CAS: 1303-58-8; Gold(Iii) Oxide

该化合物是金(III)氧化物(Au2O3),是一种化学化合物,其特点是深褐色至黑色的外观;是一种无机物质,含有黄金,具有+3氧化状态,对反应和潜在应用意义重大;金氧化物通常是在高温氧气条件下通过黄金氧化产生的;在环境条件下以其稳定性著称,但可在加热,释放氧气和再生成元素黄金为己有闻名;这种化合物因其独特性,在各个领域都具有意义,包括催化,电子和材料科学;金氧化物也可以作为合成其他金化合物和纳米粒的前体;此外,它具有有趣的光学和电子特性,成为纳米技术和光学研究的课题;然而,处理金氧化物需要谨慎,因为它可能具有某种形式的毒性,而且在使用和储存过程中应当遵守适当的安全措施.

结构式图片

欧盟法规

ECHA物质C&L通报REACH预注册

合成工艺路线路线简述

    专利信息


    专利号:US-6011171-A
    优先权日:1996-08-14
    标 题 :Process for synthesis of tertiary carboxylic acids and the esters thereof
    发明人:XU QIANG; SOUMA YOSHIE
    权利人:JIRO HIRAISHI DIRECTOR GENERAL
    摘要:The present invention provides a process for synthesizing tertiary carboxylic acids or the esters thereof having one or two more carbon atoms than the raw material has, comprising reacting in a strong acid (e.g., sulfuric acid, sulfuric acid-phosphoric acid, hydrogen fluoride, fluorosulfuric acid, boron trifluoride.water complex and trifluoromethanesulfonic acid) a raw material compound (i.e., olefin, alcohol, diene, diol or saturated hydrocarbon) with carbon monoxide in the presence of a specific metal carbonyl catalyst (i.e., platinum carbonyl catalyst, palladium carbonyl catalyst and gold dicarbonyl catalyst). The metal carbonyl catalyst is formed by reacting in a strong acid at least one specific metal compounds (e.g., platinum compound such as platinum (II, IV) oxide, platinum (II, IV) hydroxide, a platinum powder, etc.; palladium compound such as palladium (II, III, IV) oxide, palladium (II) hydroxide, palladium (II) sulfate, palladium (II) carboxylate, a palladium powder, etc.; and gold compound such as gold (I, III) oxide, gold (I, III) hydroxide, a gold powder, etc.) with carbon monoxide.

    专利号:WO-8607351-A1
    优先权日:1985-06-14
    标题 :Method and catalyst for the conversion of methane
    发明人:HICKS ROBERT FISHER
    权利人:GRACE W R & CO
    摘要:A process and catalyst for the synthesis of hydrogen, ethylene, ethane, and higher hydrocarbons from methane in the presence of oxygen. The catalyst comprises metal oxides selected from a Group IIA metal, a Group IIIA metal, a lanthanide series metal excluding Ce, or mixtures thereof and optionally a promoter metal oxide selected from a Group IA metal, a Group IIA metal, a Group IIIA metal, a lanthanide series metal, a Group IVB metal, a Group VB metal, a Group IB metal, or mixtures thereof.

    专利号:US-7270695-B2
    优先权日:2004-04-01
    标 题 :Synthesis of nanosized metal particles
    发明人:KIM INSOO; KIM GANG HYUK; LEE CHANG GUN; KIM YOUNG JIN; SMITH CHARLES
    权利人:TOKUSEN U S A INC
    摘要:The present invention is directed to methods for forming nanosized metal particles. Preferably, nanosized noble metal particles are formed. According to the methods of the invention, a product containing nanosized metal particles in a solvent are formed. Additionally, processing to remove undesirable byproducts created or used during the fabrication process are not necessary.

    专利号:US-4780449-A
    优先权日:1985-06-14
    标题 :Catalyst for the conversion of methane
    发明人:HICKS ROBERT F
    权利人:GRACE W R & CO
    摘要:A process and catalyst for the synthesis of hydrogen, ethylene, ethane, and higher hydrocarbons from methane in the presence of oxygen is disclosed. The catalyst comprises metal oxides selected from a Group IIA metal, a Group IIIA metal, a lanthanide series metal excluding Ce, or mixtures thereof and optionally a promoter metal oxide selected from a Group IA metal, a Group IIA metal, a Group IIIA metal, a lanthanide series metal, a Group IVB metal, a Group VB metal, a Group IB metal, or mixtures thereof.

    专利号:US-2017014805-A1
    优先权日:2014-04-22
    标 题 :Method for the synthesis of supported gold (au) nanoparticles for epoxidation reactions
    发明人:AL-HAZMI MOHAMMED H
    权利人:SABIC GLOBAL TECHNOLOGIES BV
    摘要:Processes for preparing supported gold nanoparticle catalysts are provided. In an exemplary embodiment, the process includes adding a solution of a phosphorus compound to a solution of chloro (dimethyl sulfide) gold (I) to obtain a solution of chloro (phosphorus compound) gold (I) complex, adding the solution of chloro (phosphorus compound) gold (I) complex to a solution of silver nitrate to obtain a solution of nitro (phosphorus compound) gold (I) complex, applying the solution of nitro (phosphorus compound) gold (I) complex to a metal hydroxide support, drying the metal hydroxide support; and calcining the dried metal hydroxide support to form the supported gold nanoparticle catalyst. Supported gold nanoparticle catalysts prepared by the process and processes for oxidizing ethylene to ethylene oxide in the presence of the supported gold nanoparticle catalysts are also provided.

    专利号:US-8062756-B2
    优先权日:2005-08-26
    标题:Stepwise growth of oligomeric redox-active molecules on a surface without the use of protecting groups
    发明人:BOCIAN DAVID F; LINDSEY JONATHAN S; JIAO JIEYING
    权利人:BOCIAN DAVID F; LINDSEY JONATHAN S; JIAO JIEYING; REGENTS OFT THE UNIVERSITY OF CALIFORNIA; UNIV NORTH CAROLINA STATE
    摘要:This invention provides a procedure for growing oligomers via a stepwise process. The oligomers can include porphyrins, which have been previously shown to be attractive candidates for molecular-based information storage. The stepwise synthesis procedure requires no protecting groups, thus eliminating protection/deprotection reactions that add complexity to the process.
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