CAS: 13311-45-0; Tetrabutylammonium Triiodide

相似化合物

311-28-4 81412-07-9 1112-67-0

上下游产品

CAS号311-28-4 四丁基碘化铵

四丁基碘化铵置于碘体系中,用 甲醇 用作溶剂,化学反应 0.17H,以85%的收率获得四正丁铵三碘盐
参考文献:在流动中使用强还原性催化介体进行芳基卤化物的阴极自由基环化
标题:在流动中使用强还原性催化介体进行芳基卤化物的阴极自由基环化
摘要:芳基卤化物的阴极自由基环化已在不分流电解池中实现,使用菲作为介体,负载量低至 0.05 当量,且无需牺牲阳极.据推测,介导的均匀电子转移在与阴极分离的反应层中进行,从而解释了观测到的选择性.
Doi:10.1002/anie.202203694

专利信息

专利号:US-9018325-B2
优先权日:2011-08-25
标题 :Catalyst for living radical polymerization and polymerization method
发明人：GOTO ATSUSHI; KAJI HIRONORI
权利人:GOTO ATSUSHI; KAJI HIRONORI; UNIV KYOTO
摘要:A nonmetallic compound having an ionic bond with a halide ion is used as a catalyst for living radical polymerization. Even if a radical initiator is not used, a monomer can be subjected to a radical polymerization to obtain a polymer having narrow molecular weight distribution. The cost of the living radical polymerization can be remarkably reduced, and it is made possible to prevent adverse effects of using a radical initiator (such as side reactions). The present invention is significantly more environmentally friendly and economically excellent than conventional living radical polymerization methods, due to advantages such as low toxicity of the catalyst, low amount of the catalyst necessary, high solubility of the catalyst, mild reaction conditions, and no coloration/no odor, etc. The catalyst can be applied to various monomers and enables synthesis of high molecular weight polymers.

专利号:WO-2024189137-A1
优先权日:2023-03-15
标 题 :Process for the synthesis of the compound 5,7-diiodo-1-oxaspiro[2,5]octa-4,7-dien-6-one