CAS: 84-65-1; Anthracene-9,10-Dione

• 英文名称Anthracene-9,10-Dione
• 中文名称蒽醌
• IUPAC名称anthracene-9,10-dione
• 其它别名9,10-Dioxoanthracene; 9,10-dihydro-9,10-dioxoanthracene; Hoelite; Morkit; Anthracenedione; 9,10-Anthraquinone
• CAS编号84-65-1
• MFCD编号:MFCD00001188
• EINECS号:201-549-0
• FDA UNII编号:030MS0JBDO
• 分子式:C14H8O2
• 分子量:208.21212
• 产品CID: 1836076
• 产品分类有机原料→分子砌块→芳环类化合物→苯类化合物

• 相似结构搜索
• 产品信息参考;;;;
• InChIKey: RZVHIXYEVGDQDX-UHFFFAOYSA-N
• InChI=1S/C14H8O2/c15-13-9-5-1-2-6-10(9)14(16)12-8-4-3-7-11(12)13/h1-8H…
• 计算化学: 氢键受体数2.0氢键供体数0.0可旋转键数0.0

物理性质

• 熔点284-286°C
• 沸点379-381°C at 760 mmHg
• 闪点185°C
• 密度1.3±0.1 g/cm3
• PSA:34.14
• LogP:2.462
• 折射率1.659
• 蒸汽压0.0±0.9 mmHg at 25°C
• 溶解性0.00007G/l
• 敏感性1. 本品低毒。能引起过敏性湿疹、鼻炎、支气管哮喘。生产车间应有良好的通风，设备要密闭，操作人员应穿戴防护用具。2. 存在于香料烟烟叶、烟气中。3. 不易被氧化，能被溴化、硝化和磺化。
• 外观形态黄绿色至卡其色至棕褐色粉末
• 储存条件2-8°C
• 产品应用蒽醌绝大部分用于染料方面,但用作制纸浆的蒸解助剂的用量已在迅速增加.(1)用于染料的生产以蒽醌为原料,经磺化,氯化,硝化等,可得到范围很广的染料中间体,用于生产蒽醌系分散染料,酸性染料,还原染料;反应染料等,形成色谱全;性能好的染料类别.据统计,蒽醌染料有四百多个品种,在合成染料领域中占有很重要的地位.(2)用作造纸制浆蒸煮剂在碱法蒸煮液中只需加入少量蒽醌,即可加快脱木素的速度,缩短蒸煮时间,提高纸浆得率,减少废液负荷.目前使用蒽醌添加剂的造纸厂越来越多.蒽醌作为蒸煮添加剂的消费量增长得很快.蒽醌还有其
• 性质描述该品为稍带淡黄色的单斜针状晶体.熔点为286°C(升华),沸点376.8°C(377°C),相对密度1.438(4/4°C),闪点(闭杯)185°C.易升华,约450°C下分解.溶于乙醇,乙醚和丙酮,不溶于水.不易被氧化,能被溴化,硝化和磺化,可燃,低毒.

MSDS等安全信息

• GHS象形图
• GHS符号GHS08 & GHS07;
  注释: Health hazard & Exclamation mark
• 危险类别致癌性 类别1B
  皮肤致敏 类别1
  皮肤致敏 类别1B
  急性毒性 类别4(吸入)
  急性毒性 类别4(经皮)
  水生急性毒性 类别1
  致癌性 类别2
  急性毒性 类别4(经口)
• 警示词Danger(危险)
• 危险描述H350 |可能致癌.
  H317 |可能引起皮肤过敏反应.
  H332 |吸入有害.
  H312 |皮肤接触有害.
  H400 |对水生生物毒性极大.
  H351 |怀疑致癌.
  H302 |吞咽有害.
• 防范说明P261-P272-P280-P302+P352-P363-P405-P501
• 危险等级9
• UN编号3077
• 危险品标志Xi
• 包装等级III
• 安全声明36/37-37/39-26-24
• 危险类别码43-36/37/38
• WGK Germany1

欧盟法规

上下游产品

合成工艺路线路线简述

• 613-31-0 = 84-65-1
  反应条件:1.1 Reagents: 1-Methylethyl 2-Iodylbenzoate Catalysts: μ-Oxobis[2,9,16,23-Tetrakis(1,1-Dimethylethyl)-29H,31H-Phthalocyaninato(2-)-Kn29... Solvents: Toluene; 2.5 H,110 °C
  标题:μ-Oxo-Bis[tetrakis(T-Butyl)Phthalocyaninatoiron(Iii)]
  作者:Lee,Ju-Hyeon; Bhattarai,Deepak; Keum,Gyochang
  参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2013 卷标:1 页码:1-3]
  
  1705-82-4 = 84-65-1
  反应条件:1.1 Reagents: Dimethyldioxirane Solvents: Acetone
  标题:Dioxirane Oxidations Of Compounds Other Than Alkenes
  作者:Adam,Waldemar; Zhao,Cong-Gui; Jakka,Kavitha
  参考文献:Organic Reactions (Hoboken 日期:2007 卷标:69 页码:1-346]
  
  85-52-9 = 84-65-1
  反应条件:1.1 Catalysts: Silica,Tungsten Hydroxide Oxide Phosphate; 3 H,250 °C1.2 2 H,220 °C
  标题:Synthesis Of Anthraquinone Over Hpw/sio2 Catalyst
  作者:Wang,Guirong; Luan,Yanqin; Hao,Suxia; Zhao,Xinqiang; Wang,Yanji
  参考文献:Shiyou Huagong 日期:2011 卷标:40(1) 页码:69-74]
  
  = 84-65-1
  反应条件:1.1 Reagents: Iodosylbenzene Catalysts: (Sp-5-31)-Carbonyl[5,10,15,20-Tetraphenyl-21H,23H-Porphinato(2-)-Kn21,Kn22,Kn23,... Solvents: Dichloromethane; 24 H,Rt
  标题:Transition Metal-Mediated Oxidations Utilizing Monomeric Iodosyl- And Iodylarene Species
  作者:Yusubov,Mekhman S.; Nemykin,Victor N.; Zhdankin,Viktor V.
  参考文献:Tetrahedron 日期:2010 卷标:66(31) 页码:5745-5752]
  
  613-31-0 = 84-65-1
  反应条件:1.1 Reagents: Picolinic Acid Catalysts: Iron Chloride (Fecl3) Solvents: Acetonitrile,Pyridine; 30 Min1.2 Reagents: Tert-Butyl Hydroperoxide; 30 Min
  标题:Gif Chemistry For Oxidation Of Activated Methylenes To Ketones
  作者:Kim,Sung Soo; Sar,Santosh Kumar; Tamrakar,Pankaj
  参考文献:Bulletin Of The Korean Chemical Society 日期:2002 卷标:23(7) 页码:937-938]
  
  4741-24-6 = 84-65-1
  反应条件:1.1 Catalysts: Sodium Hydroxide Solvents: Dichloromethane-D2; 5 Min,Rt
  标题:Base Catalysed Decomposition Of Anthracene Endoperoxide
  作者:Klaper,M.; Wessig,P.; Linker,T.
  参考文献:Chemical Communications (Cambridge 日期:2016 卷标:52(6) 页码:1210-1213]
  
  = 84-65-1
  反应条件:1.1 Reagents: Iodosylbenzene Catalysts: Bis(Methanol)-μ-Oxobis[c,C,C-Tris(1,1-Dimethylethyl)-29H,31H-Tribenzo[b,G,L]Pyri... Solvents: Methanol; 2 H,25 °C
  标题:Binuclear Iron(Iii) Phthalocyanine(μ-Oxo-Dimer)-Catalyzed Oxygenation Of Aromatic Hydrocarbons With Iodosylbenzene Sulfate And Iodosylbenzene As The Oxidants
  作者:Neu,Heather M.; Yusubov,Mekhman S.; Zhdankin,Viktor V.; Nemykin,Victor N.
  参考文献:Advanced Synthesis & Catalysis 日期:2009 卷标:351(18) 页码:3168-3174]
  
  = 84-65-1
  反应条件:1.1 Reagents: Formic Acid,Triethylamine Catalysts: Triphenylphosphine,Palladium Diacetate Solvents: Dimethylformamide
  标题:Palladium-Catalyzed Reduction Of Aryl Sulfonates. Reduction Versus Hydrolysis Selectivity Control
  作者:Cabri,Walter; De Bernardinis,Silvia; Francalanci,Franco; Penco,Sergio; Santi,Roberto
  参考文献:Journal Of Organic Chemistry 日期:1990 卷标:55(1) 页码:350-3]
  
  613-31-0 = 84-65-1
  反应条件:1.1 Reagents: Oxygen Catalysts: Carbon Nitride (C3N4) Solvents: Acetonitrile; 24 H,25 °C
  标题:G-C3N4 - Singlet Oxygen Made Easy For Organic Synthesis: Scope And Limitations
  作者:Camussi,Irene; Mannucci,Barbara; Speltini,Andrea; Profumo,Antonella; Milanese,Chiara; Et Al
  参考文献:Acs Sustainable Chemistry & Engineering 日期:2019 卷标:7(9) 页码:8176-8182]
  
  = 84-65-1
  反应条件:1.1 Reagents: Hydrogen Peroxide Catalysts: (Acetonitrile)[2,2,2-Trifluoro-N′-(2,3,4,5,6-Pentafluorophenyl)-N-[2,2,2-Trifluo... Solvents: Acetonitrile,Dichloromethane,Water; 2 H,60 °C
  标题:Copper(I)-Based Oxidation Of Polycyclic Aromatic Hydrocarbons And Product Elucidation Using Vacuum Ultraviolet Spectroscopy And Theoretical Spectral Calculations
  作者:Ponduru,Tharun T.; Qiu,Changling; Mao,James X.; Leghissa,Allegra; Smuts,Jonathan; Et Al
  参考文献:New Journal Of Chemistry 日期:2018 卷标:42(24) 页码:19442-19449]
  
  = 84-65-1
  反应条件:1.1 Reagents: Hydrogen Peroxide Catalysts: Molybdovanadophosphoric Acid (H5Pmo10V2O40),Dimethylaminoethyl Methacrylate-Styrene Diblock Copolymer Solvents: Acetonitrile,Water; 85 H,40 °C
  标题:Pombranes: Polyoxometalate-Functionalized Block Copolymer Membranes For Oxidation Catalysis
  作者:Romanenko,I.; Lechner,M.; Wendler,F.; Hoerenz,C.; Streb,C.; Et Al
  参考文献:Journal Of Materials Chemistry A: Materials For Energy And Sustainability 日期:2017 卷标:5(30) 页码:15789-15796]
  
  = 84-65-1
  反应条件:1.1 Catalysts: Cobalt Tetraphenylporphine Solvents: Dichloromethane; 2 H,Rt
  标题:Cobalt,[5,10,15,20-Tetraphenyl-21H,23H-Porphinato(2-)-Kn21,Kn22,Kn23,Kn24]-
  作者:Singh,Sanjay K.; Collier,Steven J.
  参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2013 卷标:1 页码:1-5]
  
  = 84-65-1
  反应条件:1.1 Reagents: Tert-Butyl Hydroperoxide Catalysts: Chromium (Trimesic Acid Processed Metal-Organic Framework) Solvents: Chlorobenzene,Water; 2.5 H,100 °C
  标题:Hydrocarbon Oxidation Over Fe- And Cr-Containing Metal-Organic Frameworks Mil-100 And Mil-101-A Comparative Study
  作者:Kholdeeva,Oxana A.; Skobelev,Igor Y.; Ivanchikova,Irina D.; Kovalenko,Konstantin A.; Fedin,Vladimir P.; Et Al
  参考文献:Catalysis Today 日期:2014 卷标:238 页码:54-61]
  
  90-44-8 = 84-65-1
  反应条件:1.1 Reagents: Tert-Butyl Hydroperoxide Catalysts: Manganese Oxide (Mno2) Solvents: Acetonitrile,Water; 10 H,80 °C
  标题:Oxidation Of Alkyl Aromatics To Ketones By Tert-Butyl Hydroperoxide On Manganese Dioxide Catalyst
  作者:Burange,Anand S.; Kale,Sandip R.; Jayaram,Radha V.
  参考文献:Tetrahedron Letters 日期:2012 卷标:53(24) 页码:2989-2992]
  
  = 84-65-1
  反应条件:1.1 Reagents: Hydrogen Peroxide Catalysts: 1-Butanaminium,N,N,N-Tributyl-,Hydrogen Tetracosa-μ-Oxododecaoxo[μ12-[tetrahyd... Solvents: Acetonitrile,Water; 24 H,80 °C
  标题:Oxidation Of Polycyclic Aromatic Hydrocarbons With Hydrogen Peroxide In The Presence Of Transition Metal Mono-Substituted Keggin-Type Polyoxometalates
  作者:Estrada,Ana C.; Simoes,Mario M. Q.; Santos,Isabel C. M. S.; Neves,M. Graca P. M. S.; Cavaleiro,Jose A. S.; Et Al
  参考文献:Chemcatchem 日期:2011 卷标:3(4) 页码:771-779]
  
  = 84-65-1
  反应条件:1.1 Reagents: 1-Methylethyl 2-Iodylbenzoate Catalysts: Ferrate(2-),μ-Oxobis[2,9,16,23-Tetrakis(1,1-Dimethylethyl)-29H,31H-Phthalocyani... Solvents: Toluene; 2.5 H,110 °C
  标题:Comparative Reactivity Of Hypervalent Iodine Oxidants In Metalloporphyrin-Catalyzed Oxygenation Of Hydrocarbons: Iodosylbenzene Sulfate And 2-Iodylbenzoic Acid Ester As Safe And Convenient Alternatives To Iodosylbenzene
  作者:Geraskin,Ivan M.; Pavlova,Olga; Neu,Heather M.; Yusubov,Mekhman S.; Nemykin,Victor N.; Et Al
  参考文献:Advanced Synthesis & Catalysis 日期:2009 卷标:351(5) 页码:733-737]
  
  90-44-8 = 84-65-1
  反应条件:1.1 Reagents: Oxygen Solvents: Dimethyl Sulfoxide; 760 Mm Hg,25 °C -> 70 °C
  标题:Oxidation Of Anthrone With Oxygen In Dmso
  作者:Opeida,I. A.; Kas'Yanchuk,M. G.
  参考文献:Russian Journal Of Organic Chemistry (Translation Of Zhurnal Organicheskoi Khimii) 日期:2002 卷标:38(6) 页码:905-906]
  
  90-44-8 = 84-65-1
  反应条件:1.1 Reagents: Oxygen Solvents: Dimethyl Sulfoxide
  标题:Kinetics And Mechanism Of The Liquid-Phase Oxidation Of 10-Dihydro-9-Ketoanthracene In Basic Aprotic Media
  作者:Opeida,I. A.; Kasyanchuk,M. G.
  参考文献:Theoretical And Experimental Chemistry (Translation Of Teoreticheskaya I Eksperimental'Naya Khimiya) 日期:2002 卷标:38(1) 页码:37-42]
  
  = 84-65-1 + 82-35-9
  反应条件:1.1 Reagents: Nitric Acid; 8 H,333 - 353 K
  标题:Sub-4 Nm Nanodiamonds From Graphene-Oxide And Nitrated Polycyclic Aromatic Hydrocarbons At 423 K
  作者:Shen,Yuting; Et Al
  参考文献:Acs Nano 日期:2021 卷标:15(11) 页码:17392-17400

海关参考信息

• 2912110000-甲醛
  2912210000-苯甲醛
  2914610000-蒽醌
  2914190090-其他无环酮
• 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
• 详情请参考：📖 海关编码查询和海关进出口税则

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