二氯二甲基硅烷置于水体系中,化学反应生成 六甲基环三硅氧烷 参考文献:Patnode; Wilcock,Journal Of The American Chemical Society,1946,Vol. 68,P. 360,363 标题:Patnode; Wilcock,Journal Of The American Chemical Society,1946,Vol. 68,P. 360,363
专利信息
专利号:US-2006293466-A1 优先权日:2003-06-20 标 题:Methods for synthesis of graft polymers 发明人:GAUTHIER MARIO; YUAN ZHONGSHUN 权利人:UNIV WATERLOO 摘要:A process for the synthesis of arborescent polymers comprises epoxidation of a first polymer and grafting thereto a second polymer having groups reactive to the epoxide groups on the first polymer. The epoxidation and grafting steps can be repeated. In an additional embodiment, the present invention provides a one-pot method for the synthesis of arborescent polymers. In a reaction pot, a first polymer is copolymerized and then reacted with an activating compound in order to generate a polyfunctional macroinitiator. Monomers are then added to the reaction pot, the monomers having functional groups reactive towards reactive sites on the first polymer.
专利号:US-6428778-B1 优先权日:1999-05-29 标题 :Process for the synthesis of finely divided antiperspirant active ingredient suspensions 发明人:BREKER JOHANNES; KAUFMANN BRUNO; REIBEL WOLFGANG; SCHANZ KLAUS 权利人:BK GUILINI CHEMIE GMBH UND CO 摘要:A process for synthesis of finely divided antiperspirant suspensions includes providing an antiperspirant salt consisting essentially of an Al salt which is effective as an antiperspirant and which is described by an empirical formula as follows: Al(OH)( 3−b) X b zH 2 O where b=0.4 to 3, z<4, and X=halogen; mixing the Al salt into a non-aqueous oil phase to provide a mixture; and subsequently grinding the mixture with a suitable milling device at a temperature below 80° C. to provide a suspension having a preselected fineness. A perspiration-inhibiting cosmetic preparation includes, as active ingredient, the antiperspirant suspension described above.
专利号:US-10428206-B2 优先权日:2015-07-02 标 题 :Process for the continuous synthesis of a modified diene elastomer 发明人:DORATO MARGARITA; FLESINSKI LIONEL 权利人:MICHELIN & CIE 摘要:A process for the continuous synthesis of a modified diene elastomer includes:n polymerization by n reactors r1 to rn equipped with an internal stirring system, the reactor r1 being fed by an input solution comprising a solvent, one or more monomers, an anionic polymerization initiator and a polar agent, one or more of the reactors being fed by reinjection of a purified solution comprising solvent and/or monomer(s), the number of dead chains in the output stream from the reactor rn is less than 30% of the number of living chains initiated in the reactor r1, the temperature of each reactor varying from 20° C. to 150° C.; and modification of the living diene elastomer obtained in the preceding stage and exhibiting a polydispersity index varying from 1.1 to 2, making it possible to introduce, into the elastomer, a functional group comprising at least one silicon atom directly connected to the elastomer chain.
专利号:US-11472916-B2 优先权日:2018-01-17 标题:Flow controlled synthesis of bottlebrush macromolecules 发明人:GUIRONNET DAMIEN S; WALSH DYLAN J 权利人:UNIV ILLINOIS 摘要:Shape, size and composition are nature's most fundamental design features, enabling highly complex functionalities. Despite recent advances, the independent control of shape, size and chemistry of macromolecules remains a synthetic challenge. Herein reported is a scalable methodology to produce large well-defined macromolecules with programmable shape, size and chemistry that combines reactor engineering principles and controlled polymerizations. Specifically, bottlebrush polymers with conical, ellipsoidal and concave architectures are synthesized using two orthogonal polymerizations. The chemical versatility is highlighted by the synthesis of a compositional asymmetric cone. The strong agreement between predictions and experiments validate the precision that this methodology offers.
专利号:US-7732414-B2 优先权日:2000-12-22 标题 :C-glycoside compounds for stimulating the synthesis of glycosaminoglycans 发明人:DALKO MARIA; BRETON LIONEL 权利人:OREAL 摘要:C-glycoside compounds are suited for stimulating the synthesis of glycosaminoglycans containing a D-glucosamine and/or N-acetyl-D-glucosamine residue, advantageously hyaluronic acid, and/or proteoglycans, advantageously proteoglycans containing hyaluronic acid, by fibroblasts and/or keratinocytes.
专利号:US-6774114-B2 优先权日:2000-04-10 标 题:Topical application of immixture of ascorbic acid + ascorbic acid compounds for augmenting the synthesis of epidermal ceramides 发明人:CASTIEL ISABELLE; FERRARIS CORINNE; LAVALLE-BOUCHARD ARMELLE 权利人:OREAL 摘要:Synergistic immixtures of ascorbic acid with at least one monosaccharide ester of ascorbic acid and/or at least one metal salt of phosphorylated ascorbic acid more effectively increase the synthesis of epidermal ceramides in human skin, especially types IV to VII ceramides, as well as improve the barrier function, moisture content and/or suppleness/surface appearance of the skin and which otherwise combat/prevent intrinsic aging thereof and are useful for the treatment of dermatitis.
摘要:Anderson, E. A.; Lim, D. S. W., Science of Synthesis Knowledge Updates, (2015) 1, 63. 摘要:Hardman-Baldwin, A. M.; Mattson, A. E., Science of Synthesis Knowledge Updates, (2017) 1, 233. 摘要:Denmark, S.; Chang, W.-T. T., Science of Synthesis: Cross Coupling and Heck-Type Reactions, (2012) 1, 402. 摘要:S13 | EUCOSMETICS | Combined Inventory of Ingredients Employed in Cosmetic Products (2000) and Revised Inventory (2006) | DOI:10.5281/zenodo.2624118 参考文献:10.1007/s10886-006-9091-2 摘要:Röck F, Mueller S, Weimar U, Rammensee H, Overath P. Comparative Analysis of Volatile Constituents from Mice and their Urine. Journal of Chemical Ecology. 2006 May 31;32(6):1333–46. doi: 10.1007/s10886-006-9091-2.