CAS: 13688-56-7; Trimethylsilyl Methacrylate

该化合物是一种有机硅化合物,其特征是存在甲基丙烯酯功能组和一个三甲基硅酸酯组,其化学结构具有甲基丙烯酸酯特性,因其具有聚合化能力而闻名,使甲基甲基丙烯酸酯在各种应用中,特别是在聚合物和共聚物合成过程中有用;三甲基硅酸酯组增强化合物在有机溶剂中的稳定性和溶性,同时在化学反应期间为功能组提供保护性特征;甲基甲基硅酸酯通常是一种无色液体,其粘度低,沸点相对较低;由于能够改进粘合物和密封剂的适应性和灵活性,它常常被用于涂层,粘合物和密封剂的配制;此外,甲基硫酸盐可用作制作以硅酸基材料的前体;安全考虑包括在经过通风的地区处理该化合物,并使用适当的个人防护设备,因为它在与皮肤或眼睛接触时可能造成刺激.

英文名称Trimethylsilyl Methacrylate
中文名称甲基丙烯酸三甲基硅酯
IUPAC名称trimethylsilyl methacrylate
其它别名(Trimethylsilyl)Methacrylate; Methacrylic Acid Trimethylsilyl Ester (Stabilized With Bht)
CAS编号13688-56-7
MFCD编号:MFCD00053868
EINECS号:629-466-9
分子式:C7H14O2Si
分子量:158.27
产品CID: 574310
产品分类化学试剂 → 硅烷试剂

相似结构搜索
产品信息参考;;;;
InChIKey: PGQNYIRJCLTTOJ-UHFFFAOYSA-N
InChI=1S/C7H14O2Si/c1-6(2)7(8)9-10(3,4)5/h1H2,2-5H3…
计算化学: 氢键受体数2.0氢键供体数0.0可旋转键数3.0

MSDS等安全信息

GHS象形图
GHS符号GHS02 & GHS07 & GHS08;
注释: Flame & Exclamation mark & Health hazard
危险类别易燃液体类别3
皮肤腐蚀/刺激类别2
严重眼刺激类别2
特定目标器官毒性 - 单次接触类别3
呼吸道致敏类别1
皮肤致敏类别1
警示词Danger(危险)
危险描述H226 |易燃液体和蒸气.
H315 |造成皮肤刺激.
H319 |造成严重眼刺激.
H335 |可能引起呼吸道刺激.
H334 |吸入可能引起过敏或哮喘症状或呼吸困难.
H317 |可能引起皮肤过敏反应.
防范说明P210-P233-P240-P280-P303+P361+P353-P305+P351+P338
危险等级3.2
UN编号UN 1993 3/PG 3
危险品标志Xn
包装等级III
安全声明22-26-36/37
危险类别码10-36/37/38-42/43
WGK Germany3.0

欧盟法规

ECHA物质C&L通报

上下游产品

合成工艺路线路线简述

六甲基二硅氮烷反应生成甲基丙烯酸三甲基硅酯
参考文献:
标题:

海关参考信息

2901210000-乙烯
2901220000-丙烯
2905121000-正丙醇
2912110000-甲醛
💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
详情请参考：📖 海关编码查询和海关进出口税则

专利信息

专利号:WO-2025202701-A1
优先权日:2024-08-21
标题 :Marine antifouling paint based on silyl acrylate copolymer synthesis
发明人：LAHEGHI NEJAD FARHAD
权利人:LAHEGHI NEJAD FARHAD
摘要:This invention involves the production of marine anti-fouling paint using the synthesis of silyl acrylate copolymers. One of the most effective anti-algae or anti-fouling paints was self-polishing paints based on acrylate resins containing tributyl tin, which were banned due to the toxicity of their tin compounds. One of the best-introduced alternatives is self-polishing paints based on silyl acrylate copolymers, but their performance is subpar and they have a shorter lifespan. In this invention, silyl acrylate copolymers in a controlled structure, including at least one soft monomer such as butyl acrylate, ethyl acrylate, etc., at least one hard monomer such as methyl methacrylate, 2-methoxyethyl methacrylate, etc. and at least one functional monomer such as triisopropyl silyl acrylate, triisopropyl silyl methacrylate, tertiary-butyl dimethyl silyl methacrylate, and tri-N-butyl silyl methacrylate were synthesized in which monomers or hard monomers were gradually added to the reactor in 2-6 hours.

专利号:US-4746750-A
优先权日:1987-08-31
标题 :Synthesis of silyl ketene acetal from allyl 2-organoacrylates
发明人：REVIS ANTHONY
权利人:DOW CORNING
摘要:A process is described for preparing silyl ketene acetals having the formula, n n (CH.sub.3)RCâ•?C(OSiR.sup.i.sub.3).sub.2, n n from allyl 2-organoacrylates. The process comprises contacting an allyl 2-organoacrylate with a trisubstituted silane in the presence of a rhodium catalyst; and separating and isolating the silyl ketene acetal. Silyl ketene acetal of greater than 85-90 percent purity can be recovered.

专利号:US-2016002367-A1
优先权日:2014-07-02
标题 :Synthesis of an acrylate polymer in flow reactor

专利号:KR-20090102733-A
优先权日:2006-12-27
标题 :Method for synthesis of hyperbranched polymer, hyperbranched polymer, resist composition, semiconductor integrated circuit, and method for production of semiconductor integrated circuit

专利号:KR-20090103860-A
优先权日:2006-12-28
标题:Process for synthesis of hyperbranched polymer, hyperbranched polymer, resist compositions, semiconductor integrated circuits, and process for production of semiconductor integrated circuits

专利号:JP-2017524797-A
优先权日:2014-07-02
标题 :Synthesis of acrylic polymers in a flow reactor.