CAS: 432-25-7; 2,6,6-Trimethylcyclohex-1-Ene-1-Carbaldehyde

该化合物是一种有机化合物,用化学配方C10H14O,被归类为单体甲状腺,C10H14O.其特点是,它具有令人愉快的柑橘状芳香,在香味和口味行业中具有价值.该化合物具有环状环状结构,有助于其独特的特性. -环状化学在室温下一般是无色的,在室内无色黄色液体,在有机溶剂中可溶解.它有一个相对较低的沸点,在许多挥发性有机化合物中很常见. 在再活性方面,-环状化学可以经历各种化学变异,包括氧化和减少,还因其潜在的生物活动而闻名,包括抗微生物和抗氧化性特性,在制药和天然产品化学领域引起了兴趣.安全数据表明,在与皮肤或眼睛接触时,它可能会引起刺激,但一般认为在正确处理时毒性较低.

英文名称2,6,6-Trimethylcyclohex-1-Ene-1-Carbaldehyde
中文名称β-环柠檬醛
IUPAC名称2,6,6-trimethylcyclohex-1-ene-1-carbaldehyde
其它别名.Beta.-Cyclocitral; Beta-Cyclocitrol; -Cyclocitral, Technical Grade; Beta-Cyclocitral, Analytical Standard; Pentadeuterio-Beta-Cyclocitral; 1-Formyl-2,6,6-Trimethyl-1-Cyclohexene; 2,6,6-Trimethyl-Cyclohexene-1-Carbaldehyde; 2,6,6-Trime
CAS编号432-25-7
MFCD编号:MFCD00079078
EINECS号:207-081-3
FDA UNII编号:77Y0U2X29G
分子式:C10H16O
分子量:152.24
产品CID: 1443956
产品分类有机原料→分子砌块→脂肪环类化合物→环己烷类化合物

相似结构搜索
InChIKey: MOQGCGNUWBPGTQ-UHFFFAOYSA-N
InChI=1S/C10H16O/c1-8-5-4-6-10(2,3)9(8)7-11/h7H,4-6H2,1-3H3…
计算化学: 氢键受体数1.0氢键供体数0.0可旋转键数1.0

相似化合物

472-66-2 116-31-4 471-90-9

物理性质

熔点62-63 °C
沸点62-63 °C at 3 mmHg
闪点76.9 °C
密度0.947g/cm3
PSA:17.07
LogP:2.7119
折射率n20/D 1.497(文献)
蒸汽压0.176mmHg at 25°C
溶解性Chloroform (Slightly), Dichloromethane, Ethyl Acetate (Slightly), Methanol (Slightly)
敏感性空气敏感
外观形态无色至深黄色油状物
储存条件惰性气氛,存放于冰箱中, -20°C
产品应用该化合物用于调味剂,营养剂,稳定剂,表面活性剂和乳化剂.
性质描述93％β-环柠檬醛,测得沸点213．2°C,比热210．7J／g 合成方法: 采用β-紫罗兰酮为原料,经臭氧化,还原水解反应得β-环柠檬醛.

MSDS等安全信息

GHS象形图
GHS符号GHS07;
注释: Exclamation mark
危险类别急性毒性类别4(吸入)
急性毒性类别4(经皮)
急性毒性类别4(经口)
皮肤腐蚀/刺激类别2
严重眼刺激类别2
特定目标器官毒性 - 单次接触类别3
严重眼刺激类别2A
警示词Warning(警告)
危险描述H332 |吸入有害.
H312 |皮肤接触有害.
H302 |吞咽有害.
H315 |造成皮肤刺激.
H319 |造成严重眼刺激.
H335 |可能引起呼吸道刺激.
H336 |可能引起嗜睡或头晕.
防范说明P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362+P364-P405-P501
危险等级8
UN编号1760
危险品标志Xn,Xi
包装等级III
安全声明26-36-37/39
危险类别码20/21/22-36/37/38
WGK Germany3

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

合成工艺路线路线简述

9005-53-2 = 432-25-7 + 103-81-1 + 831-00-5 + 22607-11-0 + 74421-05-9 + 2219-78-5 + 219726-60-0 + 94391-24-9 + 60826-26-8 + 7443-70-1 + 51504-54-2 + 72386-20-0 + 79-31-2 + 494-99-5 + 646-07-1 + 4041-09-2 + 1131-62-0 + 56687-68-4 + 93-15-2
反应条件:1.1 Reagents: Sodium Hydroxide Catalysts: Molybdenum,Copper Solvents: Methanol,Water; 7 H,220 °C1.2 Reagents: Water
标题:Cu-Mo Doped Zeolite Zsm-5 Catalyzed Conversion Of Lignin To Alkyl Phenols With High Selectivity
作者:Singh,Sunit Kumar; Et Al
参考文献:Catalysis Science & Technology 日期:2015 卷标:5(4) 页码:2117-2124

1-Hydroxy-2,2,6-Trimethyl-Cyclohexanecarbonitrile置于吡啶,氯化亚砜,二异丁基氢化铝体系中,用甲苯,苯作为反应溶剂,化学反应 3.0H,反应生成 1-吡咯烷羧酸,3-[[(3-溴苯基)氨基]甲基]-,1,1-二甲基乙基酯
参考文献:Kutney,James P.; Gunning,Philip J.; Clewley,Robin G.,Canadian Journal Of Chemistry,1992,Vol. 70,# 7,P. 2094-2114
标题:Kutney,James P.; Gunning,Philip J.; Clewley,Robin G.,Canadian Journal Of Chemistry,1992,Vol. 70,# 7,P. 2094-2114

海关参考信息

2901210000-乙烯
2901220000-丙烯
2912110000-甲醛
2912120000-乙醛
💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
详情请参考：📖 海关编码查询和海关进出口税则

专利信息

专利号:WO-9532946-A1
优先权日:1994-05-27
标题 :Methods for the synthesis of 9-cis retinoids and their novel intermediates
发明人：BENNANI YOUSSEF L
权利人:LIGAND PHARM INC
摘要:Methods for the synthesis of 9-cis retinoids, novel intermediates and methods for the synthesis of cyclohexadienyne nitriles and 9-cis alkyl cisoid nitriles, as well as 9-cis retinoids made using such methods are provided.

专利号:US-5817845-A
优先权日:1993-04-21
标题:Methods for stereospecific synthesis of 11,13-cis polyene esters
发明人：WHITE STEVEN K; HWANG CHAN KOU; WINN DAVID T
权利人:LIGAND PHARM INC
摘要:Methods for stereospecific synthesis of 9-cis olefins and retinoids. In one particular aspect, a cis olefin is generated via a lactol ring opening with complete retention of double bond configuration.

专利号:US-11773060-B2
优先权日:2016-05-25
标题 :Method for synthesis of 9-cis-beta-carotene and formulations thereof
发明人：GAZIT EHUD; BUZHANSKY LUDMILA; IOFFE MICHAEL; SAYER ALON
权利人:UNIV RAMOT
摘要:A formulation includes an active agent, a thickening/solidifying agent, and an antioxidant. The active agent is 9-cis-Î²-carotene (9CBC) or a derivative thereof of the following formula:where R2 is H or methyl; X isoptionally substituted with one or more methyl groups; n is an integer of 0-16; and the asterisk represents the point of attachment to the cyclohexene ring.

专利号:WO-2017203516-A1
优先权日:2016-05-25
标题:Method for synthesis of 9-cis-beta-carotene and formulations thereof

专利号:WO-9424082-A1
优先权日:1993-04-21
标题 :Stereospecific synthesis of polyene compounds

专利号:EP-0760810-A1
优先权日:1994-05-27
标题 :Methods for the synthesis of 9-cis retinoids and their novel intermediates

其他信息查阅

上海泰矶林实业有限公司

网址: http://www.tajilin.com
企业联系电话：021-50630626,18964684208👤
地址:上海市松江区沈砖公路5808号14幢5层536B室

⚠️ 未注册 · 未认证企业

备注: 📌 数据来源说明：本展台内容基于各搜索引擎等公开数据整理，仅作展示用途。请用户自行辨别
✉️ 若企业需抹除展台内容或有异议，请通过页面底部联系方式告知我们，我们会尽快处理。

第 1 / 1 页

现货

供应商参考报价(招募中)

品牌试剂参考报价(招募中)

实用工具

📌 第三方产品分析报告

✅ COA系统入驻 | 共享模式

主要参考文献

[参考文献]: Alexandra J Dickinson, Et Al. β-Cyclocitral Is A Conserved Root Growth Regulator. Proc Natl Acad Sci U S A. 2019 May 21;116(21):10563-10567.
[参考文献]: Feifei Lv, Et Al. β-Cyclocitral Upregulates Salicylic Acid Signalling To Enhance Excess Light Acclimation In Arabidopsis. J Exp Bot. 2015 Aug;66(15):4719-32.
[参考文献]: Friedrich Jüttner, Et Al. β-Cyclocitral, A Grazer Defence Signal Unique To The Cyanobacterium Microcystis. J Chem Ecol. 2010 Dec;36(12):1387-97.

合成参考文献

摘要:Taylor, R. E.; Diène, C. R.; Daly, E. M., Science of Synthesis, (2009) 46, 569.
参考文献:10.1186/s12870-017-0988-4
摘要:Li W, Liu C, He M, Li J, Cai Y, Ma Y, Xu J. Largely different contents of terpenoids in beef red-flesh tangerine and its wild type. BMC Plant Biology. 2017 Feb 03;17(1):36. doi: 10.1186/s12870-017-0988-4.
参考文献:10.1007/s00018-019-03202-5
摘要:Sujeeth N, Mehterov N, Gupta S, Qureshi MK, Fischer A, Proost S, Omidbakhshfard MA, Obata T, Benina M, Staykov N, Balazadeh S, Walther D, Fernie AR, Mueller-Roeber B, Hille J, Gechev TS. A novel seed plants gene regulates oxidative stress tolerance in Arabidopsis thaliana. Cellular and Molecular Life Sciences. 2019 Jun 27;77(4):705–18. doi: 10.1007/s00018-019-03202-5.

📝 需求与反馈

📲 手机号 / 邮箱 *

✏️ 问题内容 *

尽可能描述清楚需求与问题信息