CAS: 98-03-3; Thiophene-2-Carbaldehyde

• 英文名称Thiophene-2-Carbaldehyde
• 中文名称噻吩-2-甲醛
• IUPAC名称thiophene-2-carbaldehyde
• 其它别名2-Formylthiophene; 2-Thiophenecarboxaldehyde; 2-Thiophene carboxaldehyde; Thiophene-2-carbaldehyde
• CAS编号98-03-3
• MFCD编号:MFCD00005429
• EINECS号:202-629-8
• FDA UNII编号:IW05BB9XBM
• 分子式:C5H4OS
• 分子量:112.15
• 产品CID: 2485180
• 产品分类有机原料→分子砌块→芳杂环类化合物→噻吩类化合物

• 相似结构搜索
• InChIKey: CNUDBTRUORMMPA-UHFFFAOYSA-N
• InChI=1S/C5H4OS/c6-4-5-2-1-3-7-5/h1-4H…
• 计算化学: 氢键受体数2.0氢键供体数0.0可旋转键数1.0

物理性质

• 熔点<10°C
• 沸点198°C at 760 mmHg
• 闪点77°C
• 密度1.2±0.1 g/cm3
• PSA:17.07
• LogP:1.5606
• 折射率1.610
• 蒸汽压0.4±0.4 mmHg at 25°C
• 溶解性Chloroform (Slightly), DMSO (Slightly), Ethyl Acetate (Slightly)
• 敏感性空气敏感
• 外观形态透明黄色液体 (透明)
• 储存条件2-8°C
• 产品应用用来在有机化合物中引入噻吩基团,例如,将噻吩基团引入二甲基四氢嘧啶.所得产物与双羟萘酸成盐即得制广谱驱虫药噻嘧啶.
• 性质描述油状液体.沸点198°C,93-94°C(2.67kPa),44-45°C(0.133kPa),相对密度1.215(21/21),折光率1.5920,闪点77°C.易溶于醇,苯,醚,微溶于水.有类似杏仁味.

MSDS等安全信息

• GHS象形图
• GHS符号GHS07;
  注释: Exclamation mark
• 危险类别急性毒性 类别4(经口)
  特定目标器官毒性 - 单次接触 类别3
  皮肤腐蚀/刺激 类别2
  严重眼刺激 类别2
  皮肤致敏 类别1
  急性毒性 类别4(吸入)
  急性毒性 类别4(经皮)
  严重眼刺激 类别2A
  易燃液体 类别4
• 警示词Warning(警告)
• 危险描述H302 |吞咽有害.
  H335 |可能引起呼吸道刺激.
  H315 |造成皮肤刺激.
  H319 |造成严重眼刺激.
  H317 |可能引起皮肤过敏反应.
  H332 |吸入有害.
  H312 |皮肤接触有害.
  H227 |可燃液体
• 防范说明P210-P264-P270-P280-P330-P370+P378-P403-P501
• UN编号UN 2810
• 危险品标志Xn,Xi
• 风险等级Irritant
• 安全声明36/37/39-37-24-36-26
• 危险类别码22-36/37/38-43
• WGK Germany3.0

欧盟法规

上下游产品

合成工艺路线路线简述

• 636-72-6 = 98-03-3
  反应条件:1.1 Reagents: Tert-Butyl Nitrite Catalysts: 2579169-90-5 Solvents: (Trifluoromethyl)Benzene; 5 H,80 °C
  标题:Synthesis Of Tempo Radical Decorated Hollow Porous Aromatic Frameworks For Selective Oxidation Of Alcohols
  作者:Shen,Yan-Ming; Xue,Yun; Yan,Mi; Mao,Hui-Ling; Cheng,Hu; Et Al
  参考文献:Chemical Communications (Cambridge 日期:2021 卷标:57(7) 页码:907-910]
  
  636-72-6 = 98-03-3
  反应条件:1.1 Catalysts: 1H-Imidazolium,3,3′-[1,3-Phenylenebis(Methylene)]Bis[1-Ethenyl-,Bromide (1:2),... (Ion-Exchanged,Pyrolyzed) Solvents: Dimethyl Sulfoxide; Rt -> 120 °C; 12 H,120 °C
  标题:N-Doped Carbon Encapsulated Molybdenum Carbide As An Efficient Catalyst For Oxidant-Free Dehydrogenation Of Alcohols
  作者:Leng,Yan; Li,Jingjing; Zhang,Chenjun; Jiang,Pingping; Li,Yue; Et Al
  参考文献:Journal Of Materials Chemistry A: Materials For Energy And Sustainability (2017 日期:2017 卷标:5(33) 页码:17580-17588]
  
  57009-79-7 = 98-03-3
  反应条件:1.1 Reagents: Quinone,Oxygen Catalysts: Sodium Iodide Solvents: Acetonitrile,Water; 48 H,100 °C
  标题:Facile Deprotection Of Dithioacetals By Using A Novel 1,4-Benzoquinone/cat. Nai System
  作者:Inamoto,Kiyofumi; Yamada,Tetsuya; Kato,Sei-Ichi; Kikkawa,Shoko; Kondo,Yoshinori
  参考文献:Tetrahedron (2013 日期:2013 卷标:69(44) 页码:9192-9199]
  
  636-72-6 = 98-03-3
  反应条件:1.1 Reagents: Oxygen Catalysts: Platinum (Carbon-Supported) Solvents: 1,4-Dioxane,Water; 3 H,20 Bar,100 °C
  标题:Oxidation Of Primary Alcohols With Air On Carbon-Supported Platinum Catalysts For The Synthesis Of Aldehydes Or Acids
  作者:Korovchenko,Pavel; Donze,Cecile; Gallezot,Pierre; Besson,Michele
  参考文献:Catalysis Today (2007 日期:2007 页码:1-2]
  
  636-72-6 = 98-03-3
  反应条件:1.1 Reagents: 1,10-Phenanthroline,Cuprous Chloride Solvents: Toluene1.2 Reagents: Potassium Carbonate,1,2-Diethyl 1,2-Hydrazinedicarboxylate,Oxygen
  标题:Efficient,Ecologically Benign,Aerobic Oxidation Of Alcohols
  作者:Marko,Istvan. E.; Giles,Paul R.; Tsukazaki,Masao; Chelle-Regnaut,Isabelle; Gautier,Arnaud; Et Al
  参考文献:Journal Of Organic Chemistry (1999 日期:1999 卷标:64(7) 页码:2433-2439]
  
  636-72-6 = 98-03-3
  反应条件:1.1 Reagents: Oxygen Catalysts: Cobalt Oxide (Co3O4),Manganese Solvents: Acetonitrile; 6 H,60 °C
  标题:Manganese Doping In Cobalt Oxide Nanorods Promotes Catalytic Dehydrogenation
  作者:Ke,Qingping; Yi,Ding; Jin,Yangxin; Lu,Fei; Zhou,Bo; Et Al
  参考文献:Acs Sustainable Chemistry & Engineering (2020 日期:2020 卷标:8(14) 页码:5734-5741]
  
  636-72-6 = 98-03-3
  反应条件:1.1 Reagents: Oxygen Catalysts: Ruthenium Dioxide,Graphene Solvents: Toluene; 1 Atm,Rt -> 100 °C; 8 H,100 °C
  标题:High-Throughput Production Of Heterogeneous Ruo2/graphene Catalyst In A Hydrodynamic Reactor For Selective Alcohol Oxidation
  作者:Jeong,Jae-Min; Jin,Se Bin; Yoon,Jo Hee; Yeo,Jae Goo; Lee,Geun Young; Et Al
  参考文献:Catalysts (2019 日期:2019 卷标:9(1) 页码:1-25]
  
  636-72-6 = 98-03-3
  反应条件:1.1 Reagents: Sodium Hypochlorite Catalysts: (Sp-5-13)-Chloro[3,4,8,9-Tetrahydro-3,3,6,9,9-Pentamethyl-1H-1,4,6,8,11-Benzopen... Solvents: Acetonitrile,Water; 5 H,Ph 7,Rt
  标题:Catalytic Oxidation Of Alcohols Using Fe-Btaml And Naclo: Comparing The Reactivity Of Fe(V)O And Fe(Iv)O Intermediates
  作者:Jana,Sandipan; Thomas,Jithin; Sen Gupta,Sayam
  参考文献:Inorganica Chimica Acta (2019 日期:2019 页码:476-482]
  
  636-72-6 = 98-03-3
  反应条件:1.1 Catalysts: Tempo,2286259-65-0 Solvents: Acetonitrile; 2 H,30 °C
  标题:Base-Free Aerobic Oxidation Of Alcohols Over Copper-Based Complex Under Ambient Condition
  作者:Mei,Qingqing; Liu,Huizhen; Yang,Youdi; Liu,Hangyu; Li,Shaopeng; Et Al
  参考文献:Acs Sustainable Chemistry & Engineering (2018 日期:2018 卷标:6(2) 页码:2362-2369]
  
  636-72-6 = 98-03-3
  反应条件:1.1 Catalysts: Cuprous Iodide,N-(1-Hydroxy-2,2,6,6-Tetramethyl-4-Piperidinyl)[2,2′-Bipyridine]-5-Carboxamide Solvents: Acetonitrile; 2 Min,Rt1.2 Catalysts: 1-Methylimidazole; 2 Min,Rt1.3 Reagents: Oxygen; 4 H,25 °C
  标题:Bioinspired Aerobic Oxidation Of Alcohols With A Bifunctional Ligand Based On Bipyridine And Tempo
  作者:Wang,Lianyue; Bie,Zhixing; Shang,Sensen; Lv,Ying; Li,Guosong; Et Al
  参考文献:Rsc Advances (2016 日期:2016 卷标:6(41) 页码:35008-35013]
  
  636-72-6 = 98-03-3
  反应条件:1.1 Reagents: Sodium Perchlorate Catalysts: 4-[(2-Aminobenzoyl)Oxy]-2,2,6,6-Tetramethyl-1-Piperidinyloxy Solvents: Acetone,Water1.2 Reagents: Sodium Bicarbonate,Sodium Carbonate,Sodium Perchlorate Solvents: Acetonitrile,Water; 7 H,Rt
  标题:Efficient Electrooxidation Of Alcohols Using Tempo-Modified Polyaniline Electrode Prepared By Electrochemical Polymerization
  作者:Tang,Danyang; Yang,Xianjing; Chen,Qiguo; Shen,Zhenlu; Li,Meichao
  参考文献:Journal Of The Electrochemical Society (2016 日期:2016 卷标:163(5)]
  
  636-72-6 = 98-03-3
  反应条件:1.1 Reagents: Oxygen Catalysts: Alumina,Ruthenium Hydroxide Solvents: Toluene; 30 Min,Rt; Rt -> 80 °C; 1 H,11 Bar,80 °C
  标题:Continuous Flow Aerobic Alcohol Oxidation Reactions Using A Heterogeneous Ru(Oh)X/al2O3 Catalyst
  作者:Mannel,David S.; Stahl,Shannon S.; Root,Thatcher W.
  参考文献:Organic Process Research & Development (2014 日期:2014 卷标:18(11) 页码:1503-1508]
  
  636-72-6 = 98-03-3
  反应条件:1.1 Reagents: Tert-Butyl Nitrite,Oxygen Catalysts: Bis[1,3-Dihydro-1,1,3,3-Tetramethyl-4-(4-Pyridinyl-Kn)-7-(4-Pyridinyl)-2H-Isoind... Solvents: 1,1,2,2-Tetrachloroethane-D2; 24 H,80 °C
  标题:A Crystalline Porous Coordination Polymer Decorated With Nitroxyl Radicals Catalyzes Aerobic Oxidation Of Alcohols
  作者:Li,Liangchun; Matsuda,Ryotaro; Tanaka,Iku; Sato,Hiroshi; Kanoo,Prakash; Et Al
  参考文献:Journal Of The American Chemical Society (2014 日期:2014 卷标:136(21) 页码:7543-7546]
  
  636-72-6 = 98-03-3
  反应条件:1.1 Reagents: Oxygen Catalysts: Osmium Solvents: Toluene; 80 °C
  标题:Osmium(0) Nanoclusters Stabilized By Zeolite Framework; Highly Active Catalyst In The Aerobic Oxidation Of Alcohols Under Mild Conditions
  作者:Zahmakiran,Mehmet; Akbayrak,Serdar; Kodaira,Tetsuya; Oezkar,Saim
  参考文献:Dalton Transactions (2010 日期:2010 卷标:39(32) 页码:7521-7527]
  
  63011-97-2 = 98-03-3
  反应条件:1.1 Catalysts: 1-Butyl-3-Methylimidazolium Tetrafluoroborate Solvents: Water,1-Butyl-3-Methylimidazolium Tetrafluoroborate; 3 - 5 H,Rt
  标题:Mild And Efficient Conversion Of Aldehydes To Gem-Diacetates Using 2Nd Generation Ionic Liquids
  作者:Yadav,J. S.; Reddy,B. V. S.; Sreedhar,P.; Kondaji,G.; Nagaiah,K.
  参考文献:Catalysis Communications (2008 日期:2008 卷标:9(5) 页码:590-593]
  
  636-72-6 = 98-03-3
  反应条件:1.1 Catalysts: Bromo[1,1′-Thiobis[methane]]Copper,4,4′-Bis[[(2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-Heptadecafluorononyl)Oxy]Methyl]-2,... Solvents: Acetonitrile; 0.5 H,Rt1.2 Reagents: Tempo,Oxygen Solvents: Chlorobenzene; 8 H,90 °C; 90 °C -> 0 °C
  标题:Efficient,Recoverable,Copper-Catalyzed Aerobic Oxidation Of Alcohols Under Fbs And Thermomorphic Mode
  作者:Lu,Norman; Lin,Yan-Chou
  参考文献:Tetrahedron Letters (2007 日期:2007 卷标:48(50) 页码:8823-8828]
  
  636-72-6 = 98-03-3
  反应条件:1.1 Reagents: Oxygen Catalysts: Ruthenium Oxide (Mixed Oxide,Copper-Iron-Ruthenium-Manganese) Solvents: Toluene; 40 Min,60 °C
  标题:Aerobic Liquid-Phase Oxidation Of Alcohols With Solid Mixed Oxide Catalyst Under Mild Condition
  作者:Ji,Hong-Bing; Chen,Qing-Lin
  参考文献:Youji Huaxue (2006 日期:2006 卷标:26(4) 页码:491-496]
  
  636-72-6 = 98-03-3
  反应条件:1.1 Reagents: Oxygen Catalysts: 1-Methylimidazole,Tempo,Copper (Nitrogen-Doped Carbon-Incarcerated Copper Nanoparticle) Solvents: Acetonitrile; 20 H,1 Bar,60 °C
  标题:Aerobic Oxidation Of Alcohols Enabled By Nitrogen-Doped Copper Nanoparticle Catalysts
  作者:Tobita,Fumiya; Yasukawa,Tomohiro; Yamashita,Yasuhiro; Kobayashi,Shu
  参考文献:Catalysis Science & Technology (2022 日期:2022 卷标:12(4) 页码:1043-1048]
  
  636-72-6 = 98-03-3
  反应条件:1.1 Reagents: 1-Hydroxy-1,2-Benziodoxol-3(1H)-One 1-Oxide Solvents: Ethyl Acetate; Rt; 4 H,Rt -> Reflux
  标题:Nickel-Catalyzed,Regio- And Enantioselective Benzylic Alkenylation Of Olefins With Alkenyl Bromide
  作者:Liu,Jiandong; Gong,Hegui; Zhu,Shaolin
  参考文献:Angewandte Chemie 日期:2021 卷标:60(8) 页码:4060-4064]
  
  636-72-6 = 98-03-3
  反应条件:1.1 Reagents: Oxygen Catalysts: 1-Methylimidazole,Tempo,Copper(6+),Hexakis[μ3-[n1,N3-Bis[(1H-Imidazol-5-Yl-Kn1:Kn3)Methylene]-1,3-Propa... Solvents: Acetonitrile; 2 H,Rt
  标题:Self-Assembly Of A Mixed Valence Copper Triangular Prism And Transformation To Cage Triggered By An External Stimulus
  作者:Lai,Ya-Liang; Wang,Xue-Zhi; Zhou,Xian-Chao; Dai,Rui-Rong; Zhou,Xiao-Ping; Et Al
  参考文献:Inorganic Chemistry (2020 日期:2020 卷标:59(23) 页码:17374-17378]
  
  636-72-6 = 98-03-3
  反应条件:1.1 Reagents: 1-Methylimidazole,Oxygen Catalysts: Tempo,2445364-42-9 Solvents: Acetonitrile; 2 H,Rt
  标题:Self-Assembly Of Mixed-Valence And Heterometallic Metallocycles: Efficient Catalysts For The Oxidation Of Alcohols To Aldehydes In Ambient Air
  作者:Lai,Ya-Liang; Wang,Xue-Zhi; Dai,Rui-Rong; Huang,Yong-Liang; Zhou,Xian-Chao; Et Al
  参考文献:Dalton Transactions (2020 日期:2020 卷标:49(22) 页码:7304-7308]
  
  636-72-6 = 98-03-3
  反应条件:1.1 Reagents: Oxygen Catalysts: Oms 2 (Catalyst) Solvents: Toluene; 12 H,110 °C
  标题:Base-Free Synthesis Of 1,3,5-Triazines Via Aerobic Oxidation Of Alcohols And Benzamidine Over A Recyclable Oms-2 Catalyst
  作者:Shen,Jian; Meng,Xu
  参考文献:Catalysis Communications (2019 日期:2019 页码:58-63]
  
  636-72-6 = 98-03-3
  反应条件:1.1 Reagents: Oxygen Catalysts: 1-Methylimidazole,9-Azabicyclo[3.3.1]Non-9-Yloxy,Copper,Bromo(4′-Methoxy[2,2′-Bipyridin]-4-Ol-Kn1,Kn1′)- (Supported On Tentagel Resin) Solvents: Acetonitrile; 10 Min,Rt
  标题:Bipyridine Copper Functionalized Polymer Resins As Support Materials For The Aerobic Oxidation Of Alcohols
  作者:Sand,Henning; Weberskirch,Ralf
  参考文献:Polymer International (2017 日期:2017 卷标:66(3) 页码:428-435]
  
  1003-31-2 = 98-03-3
  反应条件:1.1 Reagents: Nickel,Phosphinic Acid,Compd. With N,N-Diethylethanamine (1:1) Solvents: Ethanol,Tetrahydrofuran
  标题:A New Hydrogen Source. 3. Chemoselective Reduction With Triethylammonium Hypophosphite Hydrate/raney Nickel And Tris(Triphenylphosphine)Ruthenium Dichloride Reagents
  作者:Khai,Bui The; Arcelli,Antonio
  参考文献:Journal Of Organic Chemistry (1989 日期:1989 卷标:54(4) 页码:949-53]
  
  636-72-6 = 98-03-3
  反应条件:1.1 Reagents: 1-Methylimidazole,Tempo Catalysts: Copper Bromide (Cubr),4-Fluoro-N-(2-Furanylmethylene)Benzenamine Solvents: Acetonitrile; 2 H,25 °C
  标题:Catalytic Behavior Of The Cu(I)/l/tempo System For Aerobic Oxidation Of Alcohols - A Kinetic And Predictive Model
  作者:Al-Hunaiti,Afnan; Abu-Radaha,Batool; Wraith,Darren; Repo,Timo
  参考文献:Rsc Advances (2022 日期:2022 卷标:12(13) 页码:7864-7871]
  
  636-72-6 = 98-03-3
  反应条件:1.1 Catalysts: 1-Methylimidazole,Copper Oxide (Cu2O),Iron Oxide (Fe3O4),Tempo Solvents: Acetonitrile; 18 H,25 °C
  标题:Magnetic Core-Shell Fe3O4@cu2O And Fe3O4@cu2O-Cu Materials As Catalysts For Aerobic Oxidation Of Benzylic Alcohols Assisted By Tempo And N-Methylimidazole
  作者:Xu,Binyu; Senthilkumar,Samuthirarajan; Zhong,Wei; Shen,Zhongquan; Lu,Chunxin; Et Al
  参考文献:Rsc Advances (2020 日期:2020 卷标:10(44) 页码:26142-26150]
  
  636-72-6 = 98-03-3
  反应条件:1.1 Reagents: Lithium Perchlorate Solvents: Methanol; 5.5 H,0 °C
  标题:Selective C-H Bond Electro-Oxidation Of Benzylic Acetates And Alcohols To Benzaldehydes
  作者:Barone,Mateus R.; Jones,Alan M.
  参考文献:Organic & Biomolecular Chemistry (2017 日期:2017 卷标:15(47) 页码:10010-10015]
  
  636-72-6 = 98-03-3
  反应条件:1.1 Reagents: Oxygen Catalysts: Graphene (Oxide) Solvents: Water; 30 H,0.2 Mpa,100 °C
  标题:Probing The Intrinsic Active Sites Of Modified Graphene Oxide For Aerobic Benzylic Alcohol Oxidation
  作者:Zhu,Shanhui; Cen,Youliang; Yang,Miao; Guo,Jing; Chen,Chengmeng; Et Al
  参考文献:Applied Catalysis 日期:2017 页码:89-97]
  
  636-72-6 = 98-03-3
  反应条件:1.1 Catalysts: 2,2′-Bipyridine,Tempo,Ferric Nitrate Solvents: Acetic Acid; 5 Min,25 °C1.2 Reagents: Oxygen; 0.5 H,1 Atm,80 °C
  标题:Iron-Catalysed Selective Aerobic Oxidation Of Alcohols To Carbonyl And Carboxylic Compounds
  作者:Lagerblom,Kalle; Wrigstedt,Pauli; Keskivaeli,Juha; Parviainen,Arno; Repo,Timo
  参考文献:Chempluschem (2016 日期:2016 卷标:81(11) 页码:1160-1165]
  
  636-72-6 = 98-03-3
  反应条件:1.1 Reagents: Acetic Acid,Tert-Butyl Nitrite,Oxygen Catalysts: Tempone Solvents: Toluene; 1 H,1 Atm,50 °C
  标题:Synergistic Catalysis Within Tempo-Functionalized Periodic Mesoporous Organosilica With Bridge Imidazolium Groups In The Aerobic Oxidation Of Alcohols
  作者:Karimi,Babak; Vahdati,Saleh; Vali,Hojatollah
  参考文献:Rsc Advances (2016 日期:2016 卷标:6(68) 页码:63717-63723]
  
  636-72-6 = 98-03-3
  反应条件:1.1 Catalysts: Tempo,Sulfuric Acid,Iron Chloride (Fecl3),Sodium Bromate Solvents: Dichloromethane,Water; 3 H,Rt
  标题:Catalyzed Oxidation Of Alcohols By 2,2,6,6-Tetramethyl-1-Iperidinyloxy With Sodium Bromate And Ferric Chloride As Accelerators
  作者:Chu,Chaosen; Wang,Xiaoli; Hu,Yutao; Yan,Xiumei; Wang,Zheng
  参考文献:Yingyong Huaxue (2015 日期:2015 卷标:32(6) 页码:666-670]
  
  636-72-6 = 98-03-3
  反应条件:1.1 Reagents: Iodine(1+),Bis(Acetato-Ko)[4-[3-(Trimethylammonio)Propoxy]Phenyl]-,4-Methylben... Catalysts: Tempo Solvents: Dichloromethane; 6 H,Rt
  标题:Various Oxidative Reactions With Novel Ion-Supported (Diacetoxyiodo)Benzenes
  作者:Iinuma,Masataka; Moriyama,Katsuhiko; Togo,Hideo
  参考文献:Tetrahedron (2013 日期:2013 卷标:69(14) 页码:2961-2970]
  
  636-72-6 = 98-03-3
  反应条件:1.1 Reagents: Dodecane,Oxygen Catalysts: Palladium Solvents: P-Xylene; 10 H,1 Atm,110 °C
  标题:Highly Dispersed Palladium Nanoparticles On Mesocellular Foam. An Efficient And Recyclable Heterogeneous Catalyst For Alcohol Oxidation
  作者:Johnston,Eric V.; Verho,Oscar; Kaerkaes,Markus D.; Shakeri,Mozaffar; Tai,Cheuk-Wai; Et Al
  参考文献:Chemistry - A European Journal (2012 日期:2012 卷标:18(39) 页码:12202-12206]
  
  636-72-6 = 98-03-3
  反应条件:1.1 Reagents: Iodine(1+),Bis(Acetato-Ko)[4-[3-(1-Methylpyrrolidinio)Propyl]Phenyl]-,4-Methyl... Catalysts: Tempo Solvents: Dichloromethane; 2 H,Rt
  标题:Tempo-Mediated Oxidation Of Alcohols With Ion-Supported (Diacetoxy Iodo)Benzenes
  作者:Suzuki,Yusuke; Iinuma,Masataka; Moriyama,Katsuhiko; Togo,Hideo
  参考文献:Synlett (2012 日期:2012 卷标:23(8) 页码:1250-1256]
  
  636-72-6 = 98-03-3
  反应条件:1.1 Reagents: Oxygen Catalysts: Ruthenium,Nickel Dihydroxide Solvents: Toluene; 0.25 H,363 K
  标题:Ruthenium-Functionalized Nickel Hydroxide Catalyst For Highly Efficient Alcohol Oxidations In The Presence Of Molecular Oxygen
  作者:Venkatesan,S.; Kumar,A. Senthil; Lee,Jyh-Fu; Chan,Ting-Shan; Zen,Jyh-Myng
  参考文献:Chemical Communications (Cambridge 日期:2009 页码:1912-1914]
  
  636-72-6 = 98-03-3
  反应条件:1.1 Reagents: Oxygen Catalysts: Palladium Solvents: Trifluorotoluene; 24 H,1 Atm,90 °C
  标题:Hydroxyapatite-Supported Palladium Nanoclusters: A Highly Active Heterogeneous Catalyst For Selective Oxidation Of Alcohols By Use Of Molecular Oxygen
  作者:Mori,Kohsuke; Hara,Takayoshi; Mizugaki,Tomoo; Ebitani,Kohki; Kaneda,Kiyotomi
  参考文献:Journal Of The American Chemical Society (2004 日期:2004 卷标:126(34) 页码:10657-10666

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