CAS: 111-80-8; Methyl Non-2-Ynoate

相似化合物

5921-73-3 111-80-8 111-12-6

上下游产品

CAS号629-05-0 1-辛炔 | CAS号79-22-1 氯甲酸甲酯 | CAS号68113-72-4 chlorozinc(1+),... | CAS号1846-70-4 2-壬炔酸 | CAS号74-88-4 碘甲烷 | CAS号67-56-1 甲醇 | CAS号81438-46-2 1-iodo°Ct-1-yne | CAS号201230-82-2 carbon monoxide | CAS号110296-07-6 °Ct-1-yn-1-yl(p... | CAS号133188-94-0 non-2-ynylsulfa... | CAS号41453-56-9 顺-2-壬烯-1-醇

1-辛炔置于正丁基锂,硫酸体系中,用 四氢呋喃,正己烷 用作溶剂,化学反应 25.5H,反应生成2-壬炔酸甲酯
参考文献:一种钯纳米颗粒-纳米胶束组合,用于室温下水中炔烃的立体选择性半氢化
标题:一种钯纳米颗粒-纳米胶束组合,用于室温下水中炔烃的立体选择性半氢化
摘要:在含有纳米胶束的水中将nabh 4 添加到pd(Oac) 2导致h 2和pd纳米颗粒的产生.随后二取代炔烃的还原以高产率提供z-烯烃.这些反应是一般的,在环境温度下在水中发生,并且提供水性反应混合物的循环以及低的总 E 因子.
Doi:10.1002/anie.201407723

专利信息

专利号:US-8153839-B2
优先权日:2005-09-14
标题:Method for synthesis of keto acids or amino acids by hydration of acetylene compound
发明人：OGO SEIJI; FUKUZUMI SHUN-ICHI
权利人:OGO SEIJI; FUKUZUMI SHUN-ICHI; JAPAN SCIENCE & TECH AGENCY
摘要:An object of the present invention is to provide a method for synthesis of keto acids by hydration of an acetylene compound (acetylene-carboxylic acids) under mild conditions free from harmful mercury catalysts and a method for synthesis of amino acids from acetylene-carboxylic acids in a single container (one-pot or tandem synthesis). In one embodiment of the method according to the present invention for synthesis of keto acids, acetylene-carboxylic acids is hydrated in the presence of a metal salt represented by General Formula (1), n nwhere M 1 represents an element in Group VIII, IX, or X of the periodic table, and X 1 , X 2 , or X 3 ligand represents halogen, H 2 O, or a solvent molecule, and k represents a valence of a cation species, and Y represents an anion species, and L represents a valence of the anion species, and each of K and L independently represents 1 or 2, and k×m=L×n.

专利号:US-6583315-B2
优先权日:2000-12-23
标 题:Process for preparing ethanebis(alkylphosphinic) acids
发明人：SICKEN MARTIN; WEFERLING NORBERT; SCHMITZ HANS-PETER
权利人:CLARIANT GMBH
摘要:The invention relates to a process for preparing ethanebis(alkylphosphinic) acids by n a) reacting elemental yellow phosphorus with alkyl halides in the presence of alkali metal hydroxide or of alkaline earth metal hydroxide to give a mixture whose main constituents are the alkali metal salts and/or alkaline earth metal salts of alkylphosphonous, phosphorous, and hypophosphorous acid, n b) liberating alkylphosphonous, phosphorous, and hypophosphorous acid by adding mineral acids, and also at the same time precipitating the alkali metal ions and, respectively, alkaline earth metal ions in the form of their salt of the mineral acids, and then n c) esterifying the alkylphosphonous acid from the mixture of the alkylphosphonous, phosphorous, and hypophosphorous acid, n d) isolating the ester of alkylphosphonous acid from the mixture and hydrolyzing the same to give alkylphosphonous acid, and n e) preparing, from the alkylphosphonous acid, the corresponding ethanebis(alkylphosphinic) acid of the general formula (I) where R 1 and R 2 may be identical or different and are hydrogen, a carboxy group, a carboxylic acid derivative, an unsubstituted or substituted alkyl group having from 1 to 10 carbon atoms, phenyl, benzyl, or alkyl-substituted aromatics, and R 3 and R 4 are identical or different and are an unsubstituted or substituted alkyl group having from 2 to 20 carbon atoms, by free-radical-initiated reaction with alkynes, and also to the use of the ethanebis(alkylphosphinic) acids prepared by this process as starting material for preparing flame retardants and precursors for the synthesis of other phosphorus-containing compounds.

专利号:EP-1932824-A1
优先权日:2005-09-14
标题:Method for synthesis of keto acid or amino acid by hydration of acethylene compound

专利号:US-2009216044-A1
优先权日:2005-09-14
标 题:Method for synthesis of keto acids or amino acids by hydration of acetylene compound

专利号:US-4276220-A
优先权日:1979-07-25
标题:Novel norbornyl-substituted pyrans, method for their synthesis and use thereof in perfumery
发明人：WILLIS BRIAN J; DITTRICK JOHN W
权利人:FRITZSCHE DODGE & OLCOTT INC
摘要:Norbornyl-substituted pyrans, their preparation and their use as olfactory components of perfume formulations are disclosed.

专利号:US-10647942-B2
优先权日:2016-12-22
标题:Fragrance and flavor materials
发明人：BLANDINO MAUREEN; LANKIN MICHAEL E
权利人:TAKASAGO PERFUMERY CO LTD
摘要:The present disclosure is directed to the synthesis and application of undecavertol derivatives having unique and desired flavor and/or fragrant characteristics. The compounds of the present disclosure can be employed alone or incorporated as fragrance or flavor ingredients in fragrance or flavor compositions. The present disclosure is also directed to consumer products comprising such derivatives and/or fragrance or flavor compositions.