CAS: 617-94-7; 2-Phenyl-2-Propanol

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CAS号100-58-3 苯基溴化镁 | CAS号67-64-1 丙酮 | CAS号80-15-9 过氧化氢异丙苯 | CAS号917-64-6 甲基碘化镁 | CAS号98-86-2 苯乙酮 | CAS号98-82-8 异丙基苯 | CAS号2085-88-3 2-苯基环氧丙烷 | CAS号13740-70-0 2-methyl-1,2-di... | CAS号108-86-1 溴苯 | CAS号3805-10-5 2-甲基-2-苯基丙醛 | CAS号585-32-0 A,A-二甲基苄胺 | CAS号3910-35-8 1,3,3-三甲基-1-苯基茚满 | CAS号6362-80-7 2,4-二苯基-4-甲基-1-戊烯 | CAS号599-64-4 4-肉桂苯酚 | CAS号101787-38-6 2-[2-(1-methyl-... | CAS号14629-57-3 2-Phenyl-2-(tri... | CAS号98-82-8 异丙基苯 | CAS号18168-40-6 2-(2-phenylprop... | CAS号18597-93-8 Hydrazinecarbox... | CAS号1889-67-4 2,3-二甲基-2,3-二苯基丁烷

过氧化氢异丙苯置于三氟化硼乙醚,氧气,Trichloroacetimidate,Sodium Chloride体系中,用 二氯甲烷,氘代乙腈,水 作为反应溶剂,化学反应 1.0H,反应生成 2-苯基-2-丙醇
参考文献:叔丁基叔丁基枯基过氧化物的光解反应中反应生成的一对对羟丙基和叔丁氧基自由基的反应性和产物分析.
标题:叔丁基叔丁基枯基过氧化物的光解反应中反应生成的一对对羟丙基和叔丁氧基自由基的反应性和产物分析.
摘要:烷氧基在化学的各个领域都起着重要的作用.了解它们的反应性对于将其化学应用于工业和生物学目的至关重要.据报道,烷氧基具有氢原子转移和c-cβ断裂反应.分别使用枯基氧基(cumo •)和叔丁氧基(t-Buo •)研究了这两个过程的比率.但是,尚未详细研究由该对自由基产生的产物.在这项研究中,粗磨•和吨-Buo •同时从光解产生的叔-丁基枯基过氧化物通过分析产物及其分布来了解这对自由基的化学行为.自由基(包括cumo •和t-Buo •)的电子顺磁共振和/或瞬态吸收光谱分析提供了有关叔丁基枯基过氧化物光解过程中产生的自由基的更多信息.此外,(3-(叔丁基过氧)戊烷-3-基)苯的光产物表明醚产物是在笼内反应中形成的.由cumo •产生的苯乙酮诱导的三重态敏化反应表明,自旋态不影响产物的分布.
DOI:10.1021/acs.Joc.0C01016

专利信息

专利号:WO-0140193-A1
优先权日:1999-12-03
标题:Method for the synthesis of pyrazolines
发明人：BOLDI ARMEN M
权利人:CHEMRX ADVANCED TECHNOLOGIES I; BOLDI ARMEN M
摘要:The present invention provides a method for the synthesis of compounds of Formula (I). Also claimed are novel intermediates and their methods of synthesis.

专利号:US-7084309-B2
优先权日:2002-03-14
标 题:Process for the synthesis of phenol and acetone
发明人：CODIGNOLA FRANCO
权利人:EUROTECNICA DEV & LICENSING S
摘要:This invention refers to a process for the synthesis of phenol and acetone starting from cumene hydroperoxide, and to a plant specifically developed for performing this process. More in particular, this invention refers to a process for the synthesis of phenol and acetone starting from cumene hydroperoxide, comprising the following steps: a) Pretreating of the starting cumene hydroperoxide with acidic resins, to obtain cumene hydroperoxide free of inorganic cations; b) Decomposing of the cumene hydroperoxide free of inorganic cations originating from the step (a) in the presence of acidic resins, to yield phenol and acetone.

专利号:US-2012029226-A1
优先权日:2009-02-06
标题:Method for the synthesis of chiral alpha-aryl propionic acid derivatives
发明人：KAPTEIN BERNARDUS; VLIEG ELIAS; NOORDUIN WILLEM LIEUWE
权利人:KAPTEIN BERNARDUS; VLIEG ELIAS; NOORDUIN WILLEM LIEUWE
摘要:The present invention provides a method for the synthesis of optically pure α-aryl propionic acid derivatives comprising subjecting the corresponding racemic α-aryl propionic acid derivatives to high sheer or impact forces, such as grinding.

专利号:US-6600040-B2
优先权日:2000-06-08
标 题:Process for the synthesis of (2R, 2-alpha-R, 3A)-2-[1-(3,5-bis(trifluoromethyl)phenyl)ethoxy]-3-(4-fluorophenyl)-1, 4-oxazine
发明人：BRANDS KAREL M JOS; TSAY FUH-RONG; CONRAD KAREN M; ZHAO MATTHEW M
权利人:MERCK & CO INC
摘要:The present invention is concerned with novel processes for the preparation of (2R, 2-alpha-R, 3a)-2-[1-[3,5-bis(trifluoromethyl)phenyl]ethoxy-3-(4-fluorophenyl)-1,4-oxazine. This compound is useful as an intermediate in the synthesis of compounds which possess pharmacological activity.

专利号:WO-2014059961-A1
优先权日:2012-10-15
标 题 :Method for the synchronous absorption of carbon dioxide from flue gas and synthesis of dialkyl carbonates and alkylene carbonates
发明人：BÃœTTNER HERMANN; Müller Jürgen; JONKER RAPHAEL; DOEDT SEBASTIAN; BOSSE TOBIAS; MAKRAN SEBASTIAN
权利人:BÃœTTNER HERMANN
摘要:The invention relates to a synchronous CCU method (carbon dioxide capture and utilisation) for the absorption of carbon dioxide from flue gas and other CO 2 -containing substance sources and simultaneous synthesis of dialkyl carbonates and alkylene carbonates. The general subject matter of the invention is, in terms of a 'carbon dioxide capture' on the one hand, the absorption of CO 2 from flue gas and other CO 2 -containing substance sources with ammonia and/or amines to form ammonium carbamates or ammonium hydrogen carbonates or ureas or urea intermediates and, in terms of a 'carbon dioxide utilisation' on the other hand, the reaction of ammonium carbamates or ammonium hydrogen carbonates or ureas or urea intermediates with aliphatic, alicyclic or unsaturated alcohols, and including unsaturated aromatic alcohols to give dialkyl carbonates or alkylene carbonates in such a form that the CO 2 n absorption agent is re-released and fed back into the repetitive process again. A repetitive process control is extremely energy and CO 2 n efficient.

专利号:US-6469164-B2
优先权日:2000-06-08
标题:Process for the synthesis of (2R, 2-alpha-R)-4-benzyl-2-[1-(3,5-bis (trifluoromethyl)phenyl)ethoxy]-1,4-oxazine-3-one
发明人：BRANDS KAREL M JOS; PAYACK JOSEPH F; PYE PHILIP J
权利人:MERCK & CO INC
摘要:The present invention is concerned with novel processes for the preparation of (2R, 2-alpha-R)-4-benzyl-2-[1-[3,5-bis(trifluoromethyl)phenyl]ethoxy-1,4-oxazin-3-one. This compound is useful as an intermediate in the synthesis of compounds which possess pharmacological activity.