising a tetraalkylammonium compound, a sodium hydroxide, a boron compound, an oxide of silicon, an iron ion source, an optional chelating agent and water to provide the crystalline ferroborosilicate which is then palladium ion-exchanged. This composition may be used alone or physically mixed with a methanol catalyst. Conversion of synthesis gas, dimethylether, ethylene and methanol to low molecular hydrocarbons employing these new ferroborosilicates as catalysts is also disclosed.
专利号:US-4670474-A 优先权日:1981-04-22 标 题:Synthetic crystalline metallosilicate compositions, the preparation thereof and their use in the conversion of synthesis gas to low molecular weight hydrocarbons 发明人:HINNENKAMP JAMES A; WALATKA VERNON V 权利人:NAT DISTILLERS CHEM CORP 摘要:Crystalline palladium or platinum ferrometallosilicate compositions are prepared from a silica-containing mixture by digesting a reaction mixture comprising (a) a tetraalkylammonium compound, (b) a sodium hydroxide, (c) a titanium compound, an aluminum compound, or a manganese compound, (d) an oxide of silicon, (e) an iron ion source, (f) optionally, a chelating agent and (g) water to provide a crystalline ferrometallosilicate which is then palladium or platinum ion-exchanged. Conversion of synthesis gas to low molecular hydrocarbons with high C 2 -C 3 alkanes selectivity employing these new ferrometallosilicates as catalysts is also disclosed.
专利号:US-2010261909-A1 优先权日:2007-06-26 标题 :Regioselective copper catalyzed synthesis of benzimidazoles and azabenzimidazoles
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合成参考文献
摘要:S10 | SWISSPHARMA | Pharmaceutical List with Consumption Data | DOI:10.5281/zenodo.2623484