CAS: 136196-47-9; 3-Hydroxy-1-(4-Hydroxy-3,5-Dimethoxyphenyl)Propan-1-One

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1-(4-(benzyloxy)-3,5-dimethoxyphenyl)-2-(2-methoxyphenoxy)propane-1,3-diol ethyl 3-(4-(benzyloxy)-3,5-dimethoxyphenyl)-3-hydroxy-2-(2-methoxyphenoxy)propanoate 1-(4-(benzyloxy)-3,5-dimethoxyphenyl)-3-hydroxy-2-(2-methoxyphenoxy)propan-1-one 1-(4-hydroxy-3,5-dimethoxyphenyl)-2-(2'-methoxyphenoxy)-1,3-propanediol 1-(4-hydroxy-3,5-dimethoxyphenyl)propan-1-one 4-n-propylsyringol 3-(4-hydroxy-3,5-dimethoxyphenyl)propan-1-ol trans-sinapyl alcohol

1-(4-(苄氧基)-3,5-二甲氧基苯基)-2(2-甲氧基苯氧基)丙烷-1,3-二醇置于甲酸,(4,4'-Di-Tert-Butyl-2,2'-Dipyridyl)-Bis-(2-Phenylpyridine(-1H))-Iridium(III) Hexafluorophosphate,五甲基苯,C26H51N2O2(1+)*bf4(1-),Silica Gel,三氯化硼,N,N-二异丙基乙胺体系中,用 二氯甲烷,乙腈 用作溶剂,化学反应 72.5H,反应生成Beta-Hydroxypropiosyringone; 3-羟基-1-(4-羟基-3,5-二甲氧基苯基)丙-1-酮
参考文献:A Photochemical Strategy For Lignin Degradation At Room Temperature
标题:A Photochemical Strategy For Lignin Degradation At Room Temperature
摘要:The Development Of A Room-Temperature Lignin Degradation Strategy Consisting Of A Chemoselective Benzylic Oxidation With A Recyclable Oxidant ([4-Acnh-Tempo]Bf4) And A Catalytic Reductive C-O Bond Cleavage Utilizing The Photocatalyst [ir(Ppy)(2)(Dtbbpy)]Pf6 Is Described. This System Was Tested On Relevant Lignin Model Substrates Containing Beta-O-4 Linkages To Generate Fragmentation Products In Good To Excellent Yields.
Doi:10.1021/ja4113462