CAS: 928-96-1; Cis-3-Hexen-1-Ol

• 英文名称Cis-3-Hexen-1-Ol
• 中文名称叶醇
• IUPAC名称(Z)-hex-3-en-1-ol
• 其它别名cis-Hex-3-en-1-ol
• CAS编号928-96-1
• MFCD编号:MFCD00063217
• EINECS号:213-192-8
• FDA UNII编号:V14F8G75P4
• 分子式:C6H12O
• 分子量:100.1584
• 产品CID: 1967698
• 产品分类有机原料→分子砌块→脂肪链类化合物

• 相似结构搜索
• 产品信息参考;;;;
• InChIKey: UFLHIIWVXFIJGU-ARJAWSKDSA-N
• InChI=1S/C6H12O/c1-2-3-4-5-6-7/h3-4,7H,2,5-6H2,1H3/b4-3-…
• 计算化学: 氢键受体数1.0氢键供体数1.0可旋转键数3.0

相似化合物

物理性质

• 熔点22.55 °C
• 沸点156.5°C at 760 mmHg
• 闪点44.44°C
• 密度0.848
• pKa:15.00±0.10(预测)
• PSA:20.23
• LogP:1.335
• 折射率1.438-1.441
• 蒸汽压1.0±0.6 mmHg at 25°C
• 溶解性DMSO: 100 mg/mL (998.40 Mm)
• 敏感性1.常温常压下稳定，避免强氧化剂 酸接触。2. 存在于烟叶中。3. 天然存在于柑橘类果汁、豆类、白兰地酒、许多种植物的叶子、精油和水果中。
• 外观形态APHA: ≤100液体
• 储存条件易燃物区域
• 产品应用顺式3-己烯醇具有类似异戊醇的香味,用于制高级香料;反式3-已烯醇在非常稀和状态有浓草香味,用于特种香料的生产.
• 性质描述液体,有顺反两种异构体,天然产品多为顺式.易溶于醇,溶于水和醚.

MSDS等安全信息

• GHS象形图
• GHS符号GHS02 & GHS07;
  注释: Flame & Exclamation mark
• 危险类别易燃液体 类别3
  严重眼刺激 类别2
  易燃固体 类别1
  急性毒性 类别4(吸入)
  特定目标器官毒性 - 单次接触 类别3
  皮肤腐蚀/刺激 类别2
• 警示词Warning(警告)
• 危险描述H226 |易燃液体和蒸气.
  H319 |造成严重眼刺激.
  H228 |易燃固体.
  H332 |吸入有害.
  H335 |可能引起呼吸道刺激.
  H315 |造成皮肤刺激.
• 防范说明P210-P233-P240-P241-P242-P243-P280-P370+P378-P501
• 危险等级3
• UN编号1987.0
• 危险品标志F
• 包装等级Ⅲ
• 安全声明16
• 危险类别码10
• WGK Germany1

欧盟法规

上下游产品

合成工艺路线路线简述

• 合成目标产物 Leaf Alcohol 主要起始原料 5,6-Dihydro-2-Methyl-2H-Pyran
• 55230-25-6 = 928-96-1
  反应条件:1.1 Reagents: Hydrogen Catalysts: Palladium Solvents: Ethanol; 6 H,2 Mpa,60 °C
  标题:Application Of Single Atom Metal Loaded Catalyst In Selective Hydrogenation Reaction
  参考文献:China]
  
  1002-28-4 = 928-96-1
  反应条件:1.1 Reagents: Hydrogen Catalysts: Salen (Palladium Chloride Complex) Solvents: Pyridine
  标题:Selective Hydrogenation By A Novel Palladium(Ii) Complex
  作者:Kerr,James M.; Suckling,Colin J.
  参考文献:Tetrahedron Letters 日期:1988 卷标:29(43) 页码:5545-8]
  
  17102-64-6 = 928-96-1
  反应条件:1.1 Reagents: Hydrogen Catalysts: Ruthenium,[(2,3,4,5-η)-(2E,4E)-2,4-Hexadienoato][(1,2,3,4,5-η)-1,2,3,4,5-Pentam... Solvents: 1,2-Dimethoxyethane,Tert-Butyl Methyl Ether
  标题:Application Of Cp*-Ruthenium(Ii) Catalysts In Stereoselective Hydrogenation Of Sorbic Acid
  作者:Driessen-Holscher,Birgit
  参考文献:Synthetic Methods Of Organometallic And Inorganic Chemistry 日期:2002 卷标:10 页码:94-98]
  
  1002-28-4 = 928-96-1
  反应条件:1.1 Reagents: Hydrogen Catalysts: Dimethyl Sulfoxide,Palladium Solvents: Hexane; 150 Min,1 Atm,40 °C
  标题:Highly Efficient Pd/sio2-Dimethyl Sulfoxide Catalyst System For Selective Semi-Hydrogenation Of Alkynes
  作者:Takahashi,Yusuke; Hashimoto,Norifumi; Hara,Takayoshi; Shimazu,Shogo; Mitsudome,Takato; Et Al
  参考文献:Chemistry Letters 日期:2011 卷标:40(4) 页码:405-407]
  
  1002-28-4 = 928-96-1
  反应条件:1.1 Reagents: Acetic Acid Catalysts: Tetrakis(Triphenylphosphine)Palladium Solvents: Dichloromethane
  标题:Selective Reduction Of Alkynes To Z-Alkenes Using Hydrosilane Functions Immobilized On Silica Gel
  作者:Kini,Abhay D.; Nadkarni,Durgesh V.; Fry,James L.
  参考文献:Tetrahedron Letters 日期:1994 卷标:35(10) 页码:1507-10]
  
  13894-62-7 = 928-96-1
  反应条件:1.1 Catalysts: Zinc 2-Ethylhexanoate,Sodium Borohydride Solvents: Diisopropyl Ether1.2 Reagents: Trimethoxysilane1.3 Reagents: Sodium Hydroxide Solvents: Water
  标题:Selective Reduction Of Carbonyl Compounds By Polymethylhydrosiloxane In The Presence Of Metal Hydride Catalysts
  作者:Mimoun,Hubert
  参考文献:Journal Of Organic Chemistry 日期:1999 卷标:64(7) 页码:2582-2589]
  
  1002-28-4 = 928-96-1
  反应条件:1.1 Reagents: Hydrogen Catalysts: Nickel Solvents: Methanol
  标题:Unsaturated Aldehydes And Ketones. Iii. Synthesis Of The Violet-Leaf Aldehyde,Trans,Cis-2,6-Nonadien-1-Al
  作者:Jutz,Christian
  参考文献:Chemische Berichte 日期:1959 卷标:92 页码:1983-9]
  
  17102-64-6 = 928-96-1
  反应条件:1.1 Reagents: Hydrogen Catalysts: Ruthenium,[(2,3,4,5-η)-(2E,4E)-2,4-Hexadienoato][(1,2,3,4,5-η)-1,2,3,4,5-Pentam... Solvents: Ethylene Glycol,Tert-Butyl Methyl Ether
  标题:Stereoselective Catalytic Hydrogenation Of Sorbic Acid And Sorbic Alcohol With New Cp*ru Complexes
  作者:Steines,Stephan; Driessen-Holscher,Birgit; Englert,Ulli
  参考文献:Chemical Communications (Cambridge) 日期:2000 卷标:(3) 页码:217-218]
  
  1002-28-4 = 928-96-1
  反应条件:1.1 Reagents: Lithium,Nickel Dichloride Catalysts: 4,4′-Bis(1,1-Dimethylethyl)-1,1′-Biphenyl Solvents: Tetrahydrofuran; 10 Min,Rt1.2 Reagents: Ethanol Solvents: Tetrahydrofuran; 8 H,Rt
  标题:Highly Stereoselective Semihydrogenation Of Alkynes Promoted By Nickel(0) Nanoparticles
  作者:Alonso,Francisco; Osante,Inaki; Yus,Miguel
  参考文献:Advanced Synthesis & Catalysis 日期:2006 卷标:348(3) 页码:305-308]
  
  = 928-96-1
  反应条件:1.1 Catalysts: Benzyltrimethylammonium Hydroxide
  标题:Preparation Of 3-(Hexenyloxy)Propanenitriles As Perfume Ingredients
  参考文献:Germany]
  
  1002-28-4 = 928-96-1
  反应条件:1.1 Reagents: Hydrogen Catalysts: Palladium,Tetrabutylammonium Borohydride Solvents: Dimethylformamide,Tetrahydrofuran; 8 Atm,30 °C
  标题:Highly Active And Selective Semihydrogenation Of Alkynes With The Palladium Nanoparticles-Tetrabutylammonium Borohydride Catalyst System
  作者:Hori,Junichi; Murata,Kunihiko; Sugai,Toshiki; Shinohara,Hisanori; Noyori,Ryoji; Et Al
  参考文献:Advanced Synthesis & Catalysis 日期:2009 卷标:351(18) 页码:3143-3149]
  
  1002-28-4 = 928-96-1
  反应条件:1.1 Reagents: Hydrogen Catalysts: Palladium,Silver Solvents: Ethanol; 5 H,Rt
  标题:Design Of Core-Pd/shell-Ag Nanocomposite Catalyst For Selective Semihydrogenation Of Alkynes
  作者:Mitsudome,Takato; Urayama,Teppei; Yamazaki,Kenji; Maehara,Yosuke; Yamasaki,Jun; Et Al
  参考文献:Acs Catalysis 日期:2016 卷标:6(2) 页码:666-670]
  
  1002-28-4 = 928-96-1
  反应条件:1.1 Reagents: Hydrogen Catalysts: [n,N′-1,2-Acenaphthylenediylidenebis[4-Methoxybenzenamine-Kn]][1,4-Dimethyl (2,3... Solvents: Tetrahydrofuran
  标题:Selective Homogeneous Palladium(0)-Catalyzed Hydrogenation Of Alkynes To (Z)-Alkenes
  作者:Van Laren,Martijn W.; Elsevier,Cornelis J.
  参考文献:Angewandte Chemie 日期:1999 卷标:38(24) 页码:3715-3717]
  
  55230-25-6 = 928-96-1
  反应条件:1.1 Reagents: Tristearyl Phosphite; Rt -> 120 °C; 2 H,120 °C1.2 Reagents: Hydrogen Catalysts: Ruthenium Solvents: Toluene; 4 H,2 Mpa,100 °C
  标题:Pretreatment Method And Application Of Methylpyran Solution In The Preparation Of Leaf Alcohol
  参考文献:China]
  
  1002-28-4 = 928-96-1
  反应条件:1.1 Reagents: Zinc Solvents: Ethanol; 3 H,Reflux
  标题:Zinc
  作者:Knochel,Paul; Grenouillat,Nathalie
  参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2006 卷标:1 页码:1-17]
  
  1002-28-4 = 928-96-1
  反应条件:1.1 Catalysts: 4,4′-Bis(1,1-Dimethylethyl)-1,1′-Biphenyl,Lithium,Nickel Dichloride Solvents: Tetrahydrofuran; 10 Min,Rt1.2 Reagents: Ethanol Solvents: Tetrahydrofuran; 8 H,Rt
  标题:Highly Selective Hydrogenation Of Multiple Carbon-Carbon Bonds Promoted By Nickel(0) Nanoparticles
  作者:Alonso,Francisco; Osante,Inaki; Yus,Miguel
  参考文献:Tetrahedron 日期:2007 卷标:63(1) 页码:93-102]
  
  13894-62-7 = 928-96-1
  反应条件:1.1 Catalysts: (Oc-6-22)-Bis(Benzoato-Ko)Bis[2-(Dimethylamino-Kn)Ethanol-Ko]Zinc Solvents: Diisopropyl Ether1.2 -1.3 Reagents: Potassium Hydroxide Solvents: Water
  标题:Reduction Of Carbonyl Compounds By A Silane In The Presence Of A Zinc Catalyst
  参考文献:World Intellectual Property Organization]
  
  55230-25-6 = 928-96-1
  反应条件:1.1 Reagents: Trimethoxysilane Catalysts: Boron Trifluoride,Iron Chloride (Fecl3) Solvents: Toluene; 20 Min,0.04 Mpa,70 °C
  标题:Method For Synthesizing Leaf Alcohol In The Presence Of Silane-Lewis Acid Catalyst System
  参考文献:China]
  
  1002-28-4 = 928-96-1
  反应条件:1.1 Reagents: Triethanolamine Catalysts: 2,3-Dihydroxynaphthalene,Copper (Loaded On 2,3-Dihydroxynaphthalene-Modified Tio2),Titania Solvents: Acetonitrile,Water; 20 H,329 K
  标题:Visible Light-Induced Diastereoselective Semihydrogenation Of Alkynes To Cis-Alkenes Over An Organically Modified Titanium(Iv) Oxide Photocatalyst Having A Metal Co-Catalyst
  作者:Fukui,Makoto; Omori,Yuya; Kitagawa,Shin-Ya; Tanaka,Atsuhiro; Hashimoto,Keiji; Et Al
  参考文献:Journal Of Catalysis 日期:2019 卷标:374 页码:36-42]
  
  1002-28-4 = 928-96-1
  反应条件:1.1 Reagents: Formic Acid,Triethylamine Catalysts: Gold (Titanium Oxide Composites),Titania Solvents: Acetone; 2 H,Rt
  标题:Heterogeneous Gold-Catalyzed Selective Semireduction Of Alkynes Using Formic Acid As Hydrogen Source
  作者:Li,Shu-Shuang; Tao,Lei; Wang,Fu-Ze-Rong; Liu,Yong-Mei; Cao,Yong
  参考文献:Advanced Synthesis & Catalysis 日期:2016 卷标:358(9) 页码:1410-1416

海关参考信息

• 2901210000-乙烯
  2901220000-丙烯
  2905121000-正丙醇
• 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
• 详情请参考：📖 海关编码查询和海关进出口税则

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