物理性质
- 熔点-38.7 °C
- 沸点18.5 °C(压力: 1.0 Torr)
- 闪点137 °F
- 密度1.1563 g/cm3(温度: 25 °C)
- PSA:30.21
- LogP:0.41
- 折射率n20/D 1.527
- 蒸汽压2.21 mm Hg at 25 °C (est)
- 溶解性95%乙醇:可溶1ML/mL,澄清
- 敏感性Air Sensitive
- 外观形态极深棕色液体
- 储存条件储存于阴凉,通风的库房,库温不宜超过37°C.远离火种,热源,避光保存.包装要求密封,不可与空气接触.应与氧化剂,碱类及食用化学品分开存放,切忌混储.不宜大量储存或久存. 储存区域需采用防爆型照明和通风设施,并禁止使用易产生火花的机械设备和工具.另外,应备有泄漏应急处理设备和合适的收容材料.
- 产品应用用作溶剂,及作为合成香料,糠醇,四氢呋喃的中间体.
- 性质描述无色或浅黄色油状液体.熔点-38.7°C,沸点161.7°C,103°C(13.3kPa),90°C(8.65kPa),67.8°C(2.66kPa),18.5°C(0.133kPa),相对密度1.1594,折光率1.5261,闪点60°C.极易溶于醇,醚,易溶于热水,丙酮,溶于苯,氯仿.在空气中易变成黄棕色.能随水蒸汽挥发,有苯醛的气味.
欧盟法规
统一分类与标签压力设备指令-第1组危险流体欧盟化妆品法规附录三-限用物质清单REACH注册ECHA物质ECHA物质食品接触材料-禁用CMR物质工作场所安全标识要求C&L通报REACH预注册废弃物危险特性清单上下游产品
furan hydrogen cyanide N,N-dimethyl-formamide (2-furyl)methyl alcohol1-(2-furyl)-1-ethanone dimethyl(furan-2-yl(hydroxy)methyl)phosphonate 2-benzoyl-3-(2-furyl)prop-2-enenitrile ethyl 2-carbethoxy-3-(2-furanyl)propenoate合成工艺路线路线简述
- 合成目标产物 Furfural 主要起始原料 1,3-Dithiane, 2-(2-Furanyl)-
- (文献来源)合成步骤主要原料 1,3-Dithiane, 2-(2-Furanyl)-
2,5-呋喃二甲醇置于palladium On Activated Charcoal,Rhodium Contaminated With Carbon,氢气体系中,50.0~150.0 °C,8.0 Mpa 条件下,反应 12.0H,反应生成 糠醛
参考文献:Dehydrogenation Of 5-Hydroxymethylfurfural To Diformylfuran In Compressed Carbon Dioxide: An Oxidant Free Approach
标题:Dehydrogenation Of 5-Hydroxymethylfurfural To Diformylfuran In Compressed Carbon Dioxide: An Oxidant Free Approach
摘要:生物质基5-羟甲基糠醛(hmf)的脱氢反应,可以在温和的反应条件下利用载体为活性炭的铑(rh/c)催化剂实现,产生2,5-二甲酰呋喃(dff).
DOI:10.1039/c6Gc02977A
专利信息
专利号:US-2010099894-A1
优先权日:2006-10-09
标 题 :Method for the Synthesis of Cyclic Acetals by the Reactive Extraction of a Polyol in a Concentrated Solution
发明人:DUBOIS JEAN-LUC; IBORRA CHORNET SARA; VELTY ALEXANDRA I LUCIENNE; CORMA CANOS AVELINO
权利人:DUBOIS JEAN-LUC; IBORRA CHORNET SARA; VELTY ALEXANDRA I LUCIENNE; CORMA CANOS AVELINO
摘要:A method for the synthesis of cyclic acetals comprises reacting at least one carbonyl-function compound selected from aldehydes, ketones, and/or linear acetals, on a polyol in a concentrated aqueous solution exceeding 20 wt % in a reactor containing an acidic catalyst. The carbonyl-function compound is selected so that the cyclic acetal obtained has a water solubility lower than 20000 mg/kg. During the catalytic reaction for the cyclic acetal synthesis, at least one portion of the organic phase containing the cyclic acetal is separated. The acidic catalysis is either homogeneous when using a water-soluble strong acid, or heterogeneous when using a solid acid such as a resin, a zeolite, or any appropriately acidified solid. The extractive reaction method can be used for obtaining high conversions and selectivity.
专利号:US-8410320-B2
优先权日:2010-12-07
标 题 :Method for synthesis of secondary alcohols
发明人:CHENG CHIEN-HONG; KARTHIKEYAN JAGANATHAN; HUANG PANG-CHI
权利人:CHENG CHIEN-HONG; KARTHIKEYAN JAGANATHAN; HUANG PANG-CHI; NAT UNIV TSING HUA
摘要:A method for synthesis of secondary alcohols is provided for pharmaceutical secondary alcohol by addition of organoboronic acids with aldehydes in presence of the cobalt ion and bidentate ligands as the catalyst. In addition, an enantioselective synthesis method for secondary alcohols is also herein provided in the present invention. The present invention has advantages in using less expensive cobalt ion and commercially available chiral ligands as the catalyst, wide scope of organoboronic acids and aldehydes compatible with this catalytic reaction and achieving excellent yields and/or enantiomeric excess.
专利号:US-9242925-B2
优先权日:2011-08-29
标题:Versatile and stereospecific synthesis of γ,δ-unsaturated amino acids by Wittig reaction
发明人:JUGE SYLVAIN; BAYARDON JEROME; REMOND EMMANUELLE; ONDEL-EYMIN MARIE-JOELLE
权利人:JUGE SYLVAIN; BAYARDON JEROME; REMOND EMMANUELLE; ONDEL-EYMIN MARIE-JOELLE; CENTRE NAT RECH SCIENT; UNIV BOURGOGNE
摘要:The γ,δ-unsaturated α-amino acids of general formula (I). Also, a versatile process for the stereospecific synthesis of said compounds of formula (I), involving a Wittig reaction. Further, intermediate products of general formulae (II) and (III), as shown below, which are involved in the synthesis of compounds (I). n n n n n n n n n n n n Compounds of general formula (I) may be useful as therapeutic substances, or as reagents or intermediates for fine chemistry.
专利号:US-6159673-A
优先权日:1996-07-17
标 题:Oxonol compound, light-sensitive material and process for the synthesis of oxonol compound
发明人:NISHIGAKI JUNJI; DEGUCHI YASUAKI
权利人:FUJI PHOTO FILM CO LTD
摘要:An oxonol compound is represented by the following formula (I): in which Z is an atomic group that forms a cyclic amide ring; each of W1 and W2 independently is an atomic group that forms an acidic nucleus ring; and M is a cation. Other oxonol compounds, a light-sensitive material containing an oxonol compound and a process for the synthesis of an oxonol compound are also disclosed.
专利号:WO-2017089470-A1
优先权日:2015-11-27
标 题:Process for the synthesis of aryldiazonium salts using nitrogen oxides in oxygen-containing gas streams, especially from industrial waste gases
发明人:HOFMANN DAGMAR; HOFMANN JOSEFA; HEINRICH MARKUS
权利人:Friedrich-Alexander-Universität Erlangen-Nürnberg
摘要:The present invention relates to a process for the synthesis of aryldiazonium salts using nitrogen oxides in oxygen-containing gas streams, especially from industrial waste gases.
专利号:US-2013338369-A1
优先权日:2011-03-07
标 题 :Process for the Synthesis of Aminobiphenylene
发明人:HEINRICH MARKUS; PRATSCH GERALD
权利人:HEINRICH MARKUS; PRATSCH GERALD; BASF SE
摘要:The present invention relates to a process for the synthesis of 2-aminobiphenylene and derivatives thereof by reacting a benzene diazonium salt with an aniline compound under basic reaction conditions.