专利号:WO-2025202701-A1 优先权日:2024-08-21 标 题 :Marine antifouling paint based on silyl acrylate copolymer synthesis 发明人:LAHEGHI NEJAD FARHAD 权利人:LAHEGHI NEJAD FARHAD 摘要:This invention involves the production of marine anti-fouling paint using the synthesis of silyl acrylate copolymers. One of the most effective anti-algae or anti-fouling paints was self-polishing paints based on acrylate resins containing tributyl tin, which were banned due to the toxicity of their tin compounds. One of the best-introduced alternatives is self-polishing paints based on silyl acrylate copolymers, but their performance is subpar and they have a shorter lifespan. In this invention, silyl acrylate copolymers in a controlled structure, including at least one soft monomer such as butyl acrylate, ethyl acrylate, etc., at least one hard monomer such as methyl methacrylate, 2-methoxyethyl methacrylate, etc. and at least one functional monomer such as triisopropyl silyl acrylate, triisopropyl silyl methacrylate, tertiary-butyl dimethyl silyl methacrylate, and tri-N-butyl silyl methacrylate were synthesized in which monomers or hard monomers were gradually added to the reactor in 2-6 hours.
专利号:US-2017029630-A1 优先权日:2011-08-17 标题 :Synthesis of Copper Pyrithione From Zinc Pyrithione and Copper Compound
专利号:WO-2008156984-A1 优先权日:2007-06-15 标 题 :Use of cyclodextrins in controlled architecture polymer synthesis 发明人:GARCIA-LEINER MANUEL A; MEHLMANN FLORENCE; PRUD HOMME ROBERT K; HERRERA-ALONSO MARGARITA; FU LIN 权利人:ARKEMA INC; UNIV PRINCETON; GARCIA-LEINER MANUEL A; MEHLMANN FLORENCE; PRUD HOMME ROBERT K; HERRERA-ALONSO MARGARITA; FU LIN 摘要:The invention relates to the use of macromolecular organic compound carriers, such as cyclodextrins, in a controlled radical polymerization process in aqueous media. The process can be used with a nitroxide-mediated process, atom transfer radical polymerization or similar processes to form controlled architecture homopolymer and block polymers. The macromolecular organic compound carriers can also be used to form amphiphilic block polymers in aqueous media by several different controlled-radical polymerization processes. Further, the use of macromolecular organic compound carriers in an aqueous media controlled radical polymerization process presents a means for recycling of the macromolecular organic compound carrier and radical control agent.
专利号:US-2014296371-A1 优先权日:2011-08-17 标题:Synthesis of Copper Pyrithione From Zinc Pyrithione and Copper Compound
专利号:JP-2014524443-A 优先权日:2011-08-17 标 题 :Synthesis of copper pyrithione from zinc pyrithione and copper compounds
专利号:JP-2017125056-A 优先权日:2011-08-17 标 题 :Synthesis of copper pyrithione from zinc pyrithione and copper compounds
参考文献:10.1007/s40684-024-00635-7 摘要:Yang JB, Lee H, Kim DR. Design and Fabrication of Nature-Inspired Surfaces for Anti-Fouling: A Review. Int. J. of Precis. Eng. and Manuf.-Green Tech. 2024 May 20;12(1):321–47. doi: 10.1007/s40684-024-00635-7.