专利号:US-6924385-B2 优先权日:2002-11-18 标 题:Method for synthesis of aliphatic isocyanates from aromatic isocyanates 发明人:LETTMANN CHRISTIAN; KOHLSTRUK STEPHAN; STOCHNIOL GUIDO; SPYROU EMMANOUIL 权利人:DEGUSSA 摘要:The invention relates to a method for synthesis of aliphatic isocyanates from aromatic isocyanates in substantially 3 stages. In particular, the invention relates to a method for synthesis of bis{4-isocyanatocyclohexyl}methane (H 12 MDI) from bis{4-isocyanatophenyl}methane (MDI). More especially, the invention relates to a method for synthesis of H 12 MDI with a trans-trans isomer content of <30%, preferably of <20%, particularly preferably of 5 to 15%.
专利号:WO-2021137711-A1 优先权日:2019-12-31 标题 :Synthesis of polyesters in aqueous polymerization systems 'from solid to solid' via biocatalysis 发明人:JOAQUIM PINA DA FONSECA LUIS; CAROLINA DOLVITSCH PFLUCK ANA; POPOVIC CORREIA DE BARROS DRAGANA 权利人:INST SUPERIOR TECNICO 摘要:The present invention relates to a process for the synthesis of polyesters comprising reacting a dicarboxylic acid monomer with a dialcohol monomer, in an equimolar concentration in the range of 0.2 M to 1.0 M, in the presence of a biocatalyst, in an aqueous polymerization medium, at a temperature in the range of 25-45°C, the biocatalyst being in the form of an enzyme immobilized on a solid support. The present invention further provides a copolymer obtained by the invention process.
专利号:US-8816125-B2 优先权日:2006-12-23 标 题 :Process for the continuous preparation of (cyclo)aliphatic diisocyanates 发明人:MICHALCZAK HANS-WERNER; KOHLSTRUK STEPHAN; KRECZINSKI MANFRED; GRUND GERDA; LOMOELDER RAINER 权利人:MICHALCZAK HANS-WERNER; KOHLSTRUK STEPHAN; KRECZINSKI MANFRED; GRUND GERDA; LOMOELDER RAINER; EVONIK DEGUSSA GMBH 摘要:The invention relates to a multi-stage process for the continuous, phosgene-free preparation of (cyclo)aliphatic diisocyanates that comprises the conversion of (cyclo)aliphatic diamines into the corresponding (cyclo)alkylene biscarbamates and the thermal cleaving of the latter into the (cyclo)alkylene diisocyanates and alcohol. The urea used in accordance with the invention and also the urea employed for the preparation of urea equivalents (e.g. alkyl carbonates, alkyl carbamates) as a possible precursor for the synthesis of the (cyclo)aliphatic biscarbamates is unconditioned.
专利号:US-12163079-B2 优先权日:2019-08-12 标 题 :Synthesis of blue-emitting ZnSe1-xTex alloy nanocrystals with low full width at half-maximum 发明人:NEWMEYER BENJAMIN; IPPEN CHRISTIAN; MA RUIQING 权利人:SHOEI CHEMICAL IND CO 摘要:The invention pertains to the field of nanotechnology. The invention provides highly luminescent nanostructures, particularly highly luminescent nanostructures comprising a ZnSe 1-x Te x core and ZnS and/or ZnSe shell layers. The nanostructures comprising a ZnSe 1-x Te x core and ZnS and/or ZnSe shell layers display a low full width at half-maximum and a high quantum yield. The invention also provides methods of producing the nanostructures.
专利号:US-11053439-B2 优先权日:2019-02-05 标题:Methods for synthesis of inorganic nanostructures using molten salt chemistry 发明人:CURLEY JOHN J; TU ALEXANDER; GUO WENZHOU; WANG CHUNMING; IPPEN CHRISTIAN; HOTZ CHARLES 权利人:NANOSYS INC 摘要:The invention relates to highly luminescent nanostructures with strong blue light absorbance, particularly core/shell nanostructures comprising an In(1-x)GaxP core and ZnSe and/or ZnS shell layers, wherein 0 专利号:US-11753587-B2 优先权日:2018-05-30 标 题:Method for synthesis of blue-emitting ZnSe1-xTEx alloy nanocrystals 发明人:IPPEN CHRISTIAN; TRUSKIER JONATHAN; MANDERS JESSE 权利人:NANOSYS INC 摘要:The invention relates to highly luminescent nanostructures, particularly highly luminescent nanostructures comprising a ZnSe 1-x Te x core and ZnS and/or ZnSe shell layers. The invention also relates to methods of producing such nanostructures.
摘要:Merck Index - O'Neil MJ, Heckelman PE, Dobbelaar PH, Roman KJ (eds). The Merck Index, An Encyclopedia of Chemicals, Drugs, and Biologicals, 15th Ed. Cambridge, UK: The Royal Society of Chemistry, 2013. 摘要:Journal of Hygiene, Epidemiology, Microbiology, and Immunology., 18(144), 1974 [] 摘要:Rossi, L., Science of Synthesis, (2005) 18, 494. 摘要:Rossi, L., Science of Synthesis, (2005) 18, 505.