CAS: 38896-30-9; Methyl Quinoline-6-Carboxylate

相似化合物

4113-04-6 10349-57-2 108166-01-4

上下游产品

CAS号67-56-1 甲醇 | CAS号10349-57-2 6-喹啉甲酸 | CAS号612-57-7 6-氯喹啉 | CAS号201230-82-2 carbon monoxide | CAS号74-98-6 丙烷 | CAS号173089-80-0 三氟甲磺酸6-喹啉酯 | CAS号14002-34-7 三(3-羟基丙基)胺 | CAS号619-50-1 4-硝基苯甲酸甲酯 | CAS号530-62-1 N,N'-羰基二咪唑(CDI) | CAS号186581-53-3 重氮甲烷 | CAS号386207-77-8 4-氯喹啉-6-甲酸 | CAS号1065092-81-0 4-羟基-喹啉-6-羧酸 | CAS号5382-47-8 喹啉-6-碳酰肼 | CAS号849807-09-6 2-氯喹啉-6-羧酸甲酯 | CAS号99071-54-2 6-氨基甲基喹啉 | CAS号100516-88-9 6-羟甲基喹啉 | CAS号177478-49-8 1,2,3,4-四氢喹啉-6-甲酸甲酯 | CAS号23395-72-4 6-氰基喹啉 | CAS号956907-14-5 6-溴-1-(喹啉-6-甲基)...

6-(Methoxycarbonyl)Quinoline 1-Oxide置于10-Phenyl-9-(2,4,6-Trimethylphenyl)Acridinium Tetrafluoroborate,二异丙胺体系中,用 乙腈 作为反应溶剂,以83 %的收率获得产物6-喹啉羧酸甲酯
参考文献:氮杂芳基氮氧化物的无金属可见光催化脱氧:利用光子进行高效的绿色合成
标题:氮杂芳基氮氧化物的无金属可见光催化脱氧:利用光子进行高效的绿色合成
摘要:缺电子氮杂芳烃的区域选择性和化学选择性官能化通常需要将其转化为相应的n-氧化物,并随后在官能化后去除氧以得到所需的取代的氮杂芳烃.使用吖啶基有机光催化剂在蓝色 Led 光下开发了一种高效的无金属可见光光氧化还原催化氮杂环化合物n氧化物脱氧的方法.该方法的高效性和温和性已通过多种具有反应性官能团的氮杂环n-氧化物的较高脱氧产率得到证明.光催化还原的稳健性已通过将反应轻松放大至克级而得到证明,且反应产率没有太大变化.
DOI:10.1002/asia.202400147

专利信息

专利号:US-7452994-B2
优先权日:2001-09-12
标 题 :Synthesis of enantiomerically pure amino-substituted fused bicyclic rings
发明人：MCEACHERN ERNEST J; BRIDGER GARY J; SKUPINSKA KRYSTYNA A; SKERLJ RENATO T; YANG WEN
权利人:ANORMED INC
摘要:This invention describes various processes for synthesis and resolution of racemic amino-substituted fused bicyclic ring systems. One process utilizes selective hydrogenation of an amino-substituted fused bicyclic aromatic ring system. An alternative process prepares the racemic amino-substituted fused bicyclic ring system via nitrosation. In addition, the present invention describes the enzymatic resolution of a racemic mixture to produce the (R)- and (S)-forms of amino-substituted fused bicyclic rings as well as a racemization process to recycle the unpreferred enantioner. Further provided by this invention is an asymmetric synthesis of the (R)- or (S)-enantiomer of primary amino-substituted fused bicyclic ring systems.

专利号:US-2003114679-A1
优先权日:2001-09-12
标 题:Synthesis of enantiomerically pure amino-substituted fused bicyclic rings

专利号:US-2005080267-A1
优先权日:2001-09-12
标 题:Synthesis of enantiomerically pure amino-substituted fused bicyclic rings

专利号:US-2007060757-A1
优先权日:2001-09-12
标题 :Synthesis of enantiomerically pure amino-substituted fused bicyclic rings

专利号:EP-1487795-A2
优先权日:2001-09-12
标题 :Synthesis of enantiomerically pure amino-substituted fused bicyclic rings

专利号:ZA-200400750-B
优先权日:2001-09-12
标 题 :Synthesis of enantiomerically pure amino-substituted fused bicyclic rings.