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专利信息
专利号:WO-2013057134-A1
优先权日:2011-10-19
标 题:Synthesis of semiconductor nanoparticles using metal precursors comprising non- or weakly coordinating anions
发明人:BAHNMUELLER STEFAN; TIAN SUSAN; TIAN SHIZHE; HOHEISEL WERNER
权利人:BAYER IP GMBH; BAYER SOUTH EAST ASIA PTE LTD
摘要:The present invention relates to a method for the synthesis of semiconductor nanoparticles comprising elements of the groups IB, IIB, IIIA, IVA, VA or VIA of the periodic classification wherein the composition of the core nanoparticle is selected from the group consisting of IB-VIA, IIB-VIA, IIIA-VIA, IB-IIIA-VIA or IB-IIB-TVA-VIA, IIB-IIIA-VIA, IIB-TVA-VA or mixtures thereof, and at least one shell comprises elements of the groups IIB and VIA,, wherein in case the core composition is IIB-VIA the shell comprises at least a further element selected from the groups IB, IIIA, IVA or VA, using metal precursors comprising non- or weakly coordinating anions. It further relates to the consecutive process for the synthesis that includes first the preparation of a binary nanoparticle system then modified to make a ternary system which again can be further modified to make a quaternary system.
专利号:WO-2024243127-A1
优先权日:2023-05-19
标题:Transformative synthesis of semiconductor nanoclusters with atomic precision via metal-ligand coordination exchange
发明人:ZENG CHENJIE; MA FUYAN
权利人:UNIV FLORIDA
摘要:Precision nanosynthesis is crucial for atomic engineering in nanostructures and mechanistic understanding of nanoscale reactions. But it is a daunting task due to emerging complexities in nanostructures and nanosynthesis. Here, we report the precision synthesis of semiconductor nanocluster via synergizing coordination, cluster, and colloidal chemistry at the nanoscale. In particular, by employing Cu26Se13(PEt2Ph)14 cluster and Cdl2(PPr3)2 coordination complex as precise precursors in colloidal cation exchange reaction, an atomically precise Cd26Se17I18(PPr3)10 cluster is produced at near- unity yield. X-ray crystallography reveals that the child CdSe cluster inherits its icosahedral-packed anion lattice and halide-phosphine-rich surface from parent cluster and complex respectively and further evolves into an enlarged structure. The hybridization of achiral precursors leads to chiral CdSe clusters co-crystallized as a 1:1 mixture of enantiomers. In-situ optical spectroscopy unveils that the reaction proceeds with well-defined pathways. Based on charge and coordination conservations, the structure of child cluster can be atomically linked to precursors via a series of transformations including surface coordination exchange, intra-cluster reorganization, and inter-cluster digestive ripening. The precision nanosynthesis with atomically defined precursors, pathways, and products is expected to further rationalize and diversify nanochemistry.
专利号:US-8957237-B2
优先权日:2011-12-19
标 题 :Method for the direct synthesis of alkylhalogenosilanes
发明人:ROSIER CÉCILE
权利人:BLUESTAR SILICONES FRANCE; BLUESTAR SILICONES FRANCE
摘要:An improved industrial method for the direct synthesis of alkylhalogenosilanes is described. Specifically, a method is described for preparing alkylhalogenosilanes by reacting, in a fluidized bed reactor, and alkyl halogenide, preferably CH3Cl, with a solid body, which is referred to as a contact body and which includes powdered silicon and a catalytic system including at least one copper catalyst and β1 and β2 promoter activities.
专利号:US-3872101-A
优先权日:1969-04-11
标题:Synthesis of {60 , {62 -unsaturated compounds
发明人:SIDDALL JOHN E; FRIED JOHN H
权利人:ZOECON CORP
摘要:Stereospecific synthesis of Alpha , Beta -ethylenically unsaturated compounds by the reaction of an organo-copper or organo-manganese reagent with an Alpha , Beta -acetylenically unsaturated compound at a temperature of -40*C or less.
专利号:US-2016317682-A1
优先权日:2015-04-30
标题:PREPARATION OF Ag18F AND ITS USE IN THE SYNTHESIS OF PET RADIOTRACERS
发明人:SCOTT PETER J H; BROOKS ALLEN F; ICHIISHI NAOKO; SANFORD MELANIE S
权利人:UNIV MICHIGAN REGENTS; THE REGENTS OFTHE UNIV OF MICHIGAN
摘要:Copper-catalyzed radiofluorination of aryl iodides using Ag 18 F, methods of preparing Ag 18 F, and compounds obtained by copper-catalyzed radiofluorination of aryl iodides using Ag 18 F are disclosed. Diagnostic and therapeutic methods involving such compounds also are disclosed.
专利号:US-11718584-B2
优先权日:2019-02-22
标题 :Process for the synthesis anthranilic diamide compounds and intermediates thereof
发明人:KARRI PHANEENDRASAI; PABBA JAGADISH; SHINDE BHARAT UTTAMRAO; KALWAGHE AMOL DNYANESHWAR; MADHAVRAO KAMBLE MARUTI; KLAUSENER ALEXANDER G M; PANMAND DEEPAK SHANKAR
权利人:PI INDUSTRIES LTD
摘要:The present invention disclosed a process for the synthesis of anthranilic diamide compound of formula (I), n n n n n n n n n n wherein, R 1 , R 2 , R 3a , R 3b , R 3c , R 4 , R 5 , R 6 and Z are as defined in the detailed description. The process comprising the step of obtaining a mono- or dicyano substituted aniline compound of formula (IV) which is then converted to an anthranilic acid compound of formula (V) or an anthranilic amide compound of formula (Va). Further, the compound of formula (VI) can be optionally synthesized from compound of formula (IV or V or Va)