CAS: 51755-66-9; 3-(Methylthio)Hexan-1-Ol

相似化合物

51755-83-0 51755-85-2 51755-66-9

上下游产品

trimethyl phosphite 3-mercapto-1-hexanol

磷酸三甲酯,3-巯基-1-己醇置于calcium Hydroxide体系中,用 N,N-二甲基甲酰胺 作为反应溶剂,化学反应 0.5H,以76%的收率获得产物3-甲硫基-1-己醇
参考文献:使用磷酸三甲酯 (Tmp)-ca(Oh)2 组合的温和杂原子(o-,N-和 S-)甲基化方案
标题:使用磷酸三甲酯 (Tmp)-ca(Oh)2 组合的温和杂原子(o-,N-和 S-)甲基化方案
摘要:已开发出使用磷酸三甲酯 (Tmp)-Ca(Oh) 2组合的温和杂原子甲基化方案,该方案在 Dmf 或水中,或在纯净条件下,在 80 oc 或室温下进行.一系列o-,N-和s-亲核试剂,包括苯酚,磺酰胺,N-杂环,例如 9 H-咔唑,吲哚衍生物和 1,8-萘酰亚胺,以及芳基/烷基硫醇,是这个协议.该协议的高效,操作简单,可扩展性,成本效益和环保性质使其成为传统碱基促进杂原子甲基化程序的有吸引力的替代方案.
DOI:10.1055/a-1731-3852

专利信息

专利号:US-5637757-A
优先权日:1995-04-11
标 题 :One-pot synthesis of ring-brominated benzoate compounds
发明人：HILL JOHN E; FAVSTRITSKY NICOLAI A; MAMUZIC RASTKO I; BHATTACHARYA BHABATOSH
权利人:GREAT LAKES CHEMICAL CORP
摘要:A method of preparing tetrabromobenzoate compounds from tetrabromophthalic anhydride by reacting tetrabromophthalic anhydride with alcohol in the presence of a decarboxylation catalyst. The reaction may be carried out in an excess of alcohol, or with a near stoichiometric amount of alcohol by performing the reaction in an inert solvent.

专利号:WO-9632368-A1
优先权日:1995-04-11
标题:One-pot synthesis of ring-brominated benzoate compounds

专利号:EP-0825974-A1
优先权日:1995-04-11
标 题 :One-pot synthesis of ring-brominated benzoate compounds

专利号:CA-2217760-A1
优先权日:1995-04-11
标题:One-pot synthesis of ring-brominated benzoate compounds

专利号:US-8865624-B2
优先权日:2010-09-01
标题 :Inhibitor for tobacco axillary bud growth and method for inhibiting tobacco axillary bud growth
发明人：TANAKA MOTOKI; TANAKA KEIJITSU; SHIBUYA TAKESHI; IKUTA EIJI; YOSHINAGA KOTARO; YAMAGUCHI YUKI
权利人:TANAKA MOTOKI; TANAKA KEIJITSU; SHIBUYA TAKESHI; IKUTA EIJI; YOSHINAGA KOTARO; YAMAGUCHI YUKI; SDS BIOTECH CORP
摘要:The present invention relates to an inhibitor for tobacco axillary bud growth, the inhibitor comprising, as an active ingredient, one or more kinds of very-long chain fatty acid synthesis inhibitors such as a chloroacetamide-based herbicide, fentrazamide, cafenstrole or indanofan; an inhibitor for tobacco axillary bud growth, the inhibitor comprising the aforesaid very-long chain fatty acid synthesis inhibitor together with clorthal-dimethyl or an aliphatic alcohol having 6 to 20 carbon atoms; and a method for inhibiting tobacco axillary bud growth which comprises applying the inhibitor for tobacco axillary bud growth. The inhibitor for tobacco axillary bud growth of the present invention shows sustained drug efficacy at a low concentration, induces neither chemical injury nor disease, and can contribute to the improvement in labor productivity.

专利号:EP-0825974-A4
优先权日:1995-04-11
标题:SYNTHESIS IN A SINGLE CONTAINER OF BROMINATED BENZOATE CYCLIC COMPOUNDS