CAS: 17849-38-6; 2-Chlorobenzyl Alcohol

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CAS号610-96-8 邻氯苯甲酸甲酯 | CAS号89-98-5 邻氯苯甲醛 | CAS号609-65-4 邻氯苯甲酰氯 | CAS号118-91-2 邻氯苯甲酸 | CAS号56961-30-9 2-氯-5-羟基苯甲酸 | CAS号7335-25-3 2-氯苯甲酸乙酯 | CAS号512180-26-6 2-[(2-chlorophe... | CAS号95-49-8 邻氯甲苯 | CAS号611-19-8 邻氯氯苄 | CAS号39545-31-8 氯甲酸邻氯苄酯 | CAS号40018-25-5 邻氯苯乙酰腈 | CAS号21122-36-1 S-phenyl 2-chlo... | CAS号2082-66-8 硫氰酸2-氯苯甲酯 | CAS号3574-96-7 2-(2-氯苯基)-1H-苯并咪唑 | CAS号95-57-8 邻氯苯酚 | CAS号89-98-5 邻氯苯甲醛 | CAS号118-91-2 邻氯苯甲酸 | CAS号67342-76-1 苄基-(2-氯苄基)胺 | CAS号69875-89-4 苄基-(2-甲氧基苄基)胺

2-氯苯甲酸置于c24H23Clcrirno3,四丁基氟化铵,四(3,5-二(三氟甲基)苯基)硼酸钠体系中,用 四氢呋喃,二氯甲烷 用作溶剂,化学反应 28.08H,反应生成邻氯苄醇
参考文献:用于羰基和羧酸衍生物有效氢化硅烷化的多功能铱(III)金属环催化剂
标题:用于羰基和羧酸衍生物有效氢化硅烷化的多功能铱(III)金属环催化剂
摘要:通用的ir Iii金属环可快速,选择性地催化各种酯,羧酸,酮和醛的还原.该反应在室温下通过氢化硅烷化然后脱甲硅烷基化以高收率进行.取决于底物,酯被还原为醇或醚,而羧酸被还原为醇或醛.
Doi:10.1002/ejoc.201700801

专利信息

专利号:US-7102023-B2
优先权日:1999-11-24
标 题:Protecting groups useful in the synthesis of polysaccharides, natural products, and combinatorial libraries
发明人：BUCHWALD STEPHEN L; PLANTE OBADIAH J; SEEBERGER PETER H
权利人:MASSACHUSETTS INST TECHNOLOGY
摘要:One aspect of the present invention relates to optionally substituted halogenated benzyl halides and the like. These compounds are useful as halogenated benzyl ether-based protecting groups for a variety of functional groups. Another aspect of the present invention relates to use of said protecting groups in an orthogonal protecting group strategy for the synthesis of complex molecules that comprise a number of suitable functional groups. Another aspect of the present invention relates to saccharides bearing various arrays of protecting groups of the present invention. Another aspect of the present invention relates to a method of synthesizing an oligosaccharide or glycoconjugate, comprising the steps of: using a saccharide bearing at least one protecting group of the present invention to glycosylate a second molecule to give a product comprising said saccharide; and removing a protecting group of the present invention from said product.

专利号:US-2009221568-A1
优先权日:2005-11-04
标题:Synthesis of Inhibitors of FtsZ
发明人：SHAW JARED; URGAONKAR SAMEER; RAYCHAUDHURI DEBABRATA; LA PIERRE HENRY
权利人:SHAW JARED; URGAONKAR SAMEER; RAYCHAUDHURI DEBABRATA; LA PIERRE HENRY
摘要:FtsZ, the bacterial analog of tubulin, is a promising new target for developing new antibiotics. It has been shown that polyphenols inhibit the GTPase activity of FtsZ, thereby inhibiting Z-ring formation during mitosis. The present invention provides novel polyphenols compounds, which can be accessed by the synthesis of dichamametin and 2′″-hydroxy-5″-benzylisouvarinol-B as described herein. These novel compounds are useful in treating infections, particularly infections caused by gram-positive organisms. Methods of preparing the inventive compounds are also provided. The compounds are prepared by the benzylation of pinocembrin or chrysin core structure. Pharmaceutical compositions and method of using the compounds to treat disease are also provided. These compounds may be screened for antimicrobial activity as well as other biological activities such as anti-neoplastic, anti-inflammatory, immunosuppressive, and cytotoxic activity.

专利号:US-2003181690-A1
优先权日:1999-11-24
标 题 :Protecting groups useful in the synthesis of polysaccharides, natural products, and combinatorial libraries

专利号:US-4269773-A
优先权日:1976-04-27
标 题:Fused oxazolidine compounds
发明人：MITSURU YOSHIOKA; TERUJI TSUJI; YASUHIRO NISHITANI; WATARU NAGATA
权利人:SHIONOGI & CO
摘要:Compounds represented by the following formula prepared from 6-aminopenicillanic acid are key intermediates in a stereo-specific synthesis of 1-oxadethiacephalosporins, highly active antibiotics: +TR [wherein COA and COB each is carboxy or protected carboxy; COX is carboxy, protected carboxy, or a group of the formula -COCQ=N2 or -COCHQ-Z (in which Q is hydrogen, lower alkyl or aryl; and Z is hydrogen or a nucleophilic group); Hal is halogen; R is lower alkyl or aralkyl; and Y is hydrogen or acyl].

专利号:US-5149814-A
优先权日:1987-09-30
标 题:Alkyl 2-benzylidene-4-(2-alkylimidazopyrid-1-yl) benzoylacetate esters as intermediate compounds
发明人：COOPER KELVIN; FRAY MICHAEL J; RICHARDSON KENNETH; STEELE JOHN
权利人:PFIZER
摘要:Intermediates useful in the synthesis of dihydropyridine platelet activating factor antagonists of the formula ##STR1## where R is phenyl or substituted phenyl; R 3 is lower alkyl; Y is 1,4-phenylene and X is 2-alkylimidazopyridyl.

专利号:CN-104710325-A
优先权日:2013-12-13
标 题:One-step synthesis of imines from alcohols and amines catalyzed by supported manganese oxides