Phenylmagnesium Chloride置于lithium Aluminium Tetrahydride体系中,化学反应生成甲基苯乙烯硅烷 参考文献:The Synthesis And Polymerization Of Organosilanes Containing Vinyl And Hydrogen Joined To The Same Silicon Atom 标题:The Synthesis And Polymerization Of Organosilanes Containing Vinyl And Hydrogen Joined To The Same Silicon Atom 摘要: Doi:10.1021/ja01589A054
专利号:US-7456298-B2 优先权日:2002-06-03 标题:Synthesis of acetonides from aryl silanes 发明人:MCAULIFFE JOSEPH C; WHITED GREGORY M; SMITH WYATT CHARLES 权利人:GENENCOR INT 摘要:The present invention is related to cis-diols and biological methods of producing cis-diols. The present invention further relates to processes for subsequently converting such silane cis-diols to the more stable acetonide derivatives, as well as a process for converting silane cis-diols to the corresponding catechols and the compounds produced thereby. The present invention also provides chemical methods for the conversion of said silane cis-diols and acetonide compounds to epoxy, saturated and otherwise modified derivatives. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that is will not be used to interpret or limit the scope or meaning of the claims.
专利号:US-2004033574-A1 优先权日:2002-06-03 标题 :Synthesis of cis-diols from aryl silanes
专利号:US-11767388-B1 优先权日:2019-09-18 标 题 :Silicon-functionalized rubber 发明人:ENSIGN SETH CODY; VIELHABER MARGARET FLOOK; JOHNGRASS JENA LYNN; MA LIQING 权利人:GOODYEAR TIRE & RUBBER 摘要:The compatibility between silica fillers and synthetic rubbers which are synthesized utilizing lanthanide-based catalyst systems, such as neodymium catalyst systems can be improved by terminating the polymerization with a vinyl silane terminating agent. In doing so the vinyl silane is allowed to react with the polymer chain ends of the neodymium rubber to functionalize the chain ends of the polymer chains with silicon containing groups. This results in the rubber having better characteristics for utilization in tire rubber formulations, such a tire tread formulations, that exhibit improved wear characteristics and lower rolling resistance. The process for the synthesis of such functionalized polydiene rubber comprises (1) polymerizing a diene monomer in the presence of a lanthanide-based catalyst system, and (2) terminating the polymerization with a vinyl silane terminator. The functionalized polydiene rubber composition made by this method is comprised of a polydiene rubber which is functionalized at its chain ends with a silicon containing group.
专利号:US-2007213550-A1 优先权日:2002-06-03 标题 :Synthesis of cis-diols from aryl silanes
专利号:US-2007213541-A1 优先权日:2002-06-03 标 题 :Synthesis of acetonides from aryl silanes
专利号:US-7381830-B2 优先权日:2002-06-03 标 题 :Synthesis of cis-diols from aryl silanes