CAS: 137-30-4; Ziram

该化合物是一个协调化合物,其特点是锌与两个二甲基二甲卡巴甲酸酯(Ingands)相协调,该化合物通常在锌中心周围显示四面形几何,对锌复合体而言很常见,在锌中心周围有四面形几何,因其在各个领域的应用而著称,包括作为杀菌剂的农业以及作为加速剂的橡胶制造.二硫卡巴甲酸盐的出现具有独特的特性,例如有机溶剂中溶性增强溶性,以及能够形成稳定的金属离子复合体.此外,该化合物还展示了抗微生物和抗硫酸盐活动,在工业和农业应用中都具有价值.其稳定性和再活性可能受到环境因素的影响,包括pH和温度.安全考虑很重要,因为许多金属复合体可能对环境产生影响.

结构式图片

欧盟法规

统一分类与标签压力设备指令-第1组危险流体REACH注册ECHA物质ECHA物质欧盟农药活性物质工作场所安全标识要求C&L通报化妆品禁用物质清单CoRAP评估清单REACH预注册废弃物危险特性清单

上下游产品

CAS号7646-85-7 氯化锌 | CAS号128-04-1 二甲基二硫代氨基甲酸钠 | CAS号137-26-8 二硫化四甲基秋兰姆 | CAS号7440-66-6 锌标准溶液 | CAS号75-15-0 二硫化碳 | CAS号124-40-3 二甲胺 | CAS号75642-17-0 | CAS号557-09-5 辛酸锌 | CAS号557-05-1 硬脂酸锌 | CAS号7640-78-0 Nonanoic acid, ... | CAS号5261-20-1 Zinc diheptanoate

合成工艺路线路线简述

    Sodium Dimethyldithiocarbamate 反应生成福美锌
    参考文献:Marathe,M. N.,Cew,24,(1989) N,C. 49
    标题:Marathe,M. N.,Cew,24,(1989) N,C. 49

    海关参考信息

    专利信息


    专利号:US-7435855-B2
    优先权日:2004-06-18
    标题:Process for the continuous synthesis of methylamines
    发明人:BOSCH MARCO; EBERHARDT JAN KURT; ROETTGER RODERICH; KRUG THOMAS; MELDER JOHANN-PETER
    权利人:BASF SE
    摘要:Process for the continuous synthesis of methylamines by reaction of methanol and/or dimethyl ether with ammonia in the presence of a heterogeneous catalyst, wherein the catalyst used is a shaped body which comprises a microporous material and at least one organosilicon compound as binder and can be produced by a process comprising the stepsn (I) preparation of a mixture comprising the microporous material, the binder, a pasting agent and a solvent, (II) mixing and densification of the mixture, (III) shaping of the densified mixture to give a shaped body, (IV) drying of the shaped body and (V) calcination of the dried shaped body.

    专利号:US-7651968-B2
    优先权日:2005-12-12
    标 题:Shaped body comprising a microporous material and at least one silicon-containing binding agent method for production and use thereof as catalyst in particular in a method for continuous synthesis of methylamines
    发明人:BOSCH MARCO; EBERHARDT JAN; ROETTGER RODERICH
    权利人:BASF SE
    摘要:A process for producing a shaped body comprising a microporous material and at least one silicon-comprising binder, which comprises the stepsn (I) preparation of a mixture comprising the microporous material, the binder and a lubricant, (II) mixing and densification of the mixture, (III) shaping of the densified mixture to give a shaped body and (IV) calcination of the shaped body,n nwherein a silicone resin having a softening point of ≧30° C. is used as binder,n nshaped bodies which can be produced by this process, their use as catalyst, in particular in organic synthesis and very particularly preferably in a process for preparing methylamines.

    专利号:US-9540520-B2
    优先权日:2011-08-17
    标 题 :Synthesis of copper pyrithione from zinc pyrithione and copper compound
    发明人:KAPPOCK PAUL S; MARTIN ROBERT J
    权利人:KAPPOCK PAUL S; MARTIN ROBERT J; ARCH CHEM INC
    摘要:A composition containing unique particles of copper pyrithione wherein greater than 20 wt % to 90 wt % of the particles have a particle size of greater than 10 microns, as determined by laser light scattering using a particle size distribution analyzer, and wherein the particles are flat acicular needle-shaped is described herein. Also described herein is an antifouling paint containing the copper pyrithione and a method of making the composition and antifouling paint.

    专利号:WO-2025056767-A1
    优先权日:2023-09-15
    标题 :Process for the preparation of enantiomerically enriched aliphatic amines
    发明人:BOU HAMDAN FARHAN; GODINEAU EDOUARD; SMEJKAL TOMAS; DUMEUNIER RAPHAEL; BOUSSEMGHOUNE MOHAMED ABDELOUAHAB; BLUM MATHIAS
    权利人:SYNGENTA CROP PROTECTION AG
    摘要:The present invention relates to a process for the preparation of enantiomerically enriched cyclobutylamines of formula (I) from α-tertiary cyclobutanones and reacting said enantiomerically enriched cyclobutylamines to enantiomerically enriched cyclobutylamides. Such compounds are useful intermediates in the synthesis of microbiocidal thiazole compounds.

    专利号:US-2016073631-A1
    优先权日:2013-03-04
    标 题 :Process for the preparation of dihydropyrrole derivatives
    发明人:EL QACEMI MYRIEM; SMITS HELMARS; CASSAYRE JEROME YVES; MULHOLLAND NICHOLAS PHILLIP; RENOLD PETER; GODINEAU EDOUARD; PITTERNA THOMAS
    权利人:SYNGENTA PARTICIPATIONS AG; SYNGENTA LTD
    摘要:The present invention provides stereoselective processes for the preparation of compounds of formula (I) n n n n n n n n n n n n wherein n P is phenyl, naphthyl, a 6-membered heteroaryl group containing one or two nitrogen atoms as ring members, or a 10-membered bicyclic heteroaryl group containing one or two nitrogen atoms as ring members, and wherein the phenyl, naphthyl and heteroaryl groups are optionally substituted; n R 1 is chlorodifluoromethyl or trifluoromethyl; n R 2 is optionally substituted aryl or optionally substituted heteroaryl; n n is 0 or 1; n including the process comprising n (a-i) reacting a compound of formula II n n n n n n n n n n n n n n n n wherein P, R 1 and R 2 are as defined for the compound of formula I; n with nitromethane in the presence a chiral catalyst to give a compound of formula III n n n n n n n n n n n n n n n n wherein P, R 1 and R 2 are as defined for the compound of formula I; and n (a-ii) reductively cyclising the compound of formula III to give the compound of formula I. n n n n n The invention also provides intermediates useful for processes for the synthesis of compounds of formula (I).

    专利号:US-9233920-B2
    优先权日:2010-06-11
    标题 :Process for the preparation of dihydropyrrole derivatives
    发明人:EL QACEMI MYRIEM; SMITS HELMARS; CASSAYRE JEROME YVES; MULHOLLAND NICHOLAS PHILLIP; RENOLD PETER; GODINEAU EDOUARD; PITTERNA THOMAS
    权利人:EL QACEMI MYRIEM; SMITS HELMARS; CASSAYRE JEROME YVES; MULHOLLAND NICHOLAS PHILLIP; RENOLD PETER; GODINEAU EDOUARD; PITTERNA THOMAS; SYNGENTA PARTICIPATIONS AG; SYNGENTA LTD
    摘要:The present invention provides stereoselective processes for the preparation of compounds of formula (I) wherein P is phenyl, naphthyl, a 6-membered heteroaryl group containing one or two nitrogen atoms as ring members, or a 10-membered bicyclic heteroaryl group containing one or two nitrogen atoms as ring members, and wherein the phenyl, naphthyl and heteroaryl groups are optionally substituted; R 1 is chlorodifluoromethyl or trifluoromethyl; R 2 is optionally substituted aryl or optionally substituted heteroaryl; n is 0 or 1; including the process comprising (a-i) reacting a compound of formula II wherein P, R 1 and R 2 are as defined for the compound of formula I; with nitromethane in the presence a chiral catalyst to give a compound of formula III Wherein P, R 1 and R 2 are as defined for the compound of formula I; and (a-ii) reductively cyclizing the compound of formula III to give the compound of formula I. The invention also provides intermediates useful for processes for the synthesis of compounds of formula (I).
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    主要参考文献


    1: Svingen T, Ramhøj L, Mandrup K, Christiansen S, Axelstad M, Vinggaard AM, Hass U. Effects on metabolic parameters in young rats born with low birth weight after exposure to a mixture of pesticides. Sci Rep. 2018 Jan 10;8(1):305. doi: 10.1038/s41598-017-18626-x.
    2: Thind TS, Hollomon DW. Thiocarbamate fungicides - Reliable tools in resistance management and future outlook. Pest Manag Sci. 2017 Dec 29. doi: 10.1002/ps.4844. [Epub ahead of print] doi: 10.1016/j.envres.2017.09.027. Epub 2017 Oct 10. doi: 10.1093/toxsci/kfx181. doi: 10.1016/j.steroids.2017.09.006. Epub 2017 Sep 23. doi: 10.1080/15376516.2017.1355950. doi: 10.1016/j.reprotox.2017.05.004. Epub 2017 May 17. doi: 10.1093/chromsci/bmw198. doi: 10.1016/j.marpolbul.2016.11.047. Epub 2016 Dec 2. Epub 2016 Jun 15.
    12: Bei E, Liao X, Meng X, Li S, Wang J, Sheng D, Chao M, Chen Z, Zhang X, Chen C. Identification of nitrosamine precursors from urban drainage during storm events: A case study in southern China. Chemosphere. 2016 Oct;160:323-31. doi: 10.1016/j.chemosphere.2016.06.081. Epub 2016 Jul 6. doi: 10.1016/j.talanta.2016.05.042. Epub 2016 May 14. doi: 10.1021/acs.chemrestox.5b00527. Epub 2016 Feb 18. doi: 10.1016/j.expneurol.2015.09.017. Epub 2015 Oct 9.

    合成参考文献


    摘要:Romer KG et al; Bull Environ Contam Toxicol 32 (5): 537-42 (1984)
    摘要:Farm Chemicals Handbook 2001. Willoughby, Ohio: Meister 2001., p. C 421
    摘要:USEPA/Office of Water; Federal-State Toxicology and Risk Analysis Committee (FSTRAC). Summary of State and Federal Drinking Water Standards and Guidelines (11/93) To Present
    摘要:40 CFR 180.116 (7/1/2001)
    摘要:U.S. Environmental Protection Agency/Office of Prevention, Pesticides, and Toxic Substances. Reigart, J.R., Roberts, J.R. Recognition and Management of Pesticide Poisonings. 5th ed. 1999. EPA Document No. EPA 735-R-98-003, and available in electronic format at: https://www.epa.gov/pesticides/safety/healthcare, p. 143
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